Structural and thermodynamic investigation of AnIVLI(O)HOPO

2017 ◽  
Vol 41 (19) ◽  
pp. 11291-11298 ◽  
Author(s):  
J. Aupiais ◽  
A. Younes ◽  
P. Moisy ◽  
C. Hennig ◽  
A. Rossberg ◽  
...  

For the first time, capillary electrophoresis coupled with inductively coupled plasma mass spectrometry has been used to determine the stability constants of PuIV with the multidentate hydroxypyridinonate chelating agents LI(O)HOPO in 0.1 M NaNO3 solution, pcH = 1.395 at 25 °C through competition with the NTA ligand.

2020 ◽  
Vol 35 (3) ◽  
pp. 455-460 ◽  
Author(s):  
Eduardo Bolea-Fernandez ◽  
Ana Rua-Ibarz ◽  
Milica Velimirovic ◽  
Kristof Tirez ◽  
Frank Vanhaecke

The occurrence of microplastics (MPs) in the environment is a matter of increasing concern. In this work, it has been shown for the first time that ICP-MS operated in single-event mode can be used for the characterization of MPs relying on their C content.


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