Synthesis and comparative charge transfer studies in porphyrin–fullerene dyads: mode of attachment effect

2017 ◽  
Vol 41 (22) ◽  
pp. 13276-13286 ◽  
Author(s):  
Neha Gupta ◽  
Chhavi Sharma ◽  
Mahesh Kumar ◽  
Rachana Kumar

Two types of dyads having different modes of attachment i.e. cyclopropanation vs. pyrrolidine type in porphyrin–fullerene linked systems are compared for their photophysical properties. Dyad II with pyrrolidine type of linkage shows faster charge separation and generation of long lived charge separated states. It also shows a new property of thermally activated electrical conductivity which makes it potential candidate for organic electronic devices.

2011 ◽  
Vol 12 (3) ◽  
pp. 520-528 ◽  
Author(s):  
Toshinori Matsushima ◽  
Guang-He Jin ◽  
Yoshihiro Kanai ◽  
Tomoyuki Yokota ◽  
Seiki Kitada ◽  
...  

Nanophotonics ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 31-40
Author(s):  
Stephen R. Forrest

AbstractOrganic light-emitting diode (OLED) displays are now poised to be the dominant mobile display technology and are at the heart of the most attractive televisions and electronic tablets on the market today. But this begs the question: what is the next big opportunity that will be addressed by organic electronics? We attempt to answer this question based on the unique attributes of organic electronic devices: their efficient optical absorption and emission properties, their ability to be deposited on ultrathin foldable, moldable and bendable substrates, the diversity of function due to the limitless palette of organic materials and the low environmental impact of the materials and their means of fabrication. With these unique qualities, organic electronics presents opportunities that range from lighting to solar cells to medical sensing. In this paper, we consider the transformative changes to electronic and photonic technologies that might yet be realized using these unconventional, soft semiconductor thin films.


2009 ◽  
Vol 95 (23) ◽  
pp. 233305 ◽  
Author(s):  
Richard R. Lunt ◽  
Brian E. Lassiter ◽  
Jay B. Benziger ◽  
Stephen R. Forrest

2013 ◽  
Vol 44 (1) ◽  
pp. 427-430 ◽  
Author(s):  
Markus Burghart ◽  
Andreas Dutkowiak ◽  
Lutz Tandler ◽  
Jörk Richter ◽  
Georg Haasemann ◽  
...  

2017 ◽  
Vol 13 ◽  
pp. 2273-2296 ◽  
Author(s):  
Satoru Mori ◽  
Norio Shibata

Phthalocyanines and subphthalocyanines are attracting attention as functional dyes that are applicable to organic solar cells, photodynamic therapy, organic electronic devices, and other applications. However, phthalocyanines are generally difficult to handle due to their strong ability to aggregate, so this property must be controlled for further applications of phthalocyanines. On the other hand, trifluoroethoxy-substituted phthalocyanines are known to suppress aggregation due to repulsion of the trifluoroethoxy group. Furthermore, the electronic characteristics of phthalocyanines are significantly changed by the strong electronegativity of fluorine. Therefore, it is expected that trifluoroethoxy-substituted phthalocyanines can be applied to new industrial fields. This review summarizes the synthesis and application of trifluoroethoxy-substituted phthalocyanine and subphthalocyanine derivatives.


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