Open and closed forms of the interpenetrated [Cu2(Tae)(Bpa)2](NO3)2·nH2O: magnetic properties and high pressure CO2/CH4 gas sorption

2018 ◽  
Vol 47 (3) ◽  
pp. 958-970
Author(s):  
Roberto Fernández de Luis ◽  
Edurne S. Larrea ◽  
Joseba Orive ◽  
Arkaitz Fidalgo-Marijuan ◽  
Luis Lezama ◽  
...  

Cationic [Cu2(Tae)(Bpa)2]2+[NO3]22−·nH2O interpenetrated networks show a solvent loss triggering dynamic aperture of the porous structure from a closed to an open form with a difference of 29% of the volume cell.

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 378
Author(s):  
Li Zhao ◽  
Zhiwei Hu ◽  
Hanjie Guo ◽  
Christoph Geibel ◽  
Hong-Ji Lin ◽  
...  

We report on the synthesis and physical properties of cm-sized CoGeO3 single crystals grown in a high pressure mirror furnace at pressures of 80 bar. Direction dependent magnetic susceptibility measurements on our single crystals reveal highly anisotropic magnetic properties that we attribute to the impact of strong single ion anisotropy appearing in this system with TN∼33.5 K. Furthermore, we observe effective magnetic moments that are exceeding the spin only values of the Co ions, which reveals the presence of sizable orbital moments in CoGeO3.


2021 ◽  
Vol 258 ◽  
pp. 117614
Author(s):  
Ilya V. Novikov ◽  
Marina A. Pigaleva ◽  
Alexander V. Naumkin ◽  
Gennady A. Badun ◽  
Eduard E. Levin ◽  
...  

2019 ◽  
Vol 125 ◽  
pp. 92-101 ◽  
Author(s):  
Shuaiwei Gu ◽  
Yuxing Li ◽  
Lin Teng ◽  
Cailin Wang ◽  
Qihui Hu ◽  
...  

1999 ◽  
Vol 46 (9) ◽  
pp. 1014-1019
Author(s):  
Takashi Saito ◽  
Masaki Azuma ◽  
Mikio Takano ◽  
Zenji Hiroi ◽  
Yasuo Narumi ◽  
...  

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