Importance of C–H⋯π interactions in stabilizing the syn/anti arrangement of pendant alkoxy side arms in two manganese(iv) Schiff base complexes: exploration of catechol oxidase and phenoxazinone synthase like activities

2017 ◽  
Vol 41 (16) ◽  
pp. 8053-8065 ◽  
Author(s):  
Nandita Sarkar ◽  
Klaus Harms ◽  
Antonio Frontera ◽  
Shouvik Chattopadhyay
Keyword(s):  
Schiff Base ◽  
Schiff Base Complexes ◽  
Catechol Oxidase ◽  
Π Interactions ◽  
Phenoxazinone Synthase

Two manganese(iv) complexes have been prepared and characterized. Both complexes exhibit catechol oxidase and phenoxazinone synthase like activities.

Synthesis, Characterization, DFT Study, Catechol Oxidase and Phenoxazinone Synthase Like Activities of Two New Manganese(IV) Schiff Base Complexes

2017 ◽  
Vol 2 (10) ◽  
pp. 2975-2984 ◽  
Author(s):  
Nandita Sarkar ◽  
Klaus Harms ◽  
Antonio Bauzá ◽  
Antonio Frontera ◽  
Shouvik Chattopadhyay
Keyword(s):  
Schiff Base ◽  
Schiff Base Complexes ◽  
Dft Study ◽  
Catechol Oxidase ◽  
Phenoxazinone Synthase

scholarly journals Unique mononuclear MnIIcomplexes of an end-off compartmental Schiff base ligand: experimental and theoretical studies on their bio-relevant catalytic promiscuity

2016 ◽  
Vol 45 (31) ◽  
pp. 12409-12422 ◽  
Author(s):  
Jaydeep Adhikary ◽  
Aratrika Chakraborty ◽  
Sanchari Dasgupta ◽  
Shyamal Kumar Chattopadhyay ◽  
Rafał Kruszynski ◽  
...  
Keyword(s):  
Schiff Base ◽  
Schiff Base Ligand ◽  
Schiff Base Complexes ◽  
Theoretical Studies ◽  
Catalytic Promiscuity ◽  
Phenoxazinone Synthase ◽  
Experimental And Theoretical Studies

MnIISchiff base complexes have been experimentally and theoretically studied for their catecholase and phenoxazinone synthase activity.

Exploration of CH⋯π interactions involving the π-system of pseudohalide coligands in metal complexes of a Schiff-base ligand

CrystEngComm ◽  
2015 ◽  
Vol 17 (25) ◽  
pp. 4680-4690 ◽  
Author(s):  
Prateeti Chakraborty ◽  
Suranjana Purkait ◽  
Sandip Mondal ◽  
Antonio Bauzá ◽  
Antonio Frontera ◽  
...  
Keyword(s):  
Schiff Base ◽  
Metal Complexes ◽  
Schiff Base Ligand ◽  
Self Assembly ◽  
The Self ◽  
Schiff Base Complexes ◽  
Π Interactions ◽  
Non Covalent Interactions ◽  
Covalent Interactions

The role of non-covalent interactions in the self-assembly of Schiff-base complexes of ZnII, CuII and NiII has been investigated experimentally and theoretically with especial attention to unconventional C–H⋯π interactions involving pseudohalide coligands.

Synthesis, characterization and catechol oxidase mimicking activity of two iron(III) schiff base complexes

Polyhedron ◽  
2018 ◽  
Vol 146 ◽  
pp. 81-92 ◽  
Author(s):  
Tanmoy Basak ◽  
Kousik Ghosh ◽  
Shouvik Chattopadhyay
Keyword(s):  
Schiff Base ◽  
Schiff Base Complexes ◽  
Catechol Oxidase

Synthesis of Mn3O4 nanozymes from structurally characterized phenoxazinone synthase models based on manganese(iii) Schiff base complexes

2020 ◽  
Vol 49 (18) ◽  
pp. 5999-6011 ◽  
Author(s):  
Arnab Mandal ◽  
Sanchari Dasgupta ◽  
Amit Adhikary ◽  
Debabrata Samanta ◽  
Ennio Zangrando ◽  
...  
Keyword(s):  
Schiff Base ◽  
Schiff Base Complexes ◽  
Phenoxazinone Synthase

Mn3O4 nanozymes of phenoxazinone synthase have been prepared from the manganese(iii) based mimicking models of the enzyme.

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