La activated high surface area titania float for the adsorption of Pb(ii) from aqueous media

2018 ◽  
Vol 42 (2) ◽  
pp. 1067-1077 ◽  
Author(s):  
Shwetharani R. ◽  
Poojashree A. ◽  
Geetha R. Balakrishna ◽  
Jyothi M. S.
Keyword(s):  
Heavy Metal ◽  
Particle Size ◽  
Surface Area ◽  
Metal Ion ◽  
High Surface ◽  
Aqueous Media ◽  
High Surface Area ◽  
Heavy Metal Ion ◽  
Enhanced Adsorption

Smaller particle size with higher surface area La-TiO2 fabricated float depicts enhanced adsorption of hazardous heavy metal ion Pb2+, present in the aqueous media and the float makes the process easy and reusable.

High surface area mesoporous titanium–zirconium oxide nanofibrous web: a heavy metal ion adsorbent

2013 ◽  
Vol 1 (19) ◽  
pp. 5847 ◽  
Author(s):  
Jonghyun Choi ◽  
Andreas Ide ◽  
Yen B. Truong ◽  
Ilias L. Kyratzis ◽  
Rachel A. Caruso
Keyword(s):  
Heavy Metal ◽  
Surface Area ◽  
Zirconium Oxide ◽  
Metal Ion ◽  
High Surface ◽  
High Surface Area ◽  
Heavy Metal Ion ◽  
Titanium Zirconium

Adsorption of divalent heavy metal ion by mesoporous-high surface area chitosan/poly (ethylene oxide) nanofibrous membrane

2017 ◽  
Vol 157 ◽  
pp. 57-64 ◽  
Author(s):  
Md Islam Shariful ◽  
Sazzad Bin Sharif ◽  
Jacky Jia Li Lee ◽  
Umma Habiba ◽  
Bee Chin Ang ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Ethylene Oxide ◽  
Surface Area ◽  
Metal Ion ◽  
High Surface ◽  
High Surface Area ◽  
Nanofibrous Membrane ◽  
Heavy Metal Ion ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene

Sol–gel derived mesoporous GaAlPO4 glass for heavy metal ion sequestration

RSC Advances ◽  
2016 ◽  
Vol 6 (101) ◽  
pp. 99149-99157 ◽  
Author(s):  
Jin He ◽  
Pengfei Ma ◽  
Ge Zhang ◽  
Rihong Li ◽  
Long Zhang
Keyword(s):  
Heavy Metal ◽  
Metal Ion ◽  
High Surface ◽  
Sol Gel ◽  
High Surface Area ◽  
Chemical Diversity ◽  
Heavy Metal Ion ◽  
Practical Applications ◽  
Ion Sequestration ◽  
Adsorbent Materials

Mesoporous phosphate materials with chemical diversity and a high surface area are essential for their practical applications as heavy metal ion adsorbent materials.

scholarly journals An Eco-Friendly Process for Removal of Lead from Aqueous Solution

2017 ◽  
Vol 11 (5) ◽  
pp. 47 ◽  
Author(s):  
Heman A. Smail ◽  
Kafia M. Shareef ◽  
Zainab H. Ramli
Keyword(s):  
Heavy Metal ◽  
Oxalic Acid ◽  
Surface Area ◽  
Pore Volume ◽  
Metal Ion ◽  
Adsorption Equilibrium ◽  
Total Pore Volume ◽  
Heavy Metal Ion ◽  
Bet Surface Area ◽  
Barley Husk

The adsorption of lead (Pb II) ion on different types of synthesized zeolite was investigated. The BET surface area, total pore volume & average pore size distribution of these synthesized zeolites were determined by adsorption isotherms for N2, the surface area & total pore volume of their sources were found by adsorption isothermN2.The adsorption equilibrium was measured after 24h at room temperature (RT) & concentration 10mg.L-1 of Pb (II) was used. The adsorption of heavy metal Pb (II) on four different prepared zeolites (LTA from Montmorillonite clay, FAU(Y)-B.H (G2) from Barley husk, Mordenite (G1) from Chert rock, FAU(X)-S.C (G3) from shale clay & modified Shale clay by oxalic acid (N1) & sodium hydroxide (N2)), were compared with the adsorption of their sources by using static batch experimental method. The major factors affecting the heavy metal ion sorption on different synthesized zeolites & their sources were investigated. The adsorption equilibrium capacity (Qm) of Pb (II) ion for different synthesized zeolites ordered from (N1>N2>LTA>G3>G2>G1&for their sources ordered Shale clay >Montmorilonite> Barley husk>Chert rock. The atomic absorption spectrometry was used for analysis of lead heavy metal ion, the obtained results in this study showed that the different synthesized zeolites were efficient ion exchanges for removing heavy metal, in particular, the modified zeolite from shale clay by oxalic acid.

scholarly journals Characteristics of Phosphorus Adsorption and Release in Different Types of Sediments

2020 ◽  
Vol 8 (05) ◽  
pp. 342-354
Author(s):  
Pengqiang Yang ◽  
Huanghe ◽  
Rujun Gao
Keyword(s):  
Heavy Metal ◽  
Particle Size ◽  
Organic Matter ◽  
Metal Ion ◽  
Organic Matter Content ◽  
Matter Content ◽  
Heavy Metal Ion ◽  
Phosphorus Adsorption ◽  
Different Types ◽  
Adsorption And Release

Taking different types of sediments as the research object, this research studied the adsorption and release characteristics of phosphorus under different conditions of different temperatures, coexisting heavy metal ion system, organic matter content and sediment particle size. Through used correlation analysis and principal component analysis, it discussed the influence of various factors on the adsorption and release of phosphorus in sediments. The results show that the adsorption of phosphorus by five different types of sediments from different sources reached saturation equilibrium in about 10 hours, and the increasing rates of 0 ℃, 15 ℃ and 30 ℃ are 17.5% ~ 23.7% and 18.2% ~ 38.3%, respectively.  The addition of coexisting heavy metal ion solution accelerated the adsorption of phosphorus in the sediment and reduced the total amount of phosphorus adsorption, that is, heavy metal ions inhibited the adsorption of phosphorus in the sediment; the presence of organic matter in the sediment would reduce its adsorption of phosphorus , Taihu farm and wetland sampling points have the largest sediment organic matter content. Compared with the other three points, the adsorption of phosphorus of these two  points accounted for 20.6% and 22.1%; the adsorption and release of phosphorus by sediment increased with the decrease of particle size. The maximum release rate was 5.216mg/kg-1·h-1. The result of principal component analysis shows that the order of influence on the adsorption and release of phosphorus by sediments is temperature> disturbance> organic matter content> heavy metal ion influence> particle size of sediments.

scholarly journals Carbon Nanomaterials for the Treatment of Heavy Metal-Contaminated Water and Environmental Remediation

2019 ◽  
Vol 14 (1) ◽  
Author(s):  
Rabia Baby ◽  
Bullo Saifullah ◽  
Mohd Zobir Hussein
Keyword(s):  
Heavy Metal ◽  
Surface Area ◽  
Environmental Remediation ◽  
Carbon Nanomaterials ◽  
Heavy Metal Contamination ◽  
High Surface ◽  
High Surface Area ◽  
Contaminated Water ◽  
Removal Of Heavy Metals ◽  
Carbon Based Nanomaterials

Abstract Nanotechnology is an advanced field of science having the ability to solve the variety of environmental challenges by controlling the size and shape of the materials at a nanoscale. Carbon nanomaterials are unique because of their nontoxic nature, high surface area, easier biodegradation, and particularly useful environmental remediation. Heavy metal contamination in water is a major problem and poses a great risk to human health. Carbon nanomaterials are getting more and more attention due to their superior physicochemical properties that can be exploited for advanced treatment of heavy metal-contaminated water. Carbon nanomaterials namely carbon nanotubes, fullerenes, graphene, graphene oxide, and activated carbon have great potential for removal of heavy metals from water because of their large surface area, nanoscale size, and availability of different functionalities and they are easier to be chemically modified and recycled. In this article, we have reviewed the recent advancements in the applications of these carbon nanomaterials in the treatment of heavy metal-contaminated water and have also highlighted their application in environmental remediation. Toxicological aspects of carbon-based nanomaterials have also been discussed.

scholarly journals Hyper-Crosslinked Polymer Nanocomposites Containing Mesoporous Silica Nanoparticles with Enhanced Adsorption Towards Polar Dyes

Polymers ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1388
Author(s):  
Marco Guerritore ◽  
Rachele Castaldo ◽  
Brigida Silvestri ◽  
Roberto Avolio ◽  
Mariacristina Cocca ◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Silica Nanoparticles ◽  
Surface Area ◽  
Organic Dyes ◽  
Mesoporous Silica Nanoparticles ◽  
High Surface ◽  
High Surface Area ◽  
Reactive Dye ◽  
New Strategy ◽  
Enhanced Adsorption

The development of new styrene-based hyper-crosslinked nanocomposites (HCLN) containing mesoporous silica nanoparticles (MSN) is reported here as a new strategy to obtain functional high surface area materials with an enhanced hydrophilic character. The HCLN composition, morphology and porous structure were analyzed using a multi-technique approach. The HCLN displayed a high surface area (above 1600 m2/g) and higher microporosity than the corresponding hyper-crosslinked neat resin. The enhanced adsorption properties of the HCLN towards polar organic dyes was demonstrated through the adsorption of a reactive dye, Remazol Brilliant Blue R (RB). In particular, the HCLN containing 5phr MSN showed the highest adsorption capacity of RB.

Synthesis and characterization of mesalamine silica nanoparticles

2021 ◽  
Vol 16 ◽  
Author(s):  
Balaji Maddiboyina ◽  
Ramya Krishna Nakkala ◽  
Prasanna Kumar Desu ◽  
Vikas Jhawat
Keyword(s):  
Particle Size ◽  
Silica Nanoparticles ◽  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
Silica Nanoparticle ◽  
Water Soluble ◽  
Infrared Spectrometry ◽  
Burst Release ◽  
Wide Range

Background: Nanoparticles made of silica are new materials that can be used in a wide range of drug delivery methods because they are biocompatible and biodegradable. Mesalamine, a classic water-soluble medication, remains loaded into the synthesized silica nanoparticle and is considered for sustained release proficiency. Precipitation approach using high surface area and pore volume tetraethyl orthosilicate yielded mesalamine-loaded silica nanoparticles. Methods: The drug-loaded nanoparticle was created and produced using two different techniques. Fourier transform infrared spectrometry, differential scanning calorimetry, X-ray powder diffraction, Brauer Emmett teller, scanning electron microscopy, particle size measurements, and dissolution investigations have all been used to analyse the substance in some way or another. Results: Because of the high surface area, well-known results like the complete silica nanoparticle created using method-2 remained mesoporous. The onset peak of the method-2 formulation's DSC was 182.27°c, and the offset peak was 192.14°c, consistent with the DSC results. The particle size range varies from 205-225nm. The results demonstrate that the uptake of the mesalamine by burst release it for 30 minutes initial, followed by sustained maintenance of dose even after 240 minutes. The results indicate that the loading process has an effect on the extent of loading. When silica nanoparticles were impregnated with mesalamine, the amount of the drug contained was significantly higher than when they were wetted. Conclusion: In addition, the XRD results show that both the pure mesalamine and the formulation did not show any polymorphic deviation.

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