Photoluminescence properties of TADF-emitting three-coordinate silver(i) halide complexes with diphosphine ligands: a comparison study with copper(i) complexes

2017 ◽  
Vol 46 (37) ◽  
pp. 12446-12455 ◽  
Author(s):  
Masahisa Osawa ◽  
Masashi Hashimoto ◽  
Isao Kawata ◽  
Mikio Hoshino
Keyword(s):  
Delayed Fluorescence ◽  
Diphosphine Ligands ◽  
Comparison Study ◽  
Photoluminescence Properties ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Halide Complexes

A series of three- and four-coordinate silver(i) halide complexes exhibiting efficient blue thermally activated delayed fluorescence have been prepared.

Near-unity thermally activated delayed fluorescence efficiency in three- and four-coordinate Au(i) complexes with diphosphine ligands

2018 ◽  
Vol 47 (25) ◽  
pp. 8229-8239 ◽  
Author(s):  
Masahisa Osawa ◽  
Masa-aki Aino ◽  
Takaki Nagakura ◽  
Mikio Hoshino ◽  
Yuya Tanaka ◽  
...  
Keyword(s):  
Crystalline State ◽  
Room Temperature ◽  
Delayed Fluorescence ◽  
Diphosphine Ligands ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Fluorescence Efficiency

Three- and four-coordinate Au(i) complexes with diphosphine ligands display near-unity luminescence in the crystalline state at room-temperature.

New Cu(i) halide complexes showing TADF combined with room temperature phosphorescence: the balance tuned by halogens

2020 ◽  
Vol 49 (10) ◽  
pp. 3155-3163 ◽  
Author(s):  
Andrey Yu. Baranov ◽  
Alexey S. Berezin ◽  
Denis G. Samsonenko ◽  
Anton S. Mazur ◽  
Peter M. Tolstoy ◽  
...  
Keyword(s):  
Room Temperature ◽  
Delayed Fluorescence ◽  
Room Temperature Phosphorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Halide Complexes

A series of Cu(i) halide complexes showing thermally activated delayed fluorescence (TADF) combined with room temperature phosphorescence are reported.

Experimental and theoretical studies of highly emissive dinuclear Cu(i) halide complexes with delayed fluorescence

2015 ◽  
Vol 44 (25) ◽  
pp. 11649-11659 ◽  
Author(s):  
Liju Kang ◽  
Jin Chen ◽  
Teng Teng ◽  
Xu-Lin Chen ◽  
Rongmin Yu ◽  
...  
Keyword(s):  
Photophysical Properties ◽  
Delayed Fluorescence ◽  
Theoretical Studies ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Halide Complexes ◽  
Experimental And Theoretical Studies

Experimental and theoretical studies of the photophysical properties of three novel emissive dinuclear Cu(i) halide complexes with thermally activated delayed fluorescence (TADF) are reported.

Temperature dependence of photoluminescence properties in a thermally activated delayed fluorescence emitter

2014 ◽  
Vol 104 (21) ◽  
pp. 213303 ◽  
Author(s):  
Akitsugu Niwa ◽  
Takashi Kobayashi ◽  
Takashi Nagase ◽  
Kenichi Goushi ◽  
Chihaya Adachi ◽  
...  
Keyword(s):  
Temperature Dependence ◽  
Delayed Fluorescence ◽  
Photoluminescence Properties ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated

Solvent Dependence of Structural Dynamics and Spin-flip Processes in 3,4,5-tri(9H-carbazole-9-yl)benzonitrile (ortho-3CzBN)

2020 ◽  
Author(s):  
Masaki Saigo ◽  
Kiyoshi Miyata ◽  
Hajime Nakanotani ◽  
Chihaya Adachi ◽  
Ken Onda
Keyword(s):  
Dft Calculations ◽  
Excited States ◽  
Structural Changes ◽  
Photophysical Properties ◽  
Delayed Fluorescence ◽  
Time Resolved ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Solvent Dependence ◽  
Acetonitrile Solutions

We have investigated the solvent-dependence of structural changes along with intersystem crossing of a thermally activated delayed fluorescence (TADF) molecule, 3,4,5-tri(9H-carbazole-9-yl)benzonitrile (o-3CzBN), in toluene, tetrahydrofuran, and acetonitrile solutions using time-resolved infrared (TR-IR) spectroscopy and DFT calculations. We found that the geometries of the S1 and T1 states are very similar in all solvents though the photophysical properties mostly depend on the solvent. In addition, the time-dependent DFT calculations based on these geometries suggested that the thermally activated delayed fluorescence process of o-3CzBN is governed more by the higher-lying excited states than by the structural changes in the excited states.<br>

New hole transport styrene polymers bearing highly π-extended conjugated side-chain moieties for high-performance solution-processable thermally activated delayed fluorescence OLEDs

2021 ◽  
Vol 12 (11) ◽  
pp. 1692-1699
Author(s):  
Ji Hye Lee ◽  
Jinhyo Hwang ◽  
Chai Won Kim ◽  
Amit Kumar Harit ◽  
Han Young Woo ◽  
...  
Keyword(s):  
High Performance ◽  
High Efficiency ◽  
Delayed Fluorescence ◽  
Hole Transport ◽  
Side Chain ◽  
Solution Processed ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Turn On ◽  
Solution Processable

New polystyrene-based polymers with high π-extended hole transport pendants were synthesized to obtain a low turn-on voltage and high efficiency in solution-processed green TADF-OLEDs.

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