Aggregation-induced emission (AIE) characteristic of water-soluble tetraphenylethene (TPE) bearing four sulfonate salts

2017 ◽  
Vol 41 (12) ◽  
pp. 4747-4749 ◽  
Author(s):  
Yousuke Ooyama ◽  
Michitaka Sugino ◽  
Toshiaki EnoKi ◽  
Kazuki Yamamoto ◽  
Nao Tsunoji ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Organic Solvent ◽  
Water Soluble ◽  
Aggregation Induced Emission ◽  
Sulfonate Salts

Aggregation-induced emission (AIE) characteristic of water-soluble tetraphenylethene (WS-TPE), was investigated by the addition of organic solvent into WS-TPE aqueous solution.

The Effects of Organic Solvent on the Electrospinning of Water-Soluble Polyacrylamide with Ultrahigh Molecular Weight

2007 ◽  
Vol 121-123 ◽  
pp. 113-116
Author(s):  
Yi Yang Zhao ◽  
X. Li ◽  
C. Wang ◽  
L.J. Li
Keyword(s):  
Electron Microscopy ◽  
Aqueous Solution ◽  
Molecular Weight ◽  
Scanning Electron Microscopy ◽  
Organic Solvent ◽  
Colloidal Particles ◽  
Water Soluble ◽  
Ultrahigh Molecular Weight ◽  
Scanning Electron

The effects of an organic solvent on the electrospinning of water-soluble polyacrylamide with ultrahigh molecular weight were investigated. An organic solvent, DMF, was introduced to the polyacrylamide aqueous solution and subsequently, transparent spinning solutions were obtained. The spinning solution was electrospun at the voltage of 10 kV and the electrospun products were examined by scanning electron microscopy (SEM). Results indicated that all the electrospinning products including colloidal particles, beaded fibers and smooth fibers were fabricated in the DMF/H2O bi-component solvent and the morphology of electrospun products changed from smooth fiber to beaded fiber with the increasing amount of DMF used.

Dual crosslinked polyamidoxime/alginate sponge for robust and efficient uranium adsorption from aqueous solution

2020 ◽  
Vol 44 (45) ◽  
pp. 19445-19449
Author(s):  
Caina Han ◽  
Yaru Yue ◽  
Xin Xu ◽  
Dong Cai ◽  
Zhongjie Liu ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Organic Solvent ◽  
Low Cost ◽  
Solvent Free ◽  
Water Soluble ◽  
Uranium Adsorption ◽  
Highly Efficient ◽  
Efficient Extraction ◽  
Uranium From Seawater

A facile, low-cost, organic solvent-free fabrication strategy is developed to prepare a seawater-stable sponge adsorbent from a water-soluble precursor for highly efficient extraction of uranium from seawater and uranium-containing wastewater.

Aggregation-induced emission properties of hydrothermally synthesized Cu–In–S quantum dots

2017 ◽  
Vol 53 (23) ◽  
pp. 3357-3360 ◽  
Author(s):  
Mingyao Mou ◽  
Yi Wu ◽  
Qianqian Niu ◽  
Yuanqi Wang ◽  
Zhengyu Yan ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Organic Solvent ◽  
Water Soluble ◽  
Aggregation Induced Emission ◽  
Emission Properties

This article reports water-soluble Cu–In–S QDs with aggregation-induced emission (AIE) properties that can be induced by both an organic solvent and cations.

Enantioselective Recognition of Chiral Guests by the Water-Soluble Chiral Keplerate {Mo132} Spherical Capsule with 30 Inner Lactate Ligands

2019 ◽  
Author(s):  
Nancy Watfa ◽  
Weimin Xuan ◽  
Zoe Sinclair ◽  
Robert Pow ◽  
Yousef Abul-Haija ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Chiral Recognition ◽  
Association Constants ◽  
Water Soluble ◽  
Enantioselective Recognition ◽  
H Nmr ◽  
Dosy Nmr ◽  
Spherical Capsule ◽  
Surface Pores ◽  
Guest Chemistry

Investigations of chiral host guest chemistry are important to explore recognition in confined environments. Here, by synthesizing water-soluble chiral porous nanocapsule based on the inorganic metal-oxo Keplerate-type cluster, {Mo<sub>132</sub>} with chiral lactate ligands with the composition [Mo<sub>132</sub>O<sub>372</sub>(H<sub>2</sub>O)<sub>72</sub>(<i>x-</i>Lactate)<sub>30</sub>]<sup>42-</sup> (<i>x</i> = D or L), it was possible to study the interaction with a chiral guest, L/D-carnitine and (<i>R</i>/<i>S</i>)-2-butanol in aqueous solution. The enantioselective recognition was studied by quantitative <sup>1</sup>H NMR and <sup>1</sup>H DOSY NMR which highlighted that the chiral recognition is regulated by two distinct sites. Differences in the association constants (K) of L- and D-carnitine, which, due to their charge, are generally restricted from entering the interior of the host, are observed, indicating that their recognition predominantly occurs at the surface pores of the structure. Conversely, a larger difference in association constants (K<i><sub>S</sub></i>/K<i><sub>R</sub></i> = 3) is observed for recognition within the capsule interior of (<i>R</i>)- and (<i>S</i>)-2-butanol.

scholarly journals Sulfobetaine Cryogels for Preferential Adsorption of Methyl Orange from Mixed Dye Solutions

Polymers ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 208
Author(s):  
Ramona B. J. Ihlenburg ◽  
Anne-Catherine Lehnen ◽  
Joachim Koetz ◽  
Andreas Taubert
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Methyl Orange ◽  
Dye Removal ◽  
Selective Adsorption ◽  
Water Soluble ◽  
Organic Substances ◽  
Preferential Adsorption ◽  
Dimethyl Ammonium ◽  
Dye Solutions

New cryogels for selective dye removal from aqueous solution were prepared by free radical polymerization from the highly water-soluble crosslinker N,N,N’,N’-tetramethyl-N,N’-bis(2-ethylmethacrylate)-propyl-1,3-diammonium dibromide and the sulfobetaine monomer 2-(N-3-sulfopropyl-N,N-dimethyl ammonium)ethyl methacrylate. The resulting white and opaque cryogels have micrometer sized pores with a smaller substructure. They adsorb methyl orange (MO) but not methylene blue (MB) from aqueous solution. Mixtures of MO and MB can be separated through selective adsorption of the MO to the cryogels while the MB remains in solution. The resulting cryogels are thus candidates for the removal of hazardous organic substances, as exemplified by MO and MB, from water. Clearly, it is possible that the cryogels are also potentially interesting for removal of other compounds such as pharmaceuticals or pesticides, but this must be investigated further.

scholarly journals Efficient Lipid Bilayer Formation by Dipping Lipid-Loaded Microperforated Sheet in Aqueous Solution

Micromachines ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 53
Author(s):  
Nobuo Misawa ◽  
Satoshi Fujii ◽  
Koki Kamiya ◽  
Toshihisa Osaki ◽  
Shoji Takeuchi
Keyword(s):  
Aqueous Solution ◽  
Membrane Protein ◽  
Organic Solvent ◽  
Lipid Membrane ◽  
Coating Layer ◽  
Bilayer Lipid Membrane ◽  
Contact Method ◽  
Electrical Measurements ◽  
Droplet Interface Bilayer ◽  
Perforated Sheet

This paper describes a method for a bilayer lipid membrane (BLM) formation using a perforated sheet along with an open chamber. Microscopic observation of the formed membrane showed a typical droplet interface bilayer. We proved that the formed membrane was a BLM based on electrical measurements of the membrane protein α-hemolysin, which produces nanopores in BLMs. Unlike the conventional approach for BLM formation based on the droplet contact method, this method provides aqueous surfaces with no organic solvent coating layer. Hence, this method is suitable for producing BLMs that facilitate the direct addition of chemicals into the aqueous phase.

Facile fractionation of bamboo hydrolysate and characterization of isolated lignin and lignin-carbohydrate complexes

Holzforschung ◽  
2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Xiaodi Wang ◽  
Yongchao Zhang ◽  
Luyao Wang ◽  
Xiaoju Wang ◽  
Qingxi Hou ◽  
...  
Keyword(s):  
Solvent Extraction ◽  
Organic Solvent ◽  
Extraction Process ◽  
Water Soluble ◽  
Organic Solvent Extraction ◽  
Glycoside Linkage ◽  
Potential Applications ◽  
Tremendous Amount ◽  
Main Components ◽  
Hemicellulosic Sugars

AbstractAn efficient separation technology for hydrolysates towards a full valorization of bamboo is still a tough challenge, especially regarding the lignin and lignin-carbohydrate complexes (LCCs). The present study aimed to develop a facile approach using organic solvent extraction for efficiently fractionating the main components of bamboo hydrolysates. The high-purity lignin with only a trace of carbohydrates was first obtained by precipitation of the bamboo hydrolysate. The water-soluble lignin (WSL) fraction was extracted in organic solvent through a three-stage organic solvent extraction process, and the hemicellulosic sugars with increased purity were also collected. Furthermore, a thorough characterization including various NMR techniques (31P, 13C, and 2D-HSQC), GPC, and GC-MS was conducted to the obtained lignin-rich-fractions. It was found that the WSL fraction contained abundant functional groups and tremendous amount of LCC structures. As compared to native LCC of bamboo, the WSL fraction exhibited more typical LCC linkages, i.e. phenyl glycoside linkage, which is the main type of chemical linkage between lignin and carbohydrate in both LCC samples. The results demonstrate that organic phase extraction is a highly efficient protocol for the fractionation of hydrolysate and the isolation of LCC-rich streams possessing great potential applications.

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