An unprecedented Zn10O4 heteroadamantane cage containing anilido-pyridinate ligand and its activity for ring opening polymerization of l-lactide and ε-caprolactone

2017 ◽  
Vol 46 (31) ◽  
pp. 10181-10184 ◽  
Author(s):  
Ming-Tsz Chen ◽  
Chi-Tien Chen
Keyword(s):  
Zinc Oxide ◽  
Self Assembly ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Oxide Cluster

An unprecedented self-assembly anilido-pyridinate zinc oxide cluster was investigated for ring opening polymerization.

Ring-opening polymerization-induced self-assembly (ROPISA) of salicylic acid o-carboxyanhydride

2021 ◽  
Author(s):  
Qianqian Shi ◽  
Yibing Chen ◽  
Junjiao Yang ◽  
Jing Yang
Keyword(s):  
Salicylic Acid ◽  
Self Assembly ◽  
Ring Opening ◽  
Ring Opening Polymerization

Reported here is the first polyester-based bioactive nanoparticles accessed via ring-opening polymerization-induced self-assembly (ROPISA) of salicylic acid o-carboxyanhydride (SAOCA) monomers. Superfast ROPISA of SAOCA was completed in 30 seconds to form worm-like morphology.

Polysarcosine: The Best Alternative of Poly (Ethylene Glycol)

2020 ◽  
Vol 04 ◽  
Author(s):  
Manu Singhai ◽  
Sankha Bhattacharya
Keyword(s):  
Ethylene Glycol ◽  
Self Assembly ◽  
Protein Delivery ◽  
Ring Opening ◽  
Biomedical Applications ◽  
High Vacuum ◽  
Ring Opening Polymerization ◽  
Poly Ethylene Glycol ◽  
Biologically Relevant ◽  
Poly Ethylene

Abstract:: Polysarcosine (psar) is a non-ionic hydrophilic polypeptoid with numerous biologically relevant properties. Polysarcosine is poly (n-methylated glycine) and has been reported first by wesley and co-workers in the 1920s. Polysarcosine was first synthesized via ring-opening polymerization (rop) of sarcosine n-carboxyanhydride, using high-vacuum techniques. Overall, findings highlight the potential of poly(sarcosine) as an alternative corona-forming polymer to poly (ethylene glycol)-based analogues of (polymerization-induced self-assembly) pisa assemblies for use in various pharmaceutical and biomedical applications. Numerous studies suggested that such polypeptoids hold enormous potential for many biomedical applications, including protein delivery, colloidal stabilization, and nanomedicine.

Self-Assembly of Amphiphilic Block Copolymer in Aqueous Solutions Tuned by Host-Guest Inclusion Complexation

2012 ◽  
Vol 487 ◽  
pp. 663-667
Author(s):  
Yu Long Shuai ◽  
Mi Zhou ◽  
Xin Qian
Keyword(s):  
Block Copolymer ◽  
Self Assembly ◽  
Ring Opening ◽  
Chain Transfer ◽  
Gene Transfection ◽  
Inclusion Complexation ◽  
Ring Opening Polymerization ◽  
Isopropyl Acrylamide ◽  
Reversible Addition ◽  
Copolymer Poly

The block copolymer poly (ε-caprolactone)-b-poly (N-isopropyl acrylamide) (PCL-b-PNIPAM) is synthesized via the combination of ring-opening polymerization (ROP) and reversible addition-fragmentation chain transfer (RAFT). PCL-b-PNIPAM can self-assemble into the micelles taking PCL as the cores and PNIPAM as the shells. Add α-CD into the micelles, because the inclusion complexation of α-CD to PCL chains and phenols is stronger than that to PCL, to regulate the hydrophilic and hydrophobic features of PCL chain. So PCL-b-PNIPAM block copolymers have potential application in drug delivery and gene transfection.

scholarly journals Aqueous Ring‐Opening Polymerization‐Induced Self‐Assembly (ROPISA) of N‐Carboxyanhydrides

2020 ◽  
Vol 59 (2) ◽  
pp. 622-626 ◽  
Author(s):  
Chloé Grazon ◽  
Pedro Salas‐Ambrosio ◽  
Emmanuel Ibarboure ◽  
Alix Buol ◽  
Elisabeth Garanger ◽  
...  
Keyword(s):  
Self Assembly ◽  
Ring Opening ◽  
Ring Opening Polymerization
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