Nanostructured 3D porous hybrid network of N-doped carbon, graphene and Si nanoparticles as an anode material for Li-ion batteries

2017 ◽  
Vol 41 (19) ◽  
pp. 10555-10560 ◽  
Author(s):  
Walid Alkarmo ◽  
Abdelhafid Aqil ◽  
Farid Ouhib ◽  
Jean-Michel Thomassin ◽  
Driss Mazouzi ◽  
...  

A facile and scalable process to prepare nanostructured 3D porous networks combining graphene, N-doped carbon and silicon nanoparticles (G@Si@C) as a promising anode material for lithium ion batteries.

2006 ◽  
Vol 78 (10) ◽  
pp. 1889-1896 ◽  
Author(s):  
Tao Zhang ◽  
Lijun Fu ◽  
Jie Gao ◽  
Lichun Yang ◽  
Yuping Wu ◽  
...  

We report an effective method for the synthesis of a core-shell Si/C nanocomposite, and its application as anode material for lithium ion (Li-ion) batteries. Polyacrylonitrile (PAN)-coated Si nanoparticles are formed by emulsion polymerization, and this precursor is heat-treated under argon to generate a Si/C core-shell nanocomposite. The conductive carbon shell envelops the silicon nanoparticles and suppresses aggregation of the nanoparticles during cycling. Meanwhile, the carbon shell combines closely with the nanocores, and significantly enhances the kinetics of lithium intercalation and de-intercalation, as well as the apparent diffusion coefficient of Li-ions. Consequently, the core-shell Si/C nanocomposite exhibits better electrochemical performance than pure Si nanoparticles, indicating that this is a promising approach to improve cyclability and kinetics of nano-anode materials for Li-ion batteries.


2019 ◽  
Vol 7 (5) ◽  
pp. 2106-2113 ◽  
Author(s):  
Gen-Cai Guo ◽  
Ru-Zhi Wang ◽  
Bang-Ming Ming ◽  
Changhao Wang ◽  
Si-Wei Luo ◽  
...  

C3N has attracted much attention as an anode material for lithium-ion (Li-ion) batteries, owing to its excellent mechanical and electronic properties.


RSC Advances ◽  
2015 ◽  
Vol 5 (29) ◽  
pp. 22449-22454 ◽  
Author(s):  
Tao Shen ◽  
Xufeng Zhou ◽  
Hailiang Cao ◽  
Chao Zheng ◽  
Zhaoping Liu

The TiO2(B)–CNT–graphene ternary composite, in which graphene and CNTs construct a highly efficient conductive network, exhibits excellent rate performance and cycling stability as an anode material for Li-ion batteries.


RSC Advances ◽  
2017 ◽  
Vol 7 (48) ◽  
pp. 30032-30037 ◽  
Author(s):  
Hui Zhang ◽  
Hui Xu ◽  
Hong Jin ◽  
Chao Li ◽  
Yu Bai ◽  
...  

A novel 3-dimensional (3D) flower-like silicon/carbon composite was synthesized through spray drying method by using NaCl as the sacrificial reagent and was evaluated as an anode material for lithium ion batteries.


Nanoscale ◽  
2015 ◽  
Vol 7 (16) ◽  
pp. 7065-7071 ◽  
Author(s):  
Kuldeep Rana ◽  
Seong Dae Kim ◽  
Jong-Hyun Ahn

This work demonstrates a simple route to develop mechanically flexible electrodes for Li-ion batteries (LIBs) that are usable as lightweight effective conducting networks for both cathodes and anodes.


2017 ◽  
Vol 5 (15) ◽  
pp. 7026-7034 ◽  
Author(s):  
Min Zhu ◽  
Jie Yang ◽  
Zhihao Yu ◽  
Haibiao Chen ◽  
Feng Pan

A Si/SiOx@C nanocomposite was synthesized from a silicone precursor and used as an effective anode material for Li-ion batteries.


2018 ◽  
Vol 6 (2) ◽  
pp. 443-455 ◽  
Author(s):  
Alois Kuhn ◽  
Juan Carlos Pérez-Flores ◽  
Markus Hoelzel ◽  
Carsten Baehtz ◽  
Isabel Sobrados ◽  
...  

Sodium hexatitanate Na2Ti6O13 with a tunnel structure has been proposed to be an attractive anode material for lithium ion batteries because of its low insertion voltage, structural stability and good reversibility.


2020 ◽  
Vol 22 (16) ◽  
pp. 8902-8912 ◽  
Author(s):  
Xiaodong Lv ◽  
Fengyu Li ◽  
Jian Gong ◽  
Jinxing Gu ◽  
Shiru Lin ◽  
...  

By means of density functional theory computations, we explored the electrochemical performance of an FeSe monolayer as an anode material for lithium and non-lithium ion batteries (LIBs and NLIBs).


2014 ◽  
Vol 2014 ◽  
pp. 1-6 ◽  
Author(s):  
Yong Chen ◽  
Xuejun Zhang ◽  
Yanhong Tian ◽  
Xi Zhao

Silicon nanoparticles have been successfully inserted into graphene sheets via a novel method combining freeze-drying and thermal reduction. The structure, electrochemical performance, and cycling stability of this anode material were characterized by SEM, X-ray diffraction (XRD), charge/discharge cycling, and cyclic voltammetry (CV). CV showed that the Si/graphene nanocomposite exhibits remarkably enhanced cycling performance and rate performance compared with bare Si nanoparticles for lithium ion batteries. XRD and SEM showed that silicon nanoparticles inserted into graphene sheets were homogeneous and had better layered structure than the bare silicon nanoparticles. Graphene sheets improved high rate discharge capacity and long cycle-life performance. The initial capacity of the Si nanoparticles/graphene keeps above 850 mAhg−1after 100 cycles at a rate of 100 mAg−1. The excellent cycle performances are caused by the good structure of the composites, which ensured uniform electronic conducting sheet and intensified the cohesion force of binder and collector, respectively.


2015 ◽  
Vol 3 (29) ◽  
pp. 15274-15279 ◽  
Author(s):  
Yi Feng ◽  
Xiaodan Li ◽  
Zongping Shao ◽  
Huanting Wang

The performance of Zn2GeO4 nanostructures in Li ion batteries was studied and the hollow structure showed enhanced performance.


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