Efficient synthesis of acetic acid via Rh catalyzed methanol hydrocarboxylation with CO2 and H2 under milder conditions

2017 ◽  
Vol 19 (15) ◽  
pp. 3558-3565 ◽  
Author(s):  
Meng Cui ◽  
Qingli Qian ◽  
Jingjing Zhang ◽  
Chunjun Chen ◽  
Buxing Han
Keyword(s):  
Acetic Acid ◽  
Efficient Synthesis ◽  
Monometallic Catalyst

Acetic acid can be efficiently synthesized via methanol hydrocarboxylation with CO2 and H2 using a Rh monometallic catalyst under milder conditions.

Ultrahigh-surface-area hierarchical porous carbon from chitosan: acetic acid mediated efficient synthesis and its application in superior supercapacitors

2017 ◽  
Vol 5 (47) ◽  
pp. 24775-24781 ◽  
Author(s):  
Jianyu Huang ◽  
Yeru Liang ◽  
Hang Hu ◽  
Simin Liu ◽  
Yijin Cai ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Surface Area ◽  
Porous Carbon ◽  
Efficient Synthesis ◽  
Hierarchical Porous Carbon ◽  
Capacitive Properties ◽  
Hierarchical Porous

Acetic acid mediated efficient synthesis of ultrahigh-surface-area hierarchical porous carbon from chitosan with very attractive capacitive properties was reported.

A Novel and Efficient Synthesis of α-Aminophosphonates by Use of Triphenyl Phosphite in Acetic Acid Media

2011 ◽  
Vol 186 (2) ◽  
pp. 334-337 ◽  
Author(s):  
Mohsen Rostamizadeh ◽  
Malek Taher Maghsoodlou ◽  
Nourallah Hazeri ◽  
Sayyed Mostafa Habibi-khorassani ◽  
Leila Keishams
Keyword(s):  
Acetic Acid ◽  
Triphenyl Phosphite ◽  
Efficient Synthesis ◽  
Acid Media

ChemInform Abstract: Efficient Synthesis of Tetrahydroquinolinones by Acetic Acid-Mediated Formal [3 + 3] Cycloaddition.

ChemInform ◽  
2013 ◽  
Vol 44 (4) ◽  
pp. no-no
Author(s):  
Quang Huy To ◽  
Yong Rok Lee ◽  
Sung Hong Kim
Keyword(s):  
Acetic Acid ◽  
Efficient Synthesis

An efficient synthesis of pterosin C and other pterosins

1984 ◽  
Vol 62 (10) ◽  
pp. 1945-1953 ◽  
Author(s):  
Kam-Mui Eva Ng ◽  
Trevor C. McMorris
Keyword(s):  
Acetic Acid ◽  
Acetic Anhydride ◽  
Methyl Ether ◽  
Sodium Acetate ◽  
Synthetic Route ◽  
Efficient Synthesis ◽  
Trans Isomers ◽  
Cis And Trans Isomers ◽  
Cis And Trans

A versatile synthetic route to pterosins, sesquiterpenoid indanones present in bracken, Pteridiumaquilinum, has been developed. The route is exemplified by the synthesis of (2S,3S)-pterosin C by Friedel–Crafts bisacylation of the methyl ether of 2-(2,6-dimethylphenyl)ethanol with methylmalonyl chloride. Demethylation of the resulting 1,3-indandione and reduction with zinc and acetic acid in the presence of acetic anhydride and sodium acetate afforded a mixture of racemic cis and trans isomers of pterosin C diacetate, which was hydrolysed to the corresponding pterosins. Separation and resolution via the S-(+)-α-phenylbutyric esters gave (2S,3S)-pterosin C and (2R,3R)-pterosin C. Other pterosins were prepared as racemates from the 1,3-indandione.

Highly Efficient Synthesis of 1‐Nitroindolizine Derivatives via the DBU/Acetic Acid System

2019 ◽  
Vol 4 (37) ◽  
pp. 11121-11124 ◽  
Author(s):  
Naili Luo ◽  
Mingshuang Li ◽  
Ting Wang ◽  
Yanxiang Li ◽  
Cunde Wang
Keyword(s):  
Acetic Acid ◽  
Acid System ◽  
Efficient Synthesis ◽  
Highly Efficient

A Facile and Efficient Synthesis of bis(Imidazo[1,2-a]pyridin-3-yl)methane and vinyl derivatives

2021 ◽  
Vol 18 ◽  
Author(s):  
D.E. Prasada Rao ◽  
M. David Raju ◽  
J. Surendra ◽  
A. Vasu Babu ◽  
P. Eswaraiah ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Trifluoroacetic Acid ◽  
Methyl Chloride ◽  
The Novel ◽  
Synthetic Route ◽  
Efficient Synthesis ◽  
Vinyl Derivatives

An efficient synthetic route for the novel bis-imdizo[1,2-a]pyridine-3-yl)methane (2a-k) derivatives have been developed using acetic acid and two drops of trifluoroacetic acid at 40-45oC, resulting in 60-72% yields. An attempt to synthesize bis(Imidazo[1,2-a]pyridin-3-yl)methyl chloride derivatives by the reaction between two moles of imidazo[1,2-a]pyridine, one mole of chloroacetaldehyde in acetic acid, and two drops of trifluoroacetic acid was not successful, instead underwent dehydrohalogenation to yield vinyl derivatives (4a-d).

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