Two dimensional covalent organic framework materials for chemical fixation of carbon dioxide: excellent repeatability and high selectivity

2017 ◽  
Vol 46 (33) ◽  
pp. 10780-10785 ◽  
Author(s):  
Kaikai Xu ◽  
Yihu Dai ◽  
Benfei Ye ◽  
Hongming Wang
Keyword(s):  
Carbon Dioxide ◽  
High Selectivity ◽  
Two Dimensional ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Covalent Organic Framework ◽  
Framework Materials ◽  
Fixation Of Carbon Dioxide ◽  
Organic Framework

Two dimensional (2D) metalloporphyrin-based covalent organic framework (COF) composites were synthesized and employed to catalyze the coupling of CO2 and epoxides to form cyclic carbonates.

Bifunctional Aluminum Catalysts for the Chemical Fixation of Carbon Dioxide into Cyclic Carbonates

2018 ◽  
Vol 6 (4) ◽  
pp. 5322-5332 ◽  
Author(s):  
Felipe de la Cruz-Martínez ◽  
Javier Martínez ◽  
Miguel A. Gaona ◽  
Juan Fernández-Baeza ◽  
Luis F. Sánchez-Barba ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Fixation Of Carbon Dioxide

scholarly journals Recent Advances in the Chemical Fixation of Carbon Dioxide: A Green Route to Carbonylated Heterocycle Synthesis

Catalysts ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 511 ◽  
Author(s):  
Renato Dalpozzo ◽  
Nicola Della Ca’ ◽  
Bartolo Gabriele ◽  
Raffaella Mancuso
Keyword(s):  
Carbon Dioxide ◽  
Value Added ◽  
The Other ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Heterocycle Synthesis ◽  
Green Industry ◽  
Green Route ◽  
Earth’S Climate ◽  
Fixation Of Carbon Dioxide

Carbon dioxide produced by human activities is one of the main contributions responsible for the greenhouse effect, which is modifying the Earth’s climate. Therefore, post-combustion CO2 capture and its conversion into high value-added chemicals are integral parts of today’s green industry. On the other hand, carbon dioxide is a ubiquitous, cheap, abundant, non-toxic, non-flammable and renewable C1 source. Among CO2 usages, this review aims to summarize and discuss the advances in the reaction of CO2, in the synthesis of cyclic carbonates, carbamates, and ureas appeared in the literature since 2017.

Nicotine-derived ammonium salts as highly efficient catalysts for chemical fixation of carbon dioxide into cyclic carbonates under solvent-free conditions

RSC Advances ◽  
2015 ◽  
Vol 5 (75) ◽  
pp. 61179-61183 ◽  
Author(s):  
Abdol R. Hajipour ◽  
Yasaman Heidari ◽  
Gholamreza Kozehgary
Keyword(s):  
Carbon Dioxide ◽  
Organic Solvent ◽  
Solvent Free ◽  
Ammonium Salts ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Highly Efficient ◽  
Solvent Free Conditions ◽  
Recyclable Catalysts ◽  
Fixation Of Carbon Dioxide

Ammonium salts based on nicotine proved to be highly efficient and recyclable catalysts for the synthesis of cyclic carbonates from epoxides and CO2 without the utilization of any organic solvent and any additives.

Supported choline chloride/urea as a heterogeneous catalyst for chemical fixation of carbon dioxide to cyclic carbonates

2007 ◽  
Vol 9 (2) ◽  
pp. 169-172 ◽  
Author(s):  
Anlian Zhu ◽  
Tao Jiang ◽  
Buxing Han ◽  
Jicheng Zhang ◽  
Ye Xie ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Heterogeneous Catalyst ◽  
Choline Chloride ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Fixation Of Carbon Dioxide

scholarly journals Chemical fixation of carbon dioxide to cyclic carbonates catalyzed by zinc(II) complex bearing 1,2-disubstituted benzimidazole ligand

2018 ◽  
Vol 39 (2) ◽  
pp. 245-249 ◽  
Author(s):  
Jorge L.S. Milani ◽  
Igor S. Oliveira ◽  
Pamella A. Dos Santos ◽  
Ana K.S.M. Valdo ◽  
Felipe T. Martins ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Fixation Of Carbon Dioxide

State-of-the-art catechol porphyrin COF catalyst for chemical fixation of carbon dioxide via cyclic carbonates and oxazolidinones

2016 ◽  
Vol 6 (15) ◽  
pp. 6152-6158 ◽  
Author(s):  
Vitthal Saptal ◽  
Digambar Balaji Shinde ◽  
Rahul Banerjee ◽  
Bhalchandra M. Bhanage
Keyword(s):  
Carbon Dioxide ◽  
Transition Metal ◽  
State Of The Art ◽  
Value Added ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Metal Free ◽  
Highly Porous ◽  
Fixation Of Carbon Dioxide

A highly porous, crystalline catechol porphyrin COF was synthesized and applied as an organocatalyst for the fixation of carbon dioxide to synthesize value-added chemicals such as cyclic carbonates and oxazolidinones under solvent and transition-metal-free conditions.

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