Hierarchical MoS2nanosheets on flexible carbon felt as an efficient flow-through electrode for dechlorination

2017 ◽  
Vol 4 (12) ◽  
pp. 2286-2296 ◽  
Author(s):  
Li-Zhi Huang ◽  
Steen Uttrup Pedersen ◽  
Emil Tveden Bjerglund ◽  
Paolo Lamagni ◽  
Marianne Glasius ◽  
...  

MoS2nanosheets were grown directly on carbon felt, which is used as flow-through electrode for reductive dechlorination.

2018 ◽  
Vol 335 ◽  
pp. 685-692 ◽  
Author(s):  
Yinqiao Zhang ◽  
Sijin Zuo ◽  
Minghua Zhou ◽  
Liang Liang ◽  
Gengbo Ren

2017 ◽  
Vol 62 (33) ◽  
pp. 3821-3828
Author(s):  
LinBo LIU ◽  
DingDing YE ◽  
Jun LI ◽  
Xun ZHU ◽  
Qian FU ◽  
...  

2005 ◽  
Vol 54 (12) ◽  
pp. 1197-1204 ◽  
Author(s):  
Yasushi HASEBE ◽  
Takayuki SHIRAI ◽  
Tomohiro NAGASHIMA ◽  
Tingting GU ◽  
Shunichi UCHIYAMA

Coatings ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1188
Author(s):  
Di Li ◽  
Siqi Zhang ◽  
Yingjia Chen ◽  
Haiming Yang ◽  
Xin Geng ◽  
...  

Electrochemical dechlorination with Pd-loaded electrodes offers an effective method for detoxification of wastewater. Electro-reductive dechlorination of 3-chlorophenol (3-CP) with Pd loaded on carbon felt (Pd/CF) was investigated. Pd was loaded on carbon felt by electrolytic method. The prepared electrodes were characterized by XRD, SEM, EDS, S-TEM and CV. The sizes of the Pd particles loaded on CF were found in the range of 100–400 nm. The preparing conditions including loading amount of Pd and loading currents were investigated. Moreover, the reduction conditions including electrolytes, reductive currents and recycle times were also studied. The Pd/CF cathodes with Pd loading of 0.5 mg/cm2, preparing current of 5 mA, electrolyte concentration of 30 mmol/L NaCl and 30 mmol/L CH3COONa were used to reduce 3-CP for dechlorination. When CH3COONa was used as the electrolyte, the current was 5 mA, the initial pH was 7.5, the initial 3-CP concentration was 1 mmol/L and the degradation rate of 3-CP could reach 95.81% after reduction of 150 min under an argon atmosphere. The electrochemical reduction of 3-CP was confirmed to follow the first-order rate law. 3-CP was qualitatively dechlorinated to phenol on electrodes with Pd. The fact that active hydrogen formed on palladium during preliminary electrolysis could be proved by the dechlorinated 3-CP in non-electroreduction after preliminary electrolysis. A possible reduction pathway was proposed based on the results.


1998 ◽  
Vol 37 (8) ◽  
pp. 105-110 ◽  
Author(s):  
Peter J. M. Middeldorp ◽  
Martine A. van Aalst ◽  
Huub H. M. Rijnaarts ◽  
Fons J. M. Stams ◽  
Han F. de Kreuk ◽  
...  

A soil from a former chemical redistribution company, contaminated with mainly chlorinated aliphatics, was studied for bioremediation purposes. Groundwater analyses revealed that the original pollutants, i.e. tetrachloroethene (PCE) and trichloroethene (TCE), were present at levels ranging from 2.3 to 122 mg/L. Dichloroethene (DCE), vinylchloride (VC), ethene and ethane were also detected at significant concentrations although they had never been introduced to the soil. Relatively high concentrations of cis-DCE as compared to trans-DCE and 1,1-DCE indicated that a slow in situ biodegradation had taken place by reductive dechlorination. Laboratory experiments with flow-through soil columns were performed to determine the optimal conditions for the enhancement of reductive dechlorination by the indigenous dechlorinating population. The addition of single electron donors to artificial groundwater resulted in the dechlorination of PCE to TCE and cis-DCE, whereas complete dechlorination to ethene was solely achieved with compost extract added to native groundwater.


2014 ◽  
Vol 482-483 ◽  
pp. 23-35 ◽  
Author(s):  
Elsa Lacroix ◽  
Alessandro Brovelli ◽  
Julien Maillard ◽  
Emmanuelle Rohrbach-Brandt ◽  
D.A. Barry ◽  
...  

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