scholarly journals From a square core to square opening: structural diversity and magnetic properties of the oxo-bridged [CrIIINbV] complexes

2018 ◽  
Vol 47 (12) ◽  
pp. 4183-4190 ◽  
Author(s):  
Marijana Jurić ◽  
Lidija Androš Dubraja ◽  
Jasminka Popović ◽  
Krešimir Molčanov ◽  
Filip Torić ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Dft Calculations ◽  
Structural Diversity ◽  
Antiferromagnetic Coupling ◽  
Magnetization Measurements

Three oxo-bridged [CrIIINbV] compounds exhibit antiferromagnetic coupling between CrIII ions mediated through the diamagnetic –O–NbV–O– bridge, as observed by magnetization measurements and DFT calculations.

Water Displacement by Cyanogold Complexes in Binuclear Nickel(II) Compounds Based on Bridging Oxalate. Synthesis, Structural Diversity, Magnetic Properties, and DFT Calculations

2003 ◽  
Vol 42 (4) ◽  
pp. 960-969 ◽  
Author(s):  
Pablo Vitoria ◽  
Iñaki Muga ◽  
Juan M. Gutiérrez-Zorrilla ◽  
Antonio Luque ◽  
Pascual Román ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Dft Calculations ◽  
Structural Diversity ◽  
Water Displacement ◽  
Oxalate Synthesis

Structural diversity and magnetic properties of six ferrocenyl monocarboxylate Mn(ii), Ni(ii) and Co(ii) complexes with 1D aqua, carboxyl or dinuclear hydroxyl bridges

CrystEngComm ◽  
2021 ◽  
Author(s):  
Misbha Rafiq Khan ◽  
Xiaoge Niu ◽  
Tianling Chen ◽  
Yan Liu ◽  
Zhongyi Liu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Magnetic Coupling ◽  
Structural Diversity ◽  
Different Types ◽  
Structure Diversity

Six ferrocenyl monocarboxylate Mn(ii), Ni(ii) and Co(ii) complexes with different types of magnetic coupling bridges were synthesized successfully. 1–6 display intriguing structure diversity and magnetic properties.

Electronic and magnetic properties of C-doped α-Al2O3 by DFT calculations

2015 ◽  
Vol 110 ◽  
pp. 368-374 ◽  
Author(s):  
L. Ao ◽  
Y.G. Yuan ◽  
Y. Tian ◽  
J.L. Nie ◽  
H.Y. Xiao ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Dft Calculations ◽  
Electronic And Magnetic Properties ◽  
Α Al2o3

Anion coordination selective [Mn3] and [Mn4] assemblies: synthesis, structural diversity, magnetic properties and catechol oxidase activity

2015 ◽  
Vol 44 (26) ◽  
pp. 11741-11754 ◽  
Author(s):  
Moumita Pait ◽  
Michael Shatruk ◽  
Debashis Ray
Keyword(s):  
Magnetic Properties ◽  
Magnetic Property ◽  
Schiff Base ◽  
Schiff Base Ligand ◽  
Structural Diversity ◽  
Manganese Complexes ◽  
Catechol Oxidase ◽  
Oxidation Study ◽  
Anion Coordination ◽  
Catechol Oxidation

The present manuscript reports the detail synthesis, characterization, magnetic property and catechol oxidation study of a family of mixed valent (MnIIMnIII) and trivalent (MnIII) manganese complexes from a Schiff base ligand.

Cationic Assembly of Metal Complex Aggregates:  Structural Diversity, Solution Stability, and Magnetic Properties

2003 ◽  
Vol 125 (31) ◽  
pp. 9476-9483 ◽  
Author(s):  
Xiang Lin ◽  
Dan M. J. Doble ◽  
Alexander J. Blake ◽  
Andrew Harrison ◽  
Claire Wilson ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Metal Complex ◽  
Structural Diversity ◽  
Solution Stability

Novel P,P-diphenylphosphinic amide-TEMPO radicals family: Synthesis, crystal structures, spectroscopic characterization, magnetic properties and DFT calculations

Polyhedron ◽  
2018 ◽  
Vol 144 ◽  
pp. 166-175 ◽  
Author(s):  
Samira G. Reis ◽  
Miguel A. del Águila-Sánchez ◽  
Guilherme P. Guedes ◽  
Yolanda Navarro ◽  
Rafael A. Allão Cassaro ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Dft Calculations ◽  
Crystal Structures ◽  
Spectroscopic Characterization

scholarly journals Nitronyl Nitroxide Biradical-Based Binuclear Lanthanide Complexes: Structure and Magnetic Properties

2020 ◽  
Vol 6 (4) ◽  
pp. 48
Author(s):  
Lu Xi ◽  
Jing Han ◽  
Xiaohui Huang ◽  
Licun Li
Keyword(s):  
Magnetic Properties ◽  
Magnetic Relaxation ◽  
Lanthanide Complexes ◽  
Magnetic Data ◽  
Antiferromagnetic Coupling ◽  
Zero Field ◽  
Nitronyl Nitroxide ◽  
Ferromagnetic Exchange ◽  
Binuclear Structure ◽  
Slow Magnetic Relaxation

Employing a new nitronyl nitroxide biradical NITPhPzbis(NITPhPzbis = 5-(1-pyrazolyl)-1,3-bis(1’-oxyl-3’-oxido-4’,4’,5’,5’-tetramethyl-4,5-hydro-1H-imidazol-2-yl)benzene), a series of 2p-4f complexes [Ln2(hfac)6(H2O)(NITPhPzbis)] (LnIII = Gd1, Tb2, Dy3; hfac = hexafluoroacetylacetonate) were successfully synthesized. In complexes 1–3, the designed biradical NITPhPzbis coordinates with two LnIII ions in chelating and bridging modes to form a four-spin binuclear structure. Direct-current magnetic study of Gd analogue indicates that ferromagnetic exchange exists between the Gd ion and the radical while antiferromagnetic coupling dominates between two mono-radicals. Dynamic magnetic data show that the χ” signals of complex 3 exhibit frequency dependence under zero field, demonstrating slow magnetic relaxation behavior in complex 3. And the estimated values of Ueff and τ0 are about 8.4 K and 9.1 × 10−8 s, respectively.

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