Catalyst free boron carbon bond cleavage and facile formation of five-membered PNBCC heterocycles

2017 ◽  
Vol 46 (44) ◽  
pp. 15190-15194 ◽  
Author(s):  
Rajarshi Dasgupta ◽  
Atanu Panda ◽  
Shiv Pal ◽  
Puthan Veetil Muhasina ◽  
Susmita De ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Cycloaddition Reaction ◽  
Carbon Bond ◽  
Catalyst Free ◽  
Phosphorus Containing ◽  
Activated Alkynes ◽  
Boron Carbon

The [3 + 2] cycloaddition reaction of N(2,6-iPr2C6H3)(PPh2)(BCy2) (1) with activated alkynes led to the boron, phosphorus containing five-membered heterocycles (2–4) with facile cleavage of B–C bond and concomitant formation of a P–C bond with an ylidic character.

Chemoselective Boron-Carbon Bond Cleavage by Hydroboration of Borirenes

2009 ◽  
Vol 15 (44) ◽  
pp. 12099-12106 ◽  
Author(s):  
Holger Braunschweig ◽  
Thomas Herbst ◽  
Krzysztof Radacki ◽  
Gernot Frenking ◽  
Mehmet Ali Celik
Keyword(s):  
Bond Cleavage ◽  
Carbon Bond ◽  
Boron Carbon

Synthesis of 2-(Cyanomethyl)benzoic Esters via Carbon–Carbon Bond Cleavage of Indanones

2021 ◽  
Author(s):  
Xiangtai Meng ◽  
Dengfeng Chen ◽  
Rui Liu ◽  
Ping Jiang ◽  
Shenlin Huang
Keyword(s):  
Bond Cleavage ◽  
Carbon Bond ◽  
Carbon Carbon Bond

scholarly journals Tricarbonyl triazolato Re(i) compounds of pyridylbenzimidazole ligands: spectroscopic and antimicrobial activity evaluation

RSC Advances ◽  
2021 ◽  
Vol 11 (37) ◽  
pp. 22715-22722
Author(s):  
Ahmed M. Mansour
Keyword(s):  
Antimicrobial Activity ◽  
Cycloaddition Reaction ◽  
Catalyst Free ◽  
Activity Evaluation

The antimicrobial activity and solvatochromism properties of mono- and binuclear tricarbonyl triazolato Re(i) complexes of pyridylbenzimidazole, formed by catalyst-free [3+2] cycloaddition reaction, were examined.

Aerobic Dehydrogenative α-Diarylation of Benzyl Ketones with Aromatics through Carbon–Carbon Bond Cleavage

2014 ◽  
Vol 16 (3) ◽  
pp. 804-807 ◽  
Author(s):  
Nagnath Yadav More ◽  
Masilamani Jeganmohan
Keyword(s):  
Bond Cleavage ◽  
Carbon Bond ◽  
Carbon Carbon Bond

A Catalyst-Free Cycloaddition Reaction: Access to Spiro[chroman-3,2’-indene-1’,3’-dione] Scaffolds

2017 ◽  
Vol 2 (35) ◽  
pp. 11380-11383 ◽  
Author(s):  
Yuzhe Han ◽  
Yingzu Zhu ◽  
Pangmiaomiao Zhang ◽  
Wenjun Li ◽  
Pengfei Li
Keyword(s):  
Cycloaddition Reaction ◽  
Catalyst Free
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