An unusual zig-zag 1D copper(ii) coordination polymer displaying magnetic phase transition

2017 ◽  
Vol 46 (44) ◽  
pp. 15178-15180 ◽  
Author(s):  
Jun Wang ◽  
Bao-Hong Li ◽  
Lu Lu ◽  
Jian-Qiang Liu ◽  
Hiroshi Sakiyama ◽  
...  
Keyword(s):  
Phase Transition ◽  
Coordination Polymer ◽  
Long Range ◽  
Magnetic Phase Transition ◽  
Magnetic Phase ◽  
Magnetic Ordering ◽  
Magnetic Behaviour ◽  
1D Chain

A new Cu(ii)-based 1D chain was prepared and its magnetic behaviour was investigated, which indicated a magnetic phase transition below 25 K as well as long-range magnetic ordering.

Observation of the correlation between the phonon frequency and long-range magnetic ordering on a MnW octacyanide molecule–based magnet

2021 ◽  
Author(s):  
Hiroko Tokoro ◽  
Naotaka Maeda ◽  
Kenta Imoto ◽  
Koji Nakabayashi ◽  
Kouji Chiba ◽  
...  
Keyword(s):  
Phase Transition ◽  
Frequency Shift ◽  
Long Range ◽  
Magnetic Phase Transition ◽  
Phonon Frequency ◽  
Magnetic Phase ◽  
Magnetic Ordering ◽  
Anomalous Change

We show an anomalous change in the phonon frequency at the magnetic phase transition on a cyanide-bridged bimetal assembly, Mn3[W(CN)8]2(pyrimidine)4·6H2O. This compound shows a frequency shift in the CN stretching...

Magnetic behaviour near the magnetic-phase transition in La1 − xSrxCoO3 (0.20 ⩽ x ⩽ 0.30) perovskites

1999 ◽  
Vol 196-197 ◽  
pp. 546-548 ◽  
Author(s):  
M. Vázquez ◽  
J.M. García-Beneytez ◽  
J. Arcas ◽  
F.J. Castaño ◽  
J. Mira ◽  
...  
Keyword(s):  
Phase Transition ◽  
Magnetic Phase Transition ◽  
Magnetic Phase ◽  
Magnetic Behaviour

scholarly journals An Uneven Chain-like Ferromagnetic Copper(II) Coordination Polymer Displaying Metamagnetic Behavior and Long-Range Magnetic Ordering

2021 ◽  
Vol 8 (1) ◽  
pp. 2
Author(s):  
Cai-Ming Liu ◽  
You Song
Keyword(s):  
Molecular Structure ◽  
Coordination Polymer ◽  
Hydrogen Bonds ◽  
Long Range ◽  
Three Dimensional ◽  
Magnetic Ordering ◽  
Antiferromagnetic Interaction ◽  
Ferromagnetic Coupling ◽  
One Dimensional ◽  
1D Chain

Ferromagnetic coupling exists in an uneven chain-like copper(II) complex with both end-on azido and syn-syn carboxylato bridges, (Cu3(L)2(N3)4(H2O)3)n (1, HL = 6-hydroxynicotinic acid). It is the first example of one-dimensional (1D) chain-like copper(II) coordination polymer showing both metamagnetic behavior and long-range magnetic ordering (Tc = 6.7 K), thanks to the interchain hydrogen bonds, which make a three-dimensional (3D) supramolecular array of the entire molecular structure and mediate the interchain antiferromagnetic interaction.

PHASE TRANSITIONS IN INSULATING VANADIUM OXIDE

2002 ◽  
Vol 16 (20n22) ◽  
pp. 3338-3338 ◽  
Author(s):  
A. JOSHI ◽  
M. MA ◽  
F. C. ZHANG
Keyword(s):  
Phase Transition ◽  
Transition Temperature ◽  
Magnetic Phase Transition ◽  
Magnetic Phase ◽  
Magnetic Transition ◽  
Magnetic Ordering ◽  
Orbital Ordering ◽  
First Order ◽  
Bond Model ◽  
Orbital Phase

The magnetic phase transition from the paramagnetic to antiferromagnetic state in insulating V2O3 shows some very interesting features. Not only is the magnetic order ng pattern anomalous, but the magnetic transition shows other surprises: I) the magnetic and orbital ordering occur at the same transition temperature; II) the transition is strongly first order; III) above the transition temperature, neutron scattering observes features in wave vectors different from the ordering wave vector. We study this system using the recently proposed S = 2 bond model (Phys. Rev. Lett.85, 1714 (2000)) for insulating V2O3. We show that this model not only explains the anomalous magnetic ordering, but also resolves the other questions associated with the magnetic phase transition (Phys. Rev. Lett.86, 5743 (2001)). We further point out the possibility of changes in the phase transition phenomenology in presence of a magnetic field, and another orbital phase transition at lower temperatures.

Structural and Magnetic Properties of RBa2Cu2NbO8 (R = La, Pr, Nd)

1992 ◽  
Vol 275 ◽  
Author(s):  
H. B. Radousky ◽  
J. C. O'Brien ◽  
M. Bennahmias ◽  
P. Klavins ◽  
C. A. Smith ◽  
...  
Keyword(s):  
Thin Film ◽  
Phase Transition ◽  
Magnetic Properties ◽  
Buffer Layer ◽  
Magnetic Phase Transition ◽  
Single Phase ◽  
Tunnel Junctions ◽  
Magnetic Phase ◽  
Magnetic Ordering ◽  
Structural And Magnetic Properties

ABSTRACTPrBa2Cu2NbO8 (PrBCNO) is an insulating analog to the YB2CU3O7 (YBCO) system, which is interesting as a thin film buffer layer in YBCO/PrBCNO/YBCO tunnel junctions as well as a potential high Tc superconductor if proper doping could be achieved. PrBCNO has a similar structure to PrBCO, with NbO2 planes replacing the CuO chains. Single phase polycrystalline samples of RBCNO have been synthesized with R = La, Pr and Nd. Attempts to synthesize this structure with the smaller ions Y and Gd have been unsuccessful. The PrBCNO samples show a signature in the magnetization of a magnetic ordering at 12 K. No such magnetic phase transition is observed down to 2 K in the NdBCNO material.

scholarly journals Study of physical properties of a ferrimagnetic spinel Cu1.5Mn1.5O4: spin dynamics, magnetocaloric effect and critical behavior

RSC Advances ◽  
2021 ◽  
Vol 11 (41) ◽  
pp. 25664-25676
Author(s):  
Abir Hadded ◽  
Jalel Massoudi ◽  
Sirine Gharbi ◽  
Essebti Dhahri ◽  
A. Tozri ◽  
...  
Keyword(s):  
Phase Transition ◽  
Transition Temperature ◽  
Physical Properties ◽  
Magnetocaloric Effect ◽  
Phase Transition Temperature ◽  
Magnetic Phase Transition ◽  
Critical Behavior ◽  
Magnetic Phase ◽  
Spin Dynamics ◽  
Critical Behaviour

The present work reports a detailed study of the spin dynamics, magnetocaloric effect and critical behaviour near the magnetic phase transition temperature, of a ferrimagnetic spinel Cu1.5Mn1.5O4.

First-order magnetic phase transition in layered Sr3YCo4O10.5 + δ-type cobaltites

JETP Letters ◽  
2012 ◽  
Vol 94 (12) ◽  
pp. 849-852 ◽  
Author(s):  
I. O. Troyanchuk ◽  
M. V. Bushinsky ◽  
V. M. Dobryanskii ◽  
N. V. Pushkarev
Keyword(s):  
Phase Transition ◽  
Magnetic Phase Transition ◽  
Magnetic Phase ◽  
First Order ◽  
Order Magnetic Phase Transition
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