A novel oxalate-based three-dimensional coordination polymer showing magnetic ordering and high proton conductivity

2017 ◽  
Vol 46 (43) ◽  
pp. 15130-15137 ◽  
Author(s):  
Marta Mon ◽  
Julia Vallejo ◽  
Jorge Pasán ◽  
Oscar Fabelo ◽  
Cyrille Train ◽  
...  
Keyword(s):  
Low Temperature ◽  
Coordination Polymer ◽  
Proton Conductivity ◽  
Three Dimensional ◽  
Magnetic Ordering ◽  
High Proton Conductivity ◽  
Multifunctional Material ◽  
High Proton

A novel example of an oxalate-based multifunctional material is reported here showing the coexistence of low-temperature magnetic ordering and high proton conductivity.

Cations mediating proton conductivity in an oxalate based microporous coordination polymer

2019 ◽  
Vol 43 (1) ◽  
pp. 24-27 ◽  
Author(s):  
Xing Meng ◽  
Hai-Ning Wang ◽  
Xiao-Kun Wang ◽  
Long-Zhang Dong ◽  
Yan-Hong Zou
Keyword(s):  
Structural Change ◽  
Relative Humidity ◽  
Coordination Polymer ◽  
Proton Conductivity ◽  
Cation Substitution ◽  
High Proton Conductivity ◽  
High Proton

Through cation substitution in a zirconium based coordination polymer, an isostructural framework 1@NH4+ has been prepared without any apparent structural change. The proton conductivity of 1@NH4+ is successfully improved. It exhibits high proton conductivity (1.39 × 10−2 S cm−1) at 98% relative humidity and 60 °C.

High Proton Conductivity in Prussian Blue Analogues and the Interference Effect by Magnetic Ordering

2010 ◽  
Vol 132 (19) ◽  
pp. 6620-6621 ◽  
Author(s):  
Shin-ichi Ohkoshi ◽  
Kosuke Nakagawa ◽  
Keisuke Tomono ◽  
Kenta Imoto ◽  
Yoshihide Tsunobuchi ◽  
...  
Keyword(s):  
Prussian Blue ◽  
Proton Conductivity ◽  
Interference Effect ◽  
Magnetic Ordering ◽  
High Proton Conductivity ◽  
Prussian Blue Analogues ◽  
High Proton

A stable polyoxometalate-based porous coordination polymer with high proton conductivity

CrystEngComm ◽  
2018 ◽  
Vol 20 (39) ◽  
pp. 6077-6081 ◽  
Author(s):  
Yu-Hui Luo ◽  
Li-Qiang Yi ◽  
Jia-Ni Lu ◽  
Long-Zhang Dong ◽  
Ya-Qian Lan
Keyword(s):  
Coordination Polymer ◽  
Aqueous Solutions ◽  
Hydrothermal Method ◽  
Proton Conductivity ◽  
Supramolecular Framework ◽  
High Proton Conductivity ◽  
High Proton ◽  
Porous Coordination Polymer ◽  
Conductive Properties

A new porous coordination polymer (1) has been prepared by a hydrothermal method. The supramolecular framework of 1 is stable in aqueous solutions with pH ranging from 1 to 13 and boiling solvents, such as water, methanol and ethanol. The proton conductive properties of 1 are also studied.

scholarly journals High proton conductivity of NaMg1-xLixHx(PO3)3 ·yH2O with the three-dimensional open framework in the intermediate temperature

2021 ◽  
Author(s):  
Naoya Ueda ◽  
Jun Nakajima ◽  
Daisuke Mori ◽  
Sou Taminato ◽  
Nobuyuki Imanishi ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Fuel Cells ◽  
Proton Conductivity ◽  
Solid Electrolytes ◽  
Three Dimensional ◽  
Intermediate Temperature ◽  
High Proton Conductivity ◽  
Open Framework ◽  
High Proton ◽  
Wide Range

Proton solid electrolytes, which exhibit high proton conductivity and thermal stability at a wide range of intermediate temperatures, are desirable for operating fuel cells at a temperature suitable for applications...

A proton transfer mechanism along the PO4 anion chain in the [Zn(HPO4)(H2PO4)]2− coordination polymer

2019 ◽  
Vol 21 (34) ◽  
pp. 18605-18611
Author(s):  
Hieu C. Dong ◽  
Hieu T. Hoang ◽  
Dinh Manh Tran ◽  
Thang B. Phan ◽  
Sareeya Bureekaew ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Proton Transfer ◽  
Proton Conductivity ◽  
Transfer Mechanism ◽  
High Proton Conductivity ◽  
High Proton

In this study, we revisit the proton transfer mechanism in [Zn(HPO4)(H2PO4)]2−, a coordination polymer possessing high proton conductivity.

scholarly journals Multifunctional Chiral Three-Dimensional Phosphite Frameworks Showing Dielectric Anomaly and High Proton Conductivity

2021 ◽  
Vol 9 ◽  
Author(s):  
S. S. Yu ◽  
C. Y. Xu ◽  
X. Pan ◽  
X. Q. Pan ◽  
H. B. Duan ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Proton Transfer ◽  
Proton Conductivity ◽  
Dielectric Response ◽  
Room Temperature ◽  
Three Dimensional ◽  
Dielectric Anomaly ◽  
High Proton Conductivity ◽  
High Proton ◽  
Hydrogen Bonding Networks

Chair 3D Co(II) phosphite frameworks have been prepared by the ionothermal method. It belongs to chiral space group P3221, and the whole framework can be topologically represented as a chiral 4-connected qtz net. It shows a multistep dielectric response arising from the reorientation of Me2-DABCO in the chiral cavities. It can also serve as a pron conductor with high conductivity, 1.71 × 10−3 S cm−1, at room temperature, which is attributed to the formation of denser hydrogen-bonding networks providing efficient proton-transfer pathways.

High proton conductivity in a nickel(ii) complex and its hybrid membrane

2019 ◽  
Vol 48 (6) ◽  
pp. 2190-2196 ◽  
Author(s):  
Shuai-Liang Yang ◽  
Yue-Ying Yuan ◽  
Fei Ren ◽  
Chen-Xi Zhang ◽  
Qing-Lun Wang
Keyword(s):  
Hydrogen Bond ◽  
Proton Conductivity ◽  
Hybrid Membrane ◽  
Water Molecules ◽  
Hybrid Membranes ◽  
High Proton Conductivity ◽  
High Proton ◽  
Hydrogen Bond Networks

A novel 2D nickel(ii) complex (1) has been successfully synthesized using a 2,2′-bipyridyl, polycarboxylsulfonate ligand H4SBTC and Ni2+ ions. Owing to the presence of abundant water molecules, hydrogen bond networks and other protons, 1 and its hybrid membranes demonstrate high proton conductivity.

Synthesis and characterization of chemically stable sulfonated copoly(triazole imide)s with high proton conductivity

2019 ◽  
Vol 59 (11) ◽  
pp. 2279-2289 ◽  
Author(s):  
Asheesh Singh ◽  
Anaparthi G. Kumar ◽  
Sayantani Saha ◽  
Rajdeep Mukherjee ◽  
Soumendu Bisoi ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Synthesis And Characterization ◽  
High Proton Conductivity ◽  
High Proton
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