High-nuclearity heterometallic clusters with both an anion and a cation sandwiched by planar cluster units: synthesis, structure and properties

2017 ◽  
Vol 46 (43) ◽  
pp. 15032-15039 ◽  
Author(s):  
Zilu Chen ◽  
Yanling Shen ◽  
Lingling Li ◽  
Huahong Zou ◽  
Xiaoxiao Fu ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Metal Cation ◽  
Sandwich Structures ◽  
Alkali Metal Cation ◽  
Structure And Properties ◽  
Halide Anion ◽  
Heterometallic Clusters

We report an unprecedented type of nonadecanuclear heterometallic sandwich structures with both halide anion and alkali metal cation sandwiched by planar nonanuclear clusters.

Axle component separated ion-pair recognition by a neutral heteroditopic [2]rotaxane

2014 ◽  
Vol 50 (13) ◽  
pp. 1540-1542 ◽  
Author(s):  
Richard C. Knighton ◽  
Paul D. Beer
Keyword(s):  
Alkali Metal ◽  
Metal Cation ◽  
Alkali Metal Cation ◽  
Ion Pairs ◽  
Ion Pair ◽  
Sodium Cation ◽  
Halide Anion ◽  
Cooperative Recognition

A neutral heteroditopic pyridine N-oxide axle containing [2]rotaxane, synthesised via sodium cation templation, displays cooperative recognition of alkali metal cation-halide anion ion-pairs in an unprecedented axle component separated ion-pair binding fashion.

Conformational effect on the preferential binding of alkali metal cation with crown ether: A molecular level investigation

2009 ◽  
Vol 12 (1-3) ◽  
pp. 93-99 ◽  
Author(s):  
Sulagna De ◽  
Sk. Musharaf Ali ◽  
M.R.K. Shenoi ◽  
Sandip K. Ghosh ◽  
Dilip K. Maity
Keyword(s):  
Crown Ether ◽  
Alkali Metal ◽  
Metal Cation ◽  
Molecular Level ◽  
Alkali Metal Cation ◽  
Conformational Effect ◽  
Preferential Binding

Dynamic chiral-at-metal stability of tetrakis(d/l-hfc)Ln(iii) complexes capped with an alkali metal cation in solution

2012 ◽  
Vol 41 (22) ◽  
pp. 6696 ◽  
Author(s):  
Yiji Lin ◽  
Fang Zou ◽  
Shigang Wan ◽  
Jie Ouyang ◽  
Lirong Lin ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Metal Cation ◽  
Alkali Metal Cation

The Influence of Alkali Metal Cation Size on the Formation and Dissociation of Crown Ether Fullerene Dimers in Electrospray Mass Spectrometry

2015 ◽  
Vol 120 (1) ◽  
pp. 786-792 ◽  
Author(s):  
Ina D. Kellner ◽  
Marc S. von Gernler ◽  
Manolis D. Tzirakis ◽  
Michael Orfanopoulos ◽  
Thomas Drewello
Keyword(s):  
Mass Spectrometry ◽  
Crown Ether ◽  
Alkali Metal ◽  
Metal Cation ◽  
Electrospray Mass Spectrometry ◽  
Alkali Metal Cation ◽  
Fullerene Dimers ◽  
Cation Size
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