TiO2 composited with carbon nanofibers or nitrogen-doped carbon nanotubes synthesized using coal fly ash as a catalyst: bisphenol-A photodegradation efficiency evaluation

2018 ◽  
Vol 42 (6) ◽  
pp. 4531-4542 ◽  
Author(s):  
Lerato Hlekelele ◽  
Paul J. Franklyn ◽  
Farai Dziike ◽  
Shane H. Durbach

The photocatalytic efficiency of TiO2 was improved by compositing it with carbon nanomaterials synthesized using a waste material, fly ash.

RSC Advances ◽  
2016 ◽  
Vol 6 (80) ◽  
pp. 76773-76779 ◽  
Author(s):  
Lerato Hlekelele ◽  
Paul J. Franklyn ◽  
Pranav K. Tripathi ◽  
Shane H. Durbach

CVD of melamine over waste coal fly ash to form N-doped carbon nanotubes (NCNTs) of various morphologies and crystallinities as a function of temperature and % N incorporation.


2018 ◽  
Vol 9 ◽  
pp. 2015-2031 ◽  
Author(s):  
Mattia Scardamaglia ◽  
Carla Bittencourt

In this review, we discuss the use of doped carbon nanomaterials in catalysis, a subject that is currently intensively studied. The availability of carbon nanotubes since the 1990’s and of graphene ten years later prompted the development of novel nanotechnologies. We review this topic linking fundamental surface science to the field of catalysis giving a timely picture of the state of the art. The main scientific questions that material scientists have addressed in the last decades are described, in particular the enduring debate on the role of the different nitrogen functionalities in the catalytic activity of nitrogen-doped carbon nanotubes and graphene.


Author(s):  
Yuning Zhang ◽  
Hao Jiang ◽  
Dongfang Niu ◽  
Manke Ingo ◽  
Chao Yang ◽  
...  

Nitrogen-doped carbon nanomaterials for electrochemical reduction of CO2 (CO2ER) to CO have been extensively investigated, evaluated, and applied recently. Nevertheless, their weak adsorption capacity for CO2 usually results in a...


2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Godfrey Keru ◽  
Patrick G. Ndungu ◽  
Vincent O. Nyamori

Nitrogen-doped carbon nanotubes (N-CNTs) were synthesized by pyrolysis of (4-{[(pyridine-4-yl)methylidene]amino}phenyl)ferrocene in a solution of either acetonitrile or toluene as carbon source. This was achieved by testing three different growth temperatures (800, 850, and 900°C), and the 850°C was found to be the most favourable condition for N-CNT growth. At the lower temperature of 800°C, amorphous carbon was mainly formed while at the higher temperature of 900°C, the yield of carbon spheres (CSs) increased. Apart from the variation in temperature, the formation of other shaped carbon nanomaterials (SCNMs) was found to be carbon source dependent. Acetonitrile was found to produce mainly N-CNTs with “bamboo” morphology while toluene formed a mixture of pristine CNTs and N-CNTs in the ratio of 1 : 1. N-CNTs, and other SCNMs synthesized were characterized by means of TEM, SEM, Raman spectroscopy, TGA, and elemental analysis.


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