Synthesis of potential bisphenol A substitutes by isomerising metathesis of renewable raw materials

2017 ◽  
Vol 19 (13) ◽  
pp. 3051-3060 ◽  
Author(s):  
A. S. Trita ◽  
L. C. Over ◽  
J. Pollini ◽  
S. Baader ◽  
S. Riegsinger ◽  
...  
Keyword(s):  
Bisphenol A ◽  
Estrogenic Activity ◽  
Raw Materials ◽  
Building Blocks ◽  
Renewable Raw Materials

Plant-derived alkenyl arenes were converted into polymer building blocks with low estrogenic activity via isomerising metathesis.

Perspectives for the Brazilian residual biomass in renewable chemistry

2014 ◽  
Vol 86 (5) ◽  
pp. 833-842 ◽  
Author(s):  
Sílvio Vaz
Keyword(s):  
Chemical Industry ◽  
Special Interest ◽  
Raw Materials ◽  
Building Blocks ◽  
Raw Material ◽  
Economic Potential ◽  
Renewable Raw Materials ◽  
Fine Chemical ◽  
Residual Biomass

AbstractThe need to change non-renewable raw materials by biomass as an oil substitute has been shown to be a strategic challenge for the 21st century. Chemicals have the highest potential to add value to a vegetable biomass chain because of the importance of conventional chemical industry and fine chemical chemistry for different sectors of the economy; these compounds may be used as building blocks, intermediaries of synthesis, and specialties. This article deals with the economic potential of the usage of residual biomass as a raw material in chemistry, with a special interest in residues from bioenergetic chains (biodiesel and ethanol). It focus on showing a scenario related to the perspectives and challenges for the development of a Brazilian renewable chemistry, considering that Brazil is one of the largest global producers of agro-industrial biomass for several purposes, especially for bioenergy.

Hydrogenolysis of glucose and fructose in glycol solutions over CuO-MgO-ZrO2 catalyst

2020 ◽  
pp. 48-55
Author(s):  
M.E. Sharanda ◽  
◽  
E.A. Bondarenko ◽  
Keyword(s):  
Ethylene Glycol ◽  
Propylene Glycol ◽  
Flow Reactor ◽  
General Trend ◽  
Raw Materials ◽  
Reaction Products ◽  
Renewable Raw Materials ◽  
High Partial Pressure ◽  
Zro2 Catalyst ◽  
Phase Process

Ethylene glycol and propylene glycol are important representatives of polyols. On an industrial scale, they are obtained from petrochemical raw materials. Within a decade, significant efforts were made for the producing of polyols from biologically renewable raw materials - carbohydrates. The general trend for carbohydrate hydrogenolysis includes application of liquid-phase process with the use of modified metal-oxide catalysts, at 120-120 ° C and pressure of 3MPa or above. So high pressure is used for the reason to increase hydrogen solubility, and also due to the high partial pressure of low boiling solvents. We supposed that usage of high boiling solvents could allow hydrogenolysis to be performed at the lower pressure. Ethylene glycol and propylene glycol are of particular interest as such kind of solvent since they are both the main products of glucose hydrogenolysis. In this work, the process of hydrogenolysis of glucose and fructose over Cu / MgO-ZrO2 catalyst have been studied at temperature range of 160-200 °C and a pressure of 0.1-0.3 MPa in a flow reactor. The solvents were simultaneously the target products of the reaction - ethylene glycol and / or propylene glycol. Gas chromatography and 13C NMR were used for the reaction products identification. It was found that the solubility of glucose in propylene glycol is 21 % by weight, and in ethylene glycol 62% by weight. It was pointed out that the process of hydrogenolysis can take place at a pressure close to atmospheric. Under these conditions, the conversion of hexoses reaches 96-100 %. The reaction products are preferably propylene glycol and ethylene glycol. The total selectivity for C3-2 polyols is 90-94 %, that is higher than in the hydrogenolysis of glucose in aqueous solution.

scholarly journals Wine By-Products as Raw Materials for the Production of Biopolymers and of Natural Reinforcing Fillers: A Critical Review

Polymers ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 381
Author(s):  
Alessandro Nanni ◽  
Mariafederica Parisi ◽  
Martino Colonna
Keyword(s):  
Critical Review ◽  
Raw Materials ◽  
Green Revolution ◽  
Building Blocks ◽  
Poly Lactic Acid ◽  
Butylene Succinate ◽  
Reinforcing Fillers ◽  
Plastic Industry ◽  
Review Reports ◽  
By Products

The plastic industry is today facing a green revolution; however, biopolymers, produced in low amounts, expensive, and food competitive do not represent an efficient solution. The use of wine waste as second-generation feedstock for the synthesis of polymer building blocks or as reinforcing fillers could represent a solution to reduce biopolymer costs and to boost the biopolymer presence in the market. The present critical review reports the state of the art of the scientific studies concerning the use of wine by-products as substrate for the synthesis of polymer building blocks and as reinforcing fillers for polymers. The review has been mainly focused on the most used bio-based and biodegradable polymers present in the market (i.e., poly(lactic acid), poly(butylene succinate), and poly(hydroxyalkanoates)). The results present in the literature have been reviewed and elaborated in order to suggest new possibilities of development based on the chemical and physical characteristics of wine by-products.

scholarly journals Characterization of Estrogenic Activity and Site-Specific Accumulation of Bisphenol-A in Epididymal Fat Pad: Interfering Effects on the Endocannabinoid System and Temporal Progression of Germ Cells

2021 ◽  
Vol 22 (5) ◽  
pp. 2540
Author(s):  
Teresa Chioccarelli ◽  
Marina Migliaccio ◽  
Antonio Suglia ◽  
Francesco Manfrevola ◽  
Veronica Porreca ◽  
...  
Keyword(s):  
Bisphenol A ◽  
Germ Cell ◽  
Germ Cells ◽  
Estrogenic Activity ◽  
Endocannabinoid System ◽  
Perinatal Period ◽  
Cell Junction ◽  
Cell Content ◽  
Site Specific ◽  
Epididymal Fat

The objective of this work has been to characterize the estrogenic activity of bisphenol-A (BPA) and the adverse effects on the endocannabinoid system (ECS) in modulating germ cell progression. Male offspring exposed to BPA during the foetal-perinatal period at doses below the no-observed-adverse-effect-level were used to investigate the exposure effects in adulthood. Results showed that BPA accumulates specifically in epididymal fat rather than in abdominal fat and targets testicular expression of 3β-hydroxysteroid dehydrogenase and cytochrome P450 aromatase, thus promoting sustained increase of estrogens and a decrease of testosterone. The exposure to BPA affects the expression levels of some ECS components, namely type-1 (CB1) and type-2 cannabinoid (CB2) receptor and monoacylglycerol-lipase (MAGL). Furthermore, it affects the temporal progression of germ cells reported to be responsive to ECS and promotes epithelial germ cell exfoliation. In particular, it increases the germ cell content (i.e., spermatogonia while reducing spermatocytes and spermatids), accelerates progression of spermatocytes and spermatids, promotes epithelial detachment of round and condensed spermatids and interferes with expression of cell–cell junction genes (i.e., zonula occcludens protein-1, vimentin and β-catenin). Altogether, our study provides evidence that early exposure to BPA produces in adulthood sustained and site-specific BPA accumulation in epididymal fat, becoming a risk factor for the reproductive endocrine pathways associated to ECS.

scholarly journals Organizational, technical and economic fundamentals of waste management and monitoring

2020 ◽  
Vol 164 ◽  
pp. 08031
Author(s):  
Evgeniy Velichko ◽  
Edward Tshovrebov ◽  
Ural Niyazgulov
Keyword(s):  
Legal Status ◽  
Raw Materials ◽  
Economic Regulation ◽  
Economic Activities ◽  
Renewable Raw Materials ◽  
Secondary Resources ◽  
Secondary Raw Materials ◽  
Production And Consumption ◽  
Level Of Use ◽  
Goals And Objectives

The article deals with issues of monitoring, planning, organizational and technical support, economic regulation and improving the efficiency of the infrastructure for processing, recycling and disposal of waste, resource conservation and management of secondary resources, their use as secondary raw materials for production, services, work and power generation. The Russian Federation has significant potential for economic growth due to the efficient use of secondary resources from billions of tons of generated production and consumption waste annually. These ecologically unsafe anthropogenic objects can be characterized as a source of valuable renewable raw materials, material and fuel and energy resources. However, the scale and level of use of various types of secondary resources are characterized by considerable unevenness and depend on the demand for secondary raw materials, the resource value of the waste, the environmental situation arising from treating them as environmental polluters, on the real economic conditions that determine the profitability of each specific type. economic activities that use secondary resources for the manufacture of products, works, services, energy production. The methods of monitoring the industry for the treatment, disposal and disposal of waste are: information-analytical, information-statistical, sociological, geo-information. The legal status of the monitoring system of the industry for the treatment, disposal and disposal of waste is determined by the limitations of its functionality within the framework of the goals and objectives facing it.

scholarly journals Palm Olein as Renewable Raw Materials for Industrial and Pharmaceutical Products Applications: Chemical Characterization and Physicochemical Properties Studies

2014 ◽  
Vol 2014 ◽  
pp. 1-5 ◽  
Author(s):  
Darfizzi Derawi ◽  
Bashar Mudhaffar Abdullah ◽  
Hasniza Zaman Huri ◽  
Rahimi M. Yusop ◽  
Jumat Salimon ◽  
...  
Keyword(s):  
Chemical Modification ◽  
Palm Olein ◽  
Raw Materials ◽  
Viscosity Index ◽  
Chemical Characterization ◽  
Pharmaceutical Products ◽  
Raw Material ◽  
Chemical Compositions ◽  
Renewable Raw Materials ◽  
Modification Process

Palm olein (POo) is widely produced as edible oil in tropical countries. POois considered as renewable raw material for the new industrial and pharmaceutical products synthesis based on its characterization. Palm olein was good on its viscosity index, oxidative stability, and flash and fire point. POocontained unsaturated triacylglycerols (TAGs): POO (33.3%); POP (29.6%) which plays an important role in chemical modification process to produce new industrial products. The double bond was detected on1H-NMR (5.3 ppm) and13C-NMR (130 ppm) spectra. The chemical compositions of POowere tested by using high performance liquid chromatography (HPLC) and gas chromatography (GC) techniques. This unsaturated oil is potentially to be used as renewable raw materials in chemical modification process to synthesise polyols, polyurethane, and biolubricant for industrial and pharmaceutical products application.

SYNTHESIS AND ESTROGENIC ACTIVITY OF BISPHENOL A MONO- AND DI-β-D-GLUCOPYRANOSIDES, PLANT METABOLITES OF BISPHENOL A

2003 ◽  
Vol 22 (10) ◽  
pp. 2275 ◽  
Author(s):  
Kaori Morohoshi ◽  
Fujio Shiraishi ◽  
Yukiko Oshima ◽  
Tomoko Koda ◽  
Nobuyoshi Nakajima ◽  
...  
Keyword(s):  
Bisphenol A ◽  
Estrogenic Activity ◽  
Plant Metabolites

Increased levels of bisphenol A (BPA) in Thai girls with precocious puberty

2016 ◽  
Vol 0 (0) ◽  
Author(s):  
Vichit Supornsilchai ◽  
Chutima Jantarat ◽  
Wichit Nosoognoen ◽  
Sopon Pornkunwilai ◽  
Suttipong Wacharasindhu ◽  
...  
Keyword(s):  
Bisphenol A ◽  
Estrogenic Activity ◽  
Age At Onset ◽  
Ultra Performance Liquid Chromatography ◽  
Cross Sectional Study ◽  
Normal Weight ◽  
Control Groups ◽  
Limit Of Quantification ◽  
Cross Sectional ◽  
Liquid Chromatography Tandem Mass

AbstractReports on the secular trend of pubertal onset indicate a recent earlier start especially in girls. Bisphenol A (BPA), which posses estrogenic activity, might be a cause of advanced puberty. The objective of the study was to determine the association between BPA and advanced puberty.A cross-sectional study was conducted in patients with advanced puberty (n=41) compared to age-matched controls (n=47). Anthropometric measurements, estradiol, basal and gonadotropin releasing hormone (GnRH)-stimulated follicle stimulating hormone (FSH) and luteinizing hormone (LH) levels, uterine sizes, ovarian diameters and bone ages were obtained. Urinary BPA concentrations were analyzed by ultra-performance liquid chromatography-tandem mass spectrometry (UPLC/MSMS) with the lower limit of quantification (LLOQ) of 0.05 ng/mL.The median adjust-BPA concentration in advanced puberty group was higher than in control groups [1.44 vs. 0.59 μg/g creatinine (Cr): p<0.05]. We also found that the median adjust-BPA concentration in girls with advanced puberty who were overweight/obese, was greater than in the normal pubertal overweight/obese girls (1.74 vs. 0.59 μg/g Cr: p<0.05), and was in the same trend among normal weight girls with advanced and normal puberty (0.83 vs. 0.49 μg/g Cr: p=0.09), but not statistically significant.The present findings suggest that BPA exposure appears to be related to an earlier age at onset of puberty especially in obese girls.

The role of catalysis in the synthesis of polyurethane foams based on renewable raw materials

2014 ◽  
Vol 223 ◽  
pp. 148-156 ◽  
Author(s):  
Sylwia Dworakowska ◽  
Dariusz Bogdał ◽  
Federica Zaccheria ◽  
Nicoletta Ravasio
Keyword(s):  
Raw Materials ◽  
Polyurethane Foams ◽  
Renewable Raw Materials
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