scholarly journals Metal organic frameworks as catalysts in solvent-free or ionic liquid assisted conditions

2018 ◽  
Vol 20 (1) ◽  
pp. 86-107 ◽  
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Abdullah M. Asiri ◽  
Mercedes Alvaro ◽  
Hermenegildo Garcia
Keyword(s):  
Ionic Liquid ◽  
Critical Review ◽  
Metal Organic Frameworks ◽  
Solvent Free ◽  
Solid Catalysts ◽  
Metal Organic

This Critical Review describes the use of Metal Organic Frameworks as Solid Catalysts under Solvent-Free or Ionic Liquid Assisted conditions.

Metal–organic frameworks as solid catalysts for the synthesis of nitrogen-containing heterocycles

2014 ◽  
Vol 43 (16) ◽  
pp. 5750-5765 ◽  
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Hermenegildo Garcia
Keyword(s):  
Critical Review ◽  
Metal Organic Frameworks ◽  
Solid Catalysts ◽  
Recent Developments ◽  
Metal Organic

This Critical Review summarizes the recent developments in the use of metal–organic frameworks as catalysts for the synthesis of nitrogen-containing heterocycles.

A direct solvent-free conversion approach to prepare mixed-metal metal–organic frameworks from doped metal oxides

2021 ◽  
Vol 57 (29) ◽  
pp. 3587-3590
Author(s):  
Beili Yi ◽  
Haojie Zhao ◽  
Yue Zhang ◽  
Xiaomeng Si ◽  
Guanqun Zhang ◽  
...  
Keyword(s):  
Metal Oxides ◽  
Metal Organic Frameworks ◽  
Solvent Free ◽  
Mixed Metal ◽  
Synthesis Strategy ◽  
Metal Metal ◽  
Metal Organic

We propose a novel solvent-free conversion strategy of Pt–ZnO to Pt-ZIF-8. This synthesis strategy may facilitate the discovery of MMOFs that have not been reported previously.

Structural Design of Mn-Metal–Organic Frameworks toward Highly Efficient Solvent-Free Cycloaddition of CO2

2021 ◽  
Author(s):  
Haonan Lin ◽  
Cheng-Hua Deng ◽  
Xiaohang Qiu ◽  
Xiao Liu ◽  
Jian-Gong Ma ◽  
...  
Keyword(s):  
Structural Design ◽  
Metal Organic Frameworks ◽  
Solvent Free ◽  
Highly Efficient ◽  
Metal Organic

scholarly journals Cobalt-Based Metal Organic Frameworks as Solids Catalysts for Oxidation Reactions

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 95
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Eva Montero Lanzuela ◽  
Sergio Navalon ◽  
Hermenegildo Garcia
Keyword(s):  
Aerobic Oxidation ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
High Surface Area ◽  
Acid Sites ◽  
Crystalline Lattice ◽  
Oxidation Reactions ◽  
Solid Catalysts ◽  
Long Term Stability ◽  
Metal Organic

Metal organic frameworks (MOFs) are porous crystalline solids whose frameworks are constituted by metal ions/nodes with rigid organic linkers leading to the formation of materials having high surface area and pore volume. One of the unique features of MOFs is the presence of coordinatively unsaturated metal sites in their crystalline lattice that can act as Lewis acid sites promoting organic transformations, including aerobic oxidation reactions of various substrates such as hydrocarbons, alcohols, and sulfides. This review article summarizes the existing Co-based MOFs for oxidation reactions organized according to the nature of substrates like hydrocarbon, alcohol, olefin, and water. Both aerobic conditions and peroxide oxidants are discussed. Emphasis is placed on comparing the advantages of using MOFs as solid catalysts with respect to homogeneous salts in terms of product selectivity and long-term stability. The final section provides our view on future developments in this field.

scholarly journals Mechanochemical and solvent-free assembly of zirconium-based metal–organic frameworks

2016 ◽  
Vol 52 (10) ◽  
pp. 2133-2136 ◽  
Author(s):  
Krunoslav Užarević ◽  
Timothy C. Wang ◽  
Su-Young Moon ◽  
Athena M. Fidelli ◽  
Joseph T. Hupp ◽  
...  
Keyword(s):  
Solid State ◽  
High Temperatures ◽  
Self Assembly ◽  
Metal Organic Frameworks ◽  
Accelerated Aging ◽  
Solvent Free ◽  
Catalytically Active ◽  
Metal Organic ◽  
Strong Acids ◽  
Zirconium Metal

Mechanochemistry and accelerated aging are new routes to zirconium metal–organic frameworks, yielding UiO-66 and catalytically active UiO-66-NH2 accessible on the gram scale through mild solid-state self-assembly, without strong acids, high temperatures or excess reactants.

Ionic Liquid-Assisted Exfoliation of Two-Dimensional Metal–Organic Frameworks for Luminescent Sensing

2020 ◽  
Vol 8 (5) ◽  
pp. 2167-2175 ◽  
Author(s):  
Dongyin Liu ◽  
Bing Liu ◽  
Chan Wang ◽  
Wei Jin ◽  
Qijun Zha ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Metal Organic Frameworks ◽  
Two Dimensional ◽  
Metal Organic ◽  
Luminescent Sensing

Efficient Solvent-Free Carbon Dioxide Fixation Reactions with Epoxides Under Mild Conditions by Mixed-Ligand Zinc(II) Metal-Organic Frameworks

ChemCatChem ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 2401-2408 ◽  
Author(s):  
Parth Patel ◽  
Bhavesh Parmar ◽  
Rukhsana I. Kureshy ◽  
Noor-ul Khan ◽  
Eringathodi Suresh
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Frameworks ◽  
Carbon Dioxide Fixation ◽  
Mixed Ligand ◽  
Free Carbon ◽  
Solvent Free ◽  
Mild Conditions ◽  
Free Carbon Dioxide ◽  
Metal Organic

Novel Solvent-Free Energetic 3D Metal-Organic Frameworks and Their Laser Response

2021 ◽  
pp. 134296
Author(s):  
Wenjia Hao ◽  
Bo Jin ◽  
Liqiong Luo ◽  
Quancheng Liu ◽  
Hu Deng ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Solvent Free ◽  
Metal Organic
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