Water-soluble transition metal complexes of ruthenium(ii), osmium(ii), rhodium(iii) and iridium(iii) with chelating N-heterocyclic carbene ligands in hydrogenation and transfer hydrogenation catalysis

2018 ◽  
Vol 47 (7) ◽  
pp. 2318-2329 ◽  
Author(s):  
Esther Bayón Castañón ◽  
Marlene Kaposi ◽  
Robert M. Reich ◽  
Fritz E. Kühn

The synthesis of novel Ru(ii), Os(ii), Rh(iii) and Ir(iii) mono-N-heterocyclic carbene (NHC) complexes and their application in hydrogenation catalysis is reported.

Polyhedron ◽  
2002 ◽  
Vol 21 (22) ◽  
pp. 2251-2256 ◽  
Author(s):  
Andrey A Karasik ◽  
Roman N Naumov ◽  
René Sommer ◽  
Oleg G Sinyashin ◽  
Evamarie Hey-Hawkins

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