One-step synthesis of MnS/MoS2/C through the calcination and sulfurization of a bi-metal–organic framework for a high-performance supercapacitor and its photocurrent investigation

2018 ◽  
Vol 47 (15) ◽  
pp. 5390-5405 ◽  
Author(s):  
Zhi Shuo Yan ◽  
Ji Ying Long ◽  
Qing Feng Zhou ◽  
Yun Gong ◽  
Jian Hua Lin

Using a bi-metallic Mn/Mo-MOF as a precursor, a MnS/MoS2/C hybrid material was synthesized with a high specific capacitance of 1162 F g−1 at 0.5 A g−1 in 2 M KOH solution due to the synergetic effects of the individual components and their exposed active sites.

2017 ◽  
Vol 41 (21) ◽  
pp. 12835-12842 ◽  
Author(s):  
Lijun Xin ◽  
Rongrong Chen ◽  
Qi Liu ◽  
Jingyuan Liu ◽  
Zhanshuang Li ◽  
...  

Nitrogen-doped porous carbon prepared via facile carbonization which displays high specific capacitance, is an excellent potential material for supercapacitors.


2020 ◽  
Vol 7 (2) ◽  
pp. 427-436 ◽  
Author(s):  
Yan Zhou ◽  
Shihang Zhao ◽  
Xianbo Yu ◽  
Yanli Li ◽  
Hongmei Chen ◽  
...  

Core–cell Cu7S4@Ni(OH)2 nanorod arrays were fabricated by using metal–organic frameworks as templates, and showed high specific capacitance, superior rate capacity and excellent cycling stability for supercapacitors.


2022 ◽  
Author(s):  
Chong-Huan Wang ◽  
Da-Wei Zhang ◽  
Shude Liu ◽  
Yusuke Yamauchi ◽  
Fei-Bao Zhang ◽  
...  

Herein, we propose a solvent-assisted approach for preparing Ni-MOF microflowers with high specific capacitance and excellent rate capability as an electrode material for supercapacitors. Such high electrochemical performance is attributed...


2015 ◽  
Vol 2015 ◽  
pp. 1-6 ◽  
Author(s):  
Jiaqiang Jiang ◽  
Fuxiang Wei ◽  
Genxi Yu ◽  
Yanwei Sui

Co3O4nanoparticles were prepared from cobalt nitrate that was accommodated in the pores of a metal-organic framework (MOF) ZIF-8 (Zn(MeIM)2, MeIM = 2-methylimidazole) by using a simple liquid-phase method. Analysis by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) showed that the obtained Co3O4was composed of separate nanoparticles with a mean size of 30 nm. The obtained Co3O4nanoparticles exhibited superior electrochemical property. Co3O4electrode exhibited a maximum specific capacitance of 189.1 F g−1at the specific current of 0.2 A g−1. Meanwhile, the Co3O4electrode possessed the high specific capacitance retention ratio at the current density ranging from 0.2 to 1.0 A g−1, thereby indicating that Co3O4electrode suited high-rate charge/discharge.


2020 ◽  
Vol 13 (02) ◽  
pp. 2051005 ◽  
Author(s):  
Godlaveeti Sreenivasa Kumar ◽  
Somala Adinarayana Reddy ◽  
Hussen Maseed ◽  
Nagireddy Ramamanohar Reddy

In this work, we present the synthesis of a ternary CeO2–SnO2/rGO nanocomposite by using a facile one-step hydrothermal method. The as-synthesized composite was structural, chemical, morphological, elemental information studied by using different characterization techniques X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy and field emission scanning electron microscope (FESEM), energy dispersive X-ray spectroscopy (EDAX) and transmission electron microscope (TEM). The CeO2–SnO2/rGO exhibited an excellent specific capacitance of 156[Formula: see text]F[Formula: see text][Formula: see text] at 0.5[Formula: see text]A/g in the presence of 3 M KOH solution. The synergic effect of CeO2, SnO2 and graphene composite coated on Ni foam endowed a high specific capacitance than their individual compounds. This work suggests that the novel ternary composite is a promising candidate for the high performance electrochemical energy storage and conversion systems.


CrystEngComm ◽  
2017 ◽  
Vol 19 (47) ◽  
pp. 7177-7184 ◽  
Author(s):  
Xin Xiong ◽  
Liuyin Zhou ◽  
Wenjie Cao ◽  
Jiyuan Liang ◽  
Yazhen Wang ◽  
...  

Two halogen-bridged di-nuclear Cu-based 3D porous frameworks present high specific capacitance and good cycling stability.


2016 ◽  
Vol 4 (21) ◽  
pp. 8283-8290 ◽  
Author(s):  
Dong Ji ◽  
Hu Zhou ◽  
Jian Zhang ◽  
Yuanyuan Dan ◽  
Hongxun Yang ◽  
...  

3DGN and MOF-derived metal oxide composites as free-standing electrodes for supercapacitors have been reported for the first time which exhibit a high specific capacitance, good rate capability and excellent long cycle stability.


2020 ◽  
Author(s):  
Jingwei Liu ◽  
Daixi Xie ◽  
Xiufang Xu ◽  
Luozhen Jiang ◽  
Rui Si ◽  
...  

Abstract Sn-based compounds with buffer matrixes possessing high theoretical capacity, low working voltage, and alleviation of the volume expansion of Sn are ideal materials for lithium storage. However, it is highly challenging to confine well-dispersed Sn within a lithium active matrix because low-melting-point Sn tends to agglomerate. Here, for the first time, we apply a metal-organic framework (MOF) chemistry between Sn-nodes and lithium active ligands to create two Sn-based MOFs comprising Sn2(dobdc) and Sn2(dobpdc) with extended ligands from H4dobdc (2,5-dioxido-1,4-benzenedicarboxylate acid) to H4dobpdc (4,4’-dioxidobiphenyl-3,3’-dicarboxylate acid) with molecule-level homodispersion of Sn in organic matrixes for lithium storage. The enhanced utilization of active sites and reaction kinetics are achieved by the isoreticular expansion of the organic linkers. The reversible formation of coordination bonds during lithium storage processes is first revealed by X-ray absorption fine structure characterization, providing an in-depth understanding of the lithium storage mechanism in coordination compounds.


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