High-nuclear heterometallic oxime clusters assembled from triangular subunits: solvothermal syntheses, crystal structures and magnetic properties

2018 ◽  
Vol 47 (1) ◽  
pp. 169-179 ◽  
Author(s):  
Hui-Ming Dong ◽  
Zhi-Chao Zhang ◽  
Hai-Yan Li ◽  
Zhong-Yi Liu ◽  
En-Cui Yang ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Crystal Structures ◽  
Magnetic Relaxation ◽  
Entropy Change ◽  
Solvothermal Syntheses

Three series of 3d–4f oxime clusters with slightly low magnetic relaxation or large entropy change were solvothermally constructed through the flexible connectivity of triangular {Ln3(μ3-OH)} subunits.

Four tetrazolate-based 3D frameworks with diverse subunits directed by inorganic anions and azido coligand: hydro/solvothermal syntheses, crystal structures, and magnetic properties

2015 ◽  
Vol 44 (5) ◽  
pp. 2223-2233 ◽  
Author(s):  
Zhao-Jun Hou ◽  
Zhong-Yi Liu ◽  
Ning Liu ◽  
En-Cui Yang ◽  
Xiao-Jun Zhao
Keyword(s):  
Magnetic Properties ◽  
Crystal Structures ◽  
Inorganic Anions ◽  
Solvothermal Syntheses ◽  
Trigonal Prismatic

Four magnetic frameworks with hourglass-shaped {Cu5(μ3-OH)2}8+ cluster, linear {Cu3(μ-Cl)2}4+ core, linear {Cu(μ1,1-N3)}+ chain and trigonal-prismatic {Cu8(μ3-tz)6}10+ motifs were reported.

Microwave and traditional solvothermal syntheses, crystal structures, mass spectrometry and magnetic properties of CoII4O4 cubes

2013 ◽  
Vol 42 (15) ◽  
pp. 5439 ◽  
Author(s):  
Kun Zhang ◽  
Jun Dai ◽  
Yun-Hong Wang ◽  
Ming-Hua Zeng ◽  
Mohamedally Kurmoo
Keyword(s):  
Mass Spectrometry ◽  
Magnetic Properties ◽  
Crystal Structures ◽  
Solvothermal Syntheses

Synthesis, crystal structures and magnetic properties of a series of pentanuclear heterometallic [CuII3LnIII2] (Ln = Ho, Dy, and Gd) complexes containing mixed organic ligands

2019 ◽  
Vol 43 (21) ◽  
pp. 8101-8108 ◽  
Author(s):  
Yong Chen ◽  
Qiao-Qiao Long ◽  
Zhao-Bo Hu ◽  
Hui-Sheng Wang ◽  
Zhi-Yong Huang ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Crystal Structures ◽  
Magnetic Relaxation ◽  
Organic Ligands ◽  
Relaxation Behaviour ◽  
Slow Magnetic Relaxation

Three novel heterometallic compounds [CuII3LnIII2] [Ln = Ho (1), Dy (2) and Gd (3)] containing mixed organic ligands were obtained. 1 and 2 show slow magnetic relaxation behaviour.

Charge transfer and slow magnetic relaxation in a series of cyano-bridged FeIII4MII2 (M = FeII, CoII, NiII) molecules

2019 ◽  
Vol 6 (2) ◽  
pp. 493-497 ◽  
Author(s):  
Jin-Hua Wang ◽  
Kuduva R. Vignesh ◽  
Jia Zhao ◽  
Zhao-Yang Li ◽  
Kim R. Dunbar
Keyword(s):  
Magnetic Properties ◽  
Charge Transfer ◽  
Single Crystal ◽  
Crystal Structures ◽  
Magnetic Relaxation ◽  
Single Crystal Structures ◽  
Slow Magnetic Relaxation

The synthesis, single-crystal structures and magnetic properties of three new cyano-bridged complexes [FeIII4MII2] (M = FeII, CoII, NiII) are reported.

Solvothermal Syntheses, Crystal Structures and Magnetic Properties of Two Nickel Cubane-Type Cluster Complexes

2019 ◽  
Vol 30 (5) ◽  
pp. 1347-1354 ◽  
Author(s):  
Chengchen Wu ◽  
Xiao Zheng ◽  
Guanghui Chen ◽  
Zhao Chen ◽  
Yu Xiao
Keyword(s):  
Magnetic Properties ◽  
Crystal Structures ◽  
Cluster Complexes ◽  
Solvothermal Syntheses

Syntheses, crystal structures and magnetic properties of two mixed-valence Co(iii)Co(ii) compounds derived from Schiff base ligands: field-supported single-ion-magnet behavior with easy-plane anisotropy

2017 ◽  
Vol 46 (38) ◽  
pp. 13135-13144 ◽  
Author(s):  
Shuvankar Mandal ◽  
Suraj Mondal ◽  
Cyril Rajnák ◽  
Ján Titiš ◽  
Roman Boča ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Schiff Base ◽  
Crystal Structures ◽  
Magnetic Relaxation ◽  
Mixed Valence ◽  
Easy Plane ◽  
Schiff Base Ligands ◽  
Plane Anisotropy ◽  
Amino Phenol ◽  
Slow Magnetic Relaxation

Positive D values and slow magnetic relaxation with two relaxation channels have been observed in two CoIIICoII compounds derived from imino-amino-phenol ligands.

3d–4f heterometallic trinuclear complexes derived from amine-phenol tripodal ligands exhibiting magnetic and luminescent properties

2017 ◽  
Vol 46 (4) ◽  
pp. 1153-1162 ◽  
Author(s):  
He-Rui Wen ◽  
Piao-Ping Dong ◽  
Sui-Jun Liu ◽  
Jin-Sheng Liao ◽  
Fu-Yong Liang ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Crystal Structures ◽  
Magnetic Relaxation ◽  
Luminescent Properties ◽  
Tripodal Ligands ◽  
Trinuclear Complexes ◽  
Slow Magnetic Relaxation

The syntheses, crystal structures, and magnetic properties of a family of new 3d–4f heterometallic trinuclear complexes were investigated. Slow magnetic relaxation was observed for the Zn–Dy–Zn complex besides stronger fluorescent emissions.

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