A heterogenized chiral imino indanol complex of manganese as an efficient catalyst for aerobic epoxidation of olefins

2017 ◽  
Vol 41 (18) ◽  
pp. 9866-9874 ◽  
Author(s):  
Vahideh Abbasi ◽  
Hassan Hosseini-Monfared ◽  
Seyed Majid Hosseini

A new composite was synthesized by grafting the (1R,2S)-1-(N-salicylideneamino)-2-indanol complex of Mn onto graphene oxide/Fe3O4@C. It catalysed the aerobic epoxidation of olefins with a selectivity of >98% and enantioselectivity of >99%.

2016 ◽  
Vol 40 (3) ◽  
pp. 2280-2286 ◽  
Author(s):  
Ali Zarnegaryan ◽  
Majid Moghadam ◽  
Shahram Tangestaninejad ◽  
Valiollah Mirkhani ◽  
Iraj Mohammdpoor-Baltork

Alkene epoxidation with tert-butyl hydroperoxide catalyzed by the Cu(ii) dithiol complex supported on graphene oxide is reported.


2017 ◽  
Vol 41 (24) ◽  
pp. 15545-15554 ◽  
Author(s):  
Charu Garkoti ◽  
Javaid Shabir ◽  
Padmini Gupta ◽  
Manisha Sharma ◽  
Subho Mozumdar

Heterogenization of amine functionalized ionic liquid and its application as an efficient and recyclable catalyst.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Rabindranath Singha ◽  
Aminul Islam ◽  
Pranab Ghosh

AbstractA convenient and efficient solvent-free, facile, one-pot three-component graphene oxide catalysed approach has been described for the synthesis of chromeno-[4,3-b]quinolin-6-one derivatives from 4-hydroxycoumarin with aldehydes and aromatic amines. Graphene oxide (GO) has proved to be a new class of heterogeneous carbocatalyst which could be easily recovered and reused up to 5th run without significant loss of its catalytic activity. A broad scope of substrate applicability is offered and a plausible mechanism is also suggested for this developed protocol.


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