A room temperature reversible phase transition containing dielectric switching of a host–guest supramolecular metal–halide compound

2017 ◽  
Vol 46 (38) ◽  
pp. 12760-12765 ◽  
Author(s):  
Yang Lu ◽  
Xiu-Ni Hua ◽  
Wei-Qiang Liao ◽  
Ji-Xing Gao ◽  
Zi Yin
Keyword(s):  
Phase Transition ◽  
Room Temperature ◽  
Metal Halide ◽  
Reversible Phase Transition ◽  
Reversible Phase

A host–guest supramolecular metal–halide compound undergoes a reversible phase transition, accompanied by distinct dielectric switching.

scholarly journals The low-temperature triclinic crystal structure of silver 3-sulfobenzoic acid

2020 ◽  
Vol 76 (8) ◽  
pp. 1275-1278
Author(s):  
Reuben T. Bettinger ◽  
Philip J. Squattrito ◽  
Darpandeep Aulakh
Keyword(s):  
Crystal Structure ◽  
Phase Transition ◽  
Low Temperature ◽  
Room Temperature ◽  
Monoclinic Structure ◽  
Structure Space ◽  
Reversible Phase Transition ◽  
Triclinic Structure ◽  
Reversible Phase ◽  
Acidic Hydrogen

Poly[(μ4-3-carboxybenzenesulfonato)silver(I)], Ag(O3SC6H4CO2H) or [Ag(C7H5O5S)] n , has been found to undergo a reversible phase transition from monoclinic to triclinic between 160 and 150 K. The low-temperature triclinic structure (space group P\overline{1}) has been determined at 100 K. In contrast to the reported room temperature monoclinic structure, in which the nearly equivalent carboxylate C—O distances indicate that the acidic hydrogen is randomly distributed between the O atoms, at 100 K the C—O (protonated) and C=O (unprotonated) bonds are clearly resolved, resulting in the reduction in symmetry from C2/c to P\overline{1}.

Reversible phase transition driven by order–disorder transformations of metal-halide moieties in [(C6H14)NH2]2·CuBr4

2016 ◽  
Vol 4 (32) ◽  
pp. 7537-7540 ◽  
Author(s):  
Muhammad Adnan Asghar ◽  
Shuquan Zhang ◽  
Tariq Khan ◽  
Zhihua Sun ◽  
Aurang Zeb ◽  
...  
Keyword(s):  
Phase Transition ◽  
Order Phase Transition ◽  
Hybrid Material ◽  
Metal Halide ◽  
Inorganic Hybrid ◽  
First Order ◽  
First Order Phase Transition ◽  
Reversible Phase Transition ◽  
First Order Phase ◽  
Reversible Phase

[(C6H14)NH2]2·CuBr4 (1), an organic–inorganic hybrid material, undergoes a reversible first-order phase transition around 194 K, triggered by the order–disorder transformation of metal-coordinated halogen atoms.

Reversible phase transition between amorphous and crystalline in Zr41.2Ti13.8Cu12.5Ni10Be22.5 under high pressure at room temperature

2000 ◽  
Vol 76 (20) ◽  
pp. 2874-2876 ◽  
Author(s):  
Liling Sun ◽  
W. K. Wang ◽  
D. W. He ◽  
W. H. Wang ◽  
Q. Wu ◽  
...  
Keyword(s):  
Phase Transition ◽  
High Pressure ◽  
Room Temperature ◽  
Reversible Phase Transition ◽  
Reversible Phase

Temperature-Dependent Solid-state Luminescence and Reversible Phase Transition of (n-Bu4N)[Au(SC6H3-3,5-Me2)2]

2003 ◽  
Vol 32 (11) ◽  
pp. 1002-1003 ◽  
Author(s):  
Seiji Watase ◽  
Takayuki Kitamura ◽  
Nobuko Kanehisa ◽  
Masami Nakamoto ◽  
Yasushi Kai ◽  
...  
Keyword(s):  
Phase Transition ◽  
Solid State ◽  
Temperature Dependent ◽  
Reversible Phase Transition ◽  
Reversible Phase ◽  
State Luminescence
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