Synthetic routes to a coordinatively unsaturated ruthenium complex supported by a tripodal, protic bis(N-heterocyclic carbene) phosphine ligand

2018 ◽  
Vol 47 (4) ◽  
pp. 1276-1283 ◽  
Author(s):  
S. E. Flowers ◽  
M. C. Johnson ◽  
B. Z. Pitre ◽  
B. M. Cossairt

A facile, one pot synthesis of a coordinatively unsaturated ruthenium complex supported by a tripodal, protic bis(N-heterocyclic carbene) phosphine ligand is presented.

1985 ◽  
Vol 1985 (3) ◽  
pp. 653-655 ◽  
Author(s):  
Gerardo Janairo ◽  
Abdul Malik ◽  
Wolfgang Voelter

2020 ◽  
Vol 18 (25) ◽  
pp. 4815-4823
Author(s):  
Rafael Mafra P. Dias ◽  
Gabriela P. de Oliveira ◽  
Antonio C. B. Burtoloso

A direct and easy approach for the preparation of popular lignin models is described by using the O–H insertion reaction from diazocompounds. This method avoids the use of haloketones and long synthetic routes commonly used to prepare these models.


2012 ◽  
Vol 488-489 ◽  
pp. 1049-1054 ◽  
Author(s):  
Rukkiat Jitchati ◽  
Yuranan Thathong ◽  
Kittiya Wongkhan

Dye-sensitized Solar Cells (DSCs) Have Received Widespread Attention Owing to their Low Cost, Easy Fabrication, and Relatively High Solar-to-electricity Conversion Efficiency. Based on the Tio2 Electrode, Ruthenium Complex Dye, Liquid Electrolyte, and Pt Counter Electrode, Dscs Have Already Exhibited an Efficiency above 11% and Offer an Appealing Alternative to Conventional Solar Cells. however, until now the Commercial and Well Known Standard Dye Is the Ruthenium Complex, Namely, Cis-bis(isothiocyanato)-bis(2,2'-bipyridyl-4,4'dicarboxylato)ruthenium(II) (N3) which Has Been Widely Used around the Word. in this Article, N3 Standard Dye Was Synthesized and Characterized by Two Synthetic Routes: Grätzel’s Protocol and a One-pot Reaction from Cheap and Easily Prepared Starting Materials.


2011 ◽  
Vol 7 ◽  
pp. 1407-1411 ◽  
Author(s):  
Jessica Baiget ◽  
Sabin Llona-Minguez ◽  
Stuart Lang ◽  
Simon P MacKay ◽  
Colin J Suckling ◽  
...  

The carboline ring system is an important pharmacophore found in a number of biologically important targets. Development of synthetic routes for the preparation of these compounds is important in order to prepare a range of analogues containing the carboline heterocyclic moiety. A manganese dioxide mediated one-pot method starting with an activated alcohol and consisting of alcohol oxidation, Pictet–Spengler cyclisation, and oxidative aromatisation, offers a convenient process that allows access to β-carbolines. This one-pot process for the preparation of methyl 9H-pyrido[3,4-b]indole-1-carboxylate has subsequently been used as the key step in the synthesis of alangiobussinine and a closely related analogue.


2020 ◽  
Author(s):  
Lucien Caspers ◽  
Julian Spils ◽  
Mattis Damrath ◽  
Enno Lork ◽  
Boris Nachtsheim

In this article we describe an efficient approach for the synthesis of cyclic diaryliodonium salts. The method is based on benzyl alcohols as starting materials and consists of an Friedel-Crafts-arylation/oxidation sequence. Besides a deep optimization, particluar focusing on the choice and ratios of the utilized Bronsted-acids and oxidants, we explore the substrate scope of this transformation. We also discuss an interesting isomerism of cyclic iodonium salts substituted with aliphatic substituents at the bridge head carbon. <br>


2017 ◽  
Vol 7 (12) ◽  
pp. 1192-1195
Author(s):  
Y. I. Shaikh ◽  
G. M. Nazeruddin ◽  
Khursheed Ahmed

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