In operando X-ray diffraction of lithium–oxygen batteries using an ionic liquid as an electrolyte co-solvent

2017 ◽  
Vol 41 (15) ◽  
pp. 7267-7272 ◽  
Author(s):  
E. Knipping ◽  
C. Aucher ◽  
G. Guirado ◽  
F. Fauth ◽  
L. Aubouy
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Lithium Metal ◽  
X Ray Diffraction ◽  
X Ray ◽  
Chemical Instability ◽  
In Operando ◽  
Lithium Oxygen Batteries

Chemical instability of ionic liquids in the presence of lithium metal leading to spontaneous LiOH formation.

Electrodeposition of Cu2ZnSnS4 Thin Films Using Ionic Liquids

2008 ◽  
Vol 1123 ◽  
Author(s):  
C.P. Chan ◽  
H. Lam ◽  
K.Y. Wong ◽  
C. Surya
Keyword(s):  
Thin Films ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Grain Orientation ◽  
Absorption Measurement ◽  
Elementary Sulfur ◽  
Sulfur Vapor ◽  
X Ray Diffraction ◽  
X Ray ◽  
Czts Thin Films

AbstractWe report the growth of Cu2ZnSnS4 (CZTS) thin films by electrodeposition in ionic liquid. Sulfurization was performed in elementary sulfur vapor environment at 450°C for 2 hours. The X-ray diffraction analysis indicated that the film has a stannite structure with preferred grain orientation along (112). Photo-absorption measurement of the sample was performed from 500 nm to 990 nm. It is found that the energy bandgap of the film is about 1.49eV and the absorption coefficient is found to be of the order of 104cm-1.

A 3D free-standing lithiophilic silver nanowire aerogel for lithium metal batteries without lithium dendrites and volume expansion: in operando X-ray diffraction

2019 ◽  
Vol 55 (40) ◽  
pp. 5689-5692 ◽  
Author(s):  
Nutthaphon Phattharasupakun ◽  
Juthaporn Wutthiprom ◽  
Salatan Duangdangchote ◽  
Montree Sawangphruk
Keyword(s):  
Dendritic Growth ◽  
Silver Nanowire ◽  
Lithium Metal ◽  
X Ray Diffraction ◽  
Free Standing ◽  
X Ray ◽  
Lithium Metal Batteries ◽  
Initial Nucleation ◽  
Lithium Dendrites ◽  
In Operando

A 3D free-standing lithiophilic silver nanowire aerogel (AgNWA) can stop the dendritic growth of lithium metal at the initial nucleation process.

X-Ray diffraction and resonance shear measurement of nano-confined ionic liquids

2018 ◽  
Vol 20 (20) ◽  
pp. 13714-13721 ◽  
Author(s):  
Kazuhito Tomita ◽  
Masashi Mizukami ◽  
Shinya Nakano ◽  
Noboru Ohta ◽  
Naoto Yagi ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
X Ray Diffraction ◽  
X Ray ◽  
Silica Surfaces ◽  
Nanometer Thickness ◽  
Lubrication Properties

The X-ray diffraction and resonance shear measurement (RSM) demonstrated the relation between the structure and lubrication properties of ionic liquid ([C4mim][NTf2], [C4mim][BF4]) films of nanometer thickness confined between silica surfaces.

STRUCTURAL AND ELECTROCHEMICAL PROPERTIES OF THIN LAYERS OF BINARY Ni–Fe ALLOYS ELECTRODEPOSITED BY TWO DIFFERENT BATHS: ACID AND IONIC LIQUID

2018 ◽  
Vol 25 (08) ◽  
pp. 1950025
Author(s):  
RAFIK MAIZI ◽  
ATHMANE MEDDOUR ◽  
CÉLINE ROUSSE
Keyword(s):  
Ionic Liquid ◽  
Nickel Content ◽  
Deposition Potential ◽  
Thin Layers ◽  
X Ray Diffraction ◽  
Sem Images ◽  
X Ray ◽  
Different Shapes ◽  
Fe Alloys ◽  
Irregular Behavior

The deposition of Ni–Fe thin layers in boric acid and ionic liquid ([BuMePyr][Tf2N]) baths were successfully prepared. The obtained materials have been characterized by X-ray diffraction (XRD), Energy Dispersive X-ray spectroscopy (EDX) and SEM. Meanwhile, these materials were carried out by chronoamperometry or chronopotentiometry by varying the intensity of the current and the deposition potential. The results indicate that the coatings of Ni–Fe alloys were successfully obtained by electroplating on the copper substrates, and the alloys composition shows irregular behavior with polarization. The nickel content in the samples is in the range of 55–90%, but the iron content ranges from 10–30%, when potential deposits were varied from [Formula: see text]2[Formula: see text]V to [Formula: see text]4[Formula: see text]V vs Ni electrode. The results also showed that the thin layers are monophased; they contain the Ni3Fe phase. Further, SEM images of Ni–Fe alloys show the different shapes of particles.

Improved Enzymatic Depolymerization of Chitosan by Ionic Liquid Pretreatment and the Effect of Oligo-Chitosan on Intestinal Flora In Vitro

2011 ◽  
Vol 391-392 ◽  
pp. 1319-1323
Author(s):  
Cui Zheng ◽  
Lin Li ◽  
Hao Pang ◽  
Zhao Mei Wang ◽  
Na Li
Keyword(s):  
Ionic Liquid ◽  
Hydrogen Bonds ◽  
Molecular Hydrogen ◽  
Intestinal Flora ◽  
X Ray Diffraction ◽  
X Ray ◽  
Hydrolysis Of ◽  
Positive Effect ◽  
Enzymatic Depolymerization

It still remains challenging for effective hydrolysis of chitosan into chitosan oligomers. In this work, a pretreatment was conducted on chitosan by an ionic liquid 1-butyl-3-methylimidazolium chloride ([C4mim]Cl), aiming at improving enzymatic depolymerization of chitosan. X-ray diffraction analysis indicated that the inter- and intra-molecular hydrogen bonds within chitosan molecules were broken by [C4mim]Cl and the crystalline was destroyed. The oligo-chitosan hydrolyzed from IL-pretreated chitosan, coded as COS-IL, showed a DP of 3~5, in contrast to DP 5~8 with oligo-chitosan obtained from untreated chitosan(coded as COS-UN). COS-IL was more effective than COS-UN in inhibiting intestinal spoilage bacterials growth and it has positive effect on the growth of intestinal probiotic bacterials.

Synthesis of Nickel Hydroxide with Different Morphologies Using an Ionic Liquid

2010 ◽  
Vol 663-665 ◽  
pp. 1163-1166
Author(s):  
Cun Ying Xu ◽  
Yi Xin Hua
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Ionic Liquid ◽  
Volume Ratio ◽  
X Ray Diffraction ◽  
X Ray ◽  
Reaction Media ◽  
Solvothermal Conditions ◽  
Facile Route ◽  
Scanning Electron

A new and facile route has been developed to synthesize β-Ni(OH)2 nanostructures using ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate ([Bmim]BF4) as reaction media under solvothermal conditions. The β-Ni(OH)2 with different morphologies, such as nanoflakes, nanoplatelet and nanorods, can be obtained by controlling the volume ratio of the ionic liquid to water and reaction temperature. The as-prepared products were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM).

Synthesis, Characterization, and Crystal Structure of Several Novel Acidic Ionic Liquids: 1-ethyl-2-alkyl-benzimidazolium Tetra-Fluoroborate

2013 ◽  
Vol 457-458 ◽  
pp. 139-143 ◽  
Author(s):  
Ming Tian Wang ◽  
Chang Ping Pan ◽  
Wei Peng Gai ◽  
Xiao Xia Lv ◽  
Min Gang Zhai ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Ionic Liquid ◽  
Acetic Acid ◽  
Catalytic Activity ◽  
Lamellar Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
Acidic Ionic Liquid ◽  
Acidic Ionic Liquids ◽  
Good Catalytic Activity

A series of novel acidic ionic liquid: 1-ethyl-2-alkyl-benzimidazolium tetra-fluoroborate (alkyl= Et, Pr-n, Bu-n) were prepared by simple acid-based neutralization of 1-ethyl-2-alkyl-benzimidazole and tetrafluoroboric acid. The compounds were characterized by FTIR spectra, elemental analysis,1HNMR spectra and thermogravimetric analysis. These novel tetra-fluoroborate salts show good catalytic activity to esterification of benzyl alcohol and acetic acid. Furthermore, a crystal of ([H-ebBiBF4) was prepared with the crystal structure and determined by X-ray diffraction analysis. The molecular is of lamellar structure as mainly π electron ring is stacked interleaving between two layers. The results of cation and anion arranged orderly in pair indicate that the coulombic attraction is more dominant. Simultaneously, the weak local hydrogen bonds C-H···F exist in the molecules.

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