scholarly journals Hybrid electrolytes with 3D bicontinuous ordered ceramic and polymer microchannels for all-solid-state batteries

2018 ◽  
Vol 11 (1) ◽  
pp. 185-201 ◽  
Author(s):  
Stefanie Zekoll ◽  
Cassian Marriner-Edwards ◽  
A. K. Ola Hekselman ◽  
Jitti Kasemchainan ◽  
Christian Kuss ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Solid State ◽  
Lithium Batteries ◽  
Templating Method ◽  
Solid State Batteries ◽  
All Solid State Batteries

A novel templating method to create 3D bicontinuous structured hybrid electrolytes with improved mechanical properties for all-solid-state lithium batteries.

Mechanical Properties of Li2S–P2S5 Glasses with Lithium Halides and Application in All-Solid-State Batteries

2018 ◽  
Vol 1 (3) ◽  
pp. 1002-1007 ◽  
Author(s):  
Atsutaka Kato ◽  
Mirai Yamamoto ◽  
Atsushi Sakuda ◽  
Akitoshi Hayashi ◽  
Masahiro Tatsumisago
Keyword(s):  
Mechanical Properties ◽  
Solid State ◽  
Solid State Batteries ◽  
All Solid State Batteries ◽  
Lithium Halides

Recent advances in the sulfide electrolytes toward high specific energy solid-state lithium batteries

2021 ◽  
Author(s):  
Tao Yu ◽  
Bingyu Ke ◽  
Haoyu Li ◽  
Shaohua Guo ◽  
Haoshen Zhou
Keyword(s):  
Solid State ◽  
Energy Density ◽  
Specific Energy ◽  
Lithium Batteries ◽  
Lithium Ion ◽  
Liquid Lithium ◽  
Specific Energy Density ◽  
Solid State Batteries ◽  
All Solid State Batteries ◽  
High Specific Energy

All solid-state batteries (ASSBs) have gained extensive attention due to the improved safety, and high specific energy density compared with conventional liquid lithium-ion batteries. As the key component of ASSBs,...

scholarly journals Mechanical properties of sulfide glasses in all-solid-state batteries

2018 ◽  
Vol 126 (9) ◽  
pp. 719-727 ◽  
Author(s):  
Atsutaka Kato ◽  
Masashi Nose ◽  
Mirai Yamamoto ◽  
Atsushi Sakuda ◽  
Akitoshi Hayashi ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Solid State ◽  
Solid State Batteries ◽  
All Solid State Batteries ◽  
Sulfide Glasses

scholarly journals A new halospinel superionic conductor for high-voltage all solid state lithium batteries

2020 ◽  
Vol 13 (7) ◽  
pp. 2056-2063 ◽  
Author(s):  
Laidong Zhou ◽  
Chun Yuen Kwok ◽  
Abhinandan Shyamsunder ◽  
Qiang Zhang ◽  
Xiaohan Wu ◽  
...  
Keyword(s):  
Solid State ◽  
High Voltage ◽  
Lithium Batteries ◽  
Superionic Conductor ◽  
Solid State Batteries ◽  
All Solid State Batteries

A new disordered chlorospinel superionic conductor, Li2Sc2/3Cl4, enables high-voltage all solid state batteries up to 4.6 V vs. Li+/Li.

Prospects of production technologies and manufacturing costs of oxide-based all-solid-state lithium batteries

2019 ◽  
Vol 12 (6) ◽  
pp. 1818-1833 ◽  
Author(s):  
Joscha Schnell ◽  
Frank Tietz ◽  
Célestine Singer ◽  
Andreas Hofer ◽  
Nicolas Billot ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Batteries ◽  
Mass Production ◽  
Small Scale ◽  
Manufacturing Cost ◽  
Manufacturing Costs ◽  
Solid State Batteries ◽  
Production Technologies ◽  
All Solid State Batteries

This manuscript analyzes different scenarios to estimate the manufacturing cost for small-scale and mass production of all-solid-state batteries.

Development of Solid Electrolytes for All-Solid-State Batteries

2019 ◽  
Vol 92 (11) ◽  
pp. 430-434
Author(s):  
Akitoshi HAYASHI ◽  
Atsushi SAKUDA ◽  
Masahiro TATSUMISAGO
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
Solid State Batteries ◽  
All Solid State Batteries

Rational Design of Quasi Zero-Strain NCM Cathode Materials for Minimizing Volume Change Effects in All-Solid-State Batteries

2019 ◽  
Author(s):  
Florian Strauss ◽  
Lea de Biasi ◽  
A-Young Kim ◽  
Jonas Hertle ◽  
Simon Schweidler ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Cathode Materials ◽  
Rational Design ◽  
Electrode Materials ◽  
Cycling Performance ◽  
Mechanical Degradation ◽  
Volume Changes ◽  
Solid State Batteries ◽  
All Solid State Batteries

Measures to improve the cycling performance and stability of bulk-type all-solid-state batteries (SSBs) are currently being developed with the goal of substituting conventional Li-ion battery (LIB) technology. As known from liquid electrolyte based LIBs, layered oxide cathode materials undergo volume changes upon (de)lithiation, causing mechanical degradation due to particle fracture, among others. Unlike solid electrolytes, liquid electrolytes are somewhat capable of accommodating morphological changes. In SSBs, the rigidity of the materials used typically leads to adverse contact loss at the interfaces of cathode material and solid electrolyte during cycling. Hence, designing zero- or low-strain electrode materials for application in next-generation SSBs is desirable. In the present work, we report on novel Co-rich NCMs, NCM361 (60% Co) and NCM271 (70% Co), showing minor volume changes up to 4.5 V vs Li<sup>+</sup>/Li, as determined by <i>operando</i> X-ray diffraction and pressure measurements of LIB pouch and pelletized SSB cells, respectively. Both cathode materials exhibit good cycling performance when incorporated into SSB cells using argyrodite Li<sub>6</sub>PS<sub>5</sub>Cl solid electrolyte, albeit their morphology and secondary particle size have not yet been optimized.

Rational Design of Quasi Zero-Strain NCM Cathode Materials for Minimizing Volume Change Effects in All-Solid-State Batteries

2019 ◽  
Author(s):  
Florian Strauss ◽  
Lea de Biasi ◽  
A-Young Kim ◽  
Jonas Hertle ◽  
Simon Schweidler ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Cathode Materials ◽  
Rational Design ◽  
Electrode Materials ◽  
Cycling Performance ◽  
Mechanical Degradation ◽  
Volume Changes ◽  
Solid State Batteries ◽  
All Solid State Batteries

Measures to improve the cycling performance and stability of bulk-type all-solid-state batteries (SSBs) are currently being developed with the goal of substituting conventional Li-ion battery (LIB) technology. As known from liquid electrolyte based LIBs, layered oxide cathode materials undergo volume changes upon (de)lithiation, causing mechanical degradation due to particle fracture, among others. Unlike solid electrolytes, liquid electrolytes are somewhat capable of accommodating morphological changes. In SSBs, the rigidity of the materials used typically leads to adverse contact loss at the interfaces of cathode material and solid electrolyte during cycling. Hence, designing zero- or low-strain electrode materials for application in next-generation SSBs is desirable. In the present work, we report on novel Co-rich NCMs, NCM361 (60% Co) and NCM271 (70% Co), showing minor volume changes up to 4.5 V vs Li<sup>+</sup>/Li, as determined by <i>operando</i> X-ray diffraction and pressure measurements of LIB pouch and pelletized SSB cells, respectively. Both cathode materials exhibit good cycling performance when incorporated into SSB cells using argyrodite Li<sub>6</sub>PS<sub>5</sub>Cl solid electrolyte, albeit their morphology and secondary particle size have not yet been optimized.

Operando Visualization of Morphological Dynamics in All-Solid-State Batteries

2019 ◽  
Author(s):  
Xiaohan Wu ◽  
Juliette Billaud ◽  
Iwan Jerjen ◽  
Federica Marone ◽  
Yuya Ishihara ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
Rational Design ◽  
Morphological Evolution ◽  
Active Material ◽  
Composite Layer ◽  
Transference Number ◽  
Thermal Stabilities ◽  
Solid State Batteries ◽  
All Solid State Batteries

<div> <div> <div> <p>All-solid-state batteries are considered as attractive options for next-generation energy storage owing to the favourable properties (unit transference number and thermal stabilities) of solid electrolytes. However, there are also serious concerns about mechanical deformation of solid electrolytes leading to the degradation of the battery performance. Therefore, understanding the mechanism underlying the electro-mechanical properties in SSBs are essentially important. Here, we show three-dimensional and time-resolved measurements of an all-solid-state cell using synchrotron radiation x-ray tomographic microscopy. We could clearly observe the gradient of the electrochemical reaction and the morphological evolution in the composite layer. Volume expansion/compression of the active material (Sn) was strongly oriented along the thickness of the electrode. While this results in significant deformation (cracking) in the solid electrolyte region, we also find organized cracking patterns depending on the particle size and their arrangements. This study based on operando visualization therefore opens the door towards rational design of particles and electrode morphology for all-solid-state batteries. </p> </div> </div> </div>

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