1,2-Diaza-4-phosphaferrocenes: synthesis, structural characterization, 57Fe Mössbauer spectrum analysis, and DFT calculation

2017 ◽  
Vol 46 (26) ◽  
pp. 8354-8358 ◽  
Author(s):  
Lian Duan ◽  
Xiang Zhang ◽  
Wenjun Zheng
Keyword(s):  
Structural Characterization ◽  
Spectrum Analysis ◽  
Lewis Acids ◽  
Dft Calculation ◽  
Mossbauer Spectrum ◽  
Mössbauer Spectrum ◽  
57Fe Mössbauer ◽  
Lone Pairs

1,2-Diaza-4-phosphaferrocenes [(η5-3,5-R2dp)Fe(η5-CpMe5)] (R = tBu (3), Ph (4)) with a single η5 ring containing two nitrogen atoms are kinetically and thermodynamically very stable without the use of Lewis acids such as BH3 or BF3 to protect the nitrogen lone pairs.

The 57Fe Mössbauer spectrum of iodopentakis(p-tolylisocyanide)iron(II) tri-iodide

1973 ◽  
Vol 7 ◽  
pp. 563-564 ◽  
Author(s):  
John W. Schindler ◽  
John R. Luoma ◽  
James P. Cusick
Keyword(s):  
Mossbauer Spectrum ◽  
Mössbauer Spectrum ◽  
57Fe Mössbauer

Structural, Magnetic and Mossbauer Studies of Magnesium Ferrite Nanoparticles Prepared by Hydrothermal Method

2017 ◽  
Vol 17 (01n02) ◽  
pp. 1760001 ◽  
Author(s):  
Jessyamma Kurian ◽  
M. Jacob Mathew
Keyword(s):  
Magnetic Properties ◽  
Crystallite Size ◽  
Hydrothermal Method ◽  
Spectrum Analysis ◽  
Fine Particles ◽  
Lattice Parameter ◽  
Mossbauer Spectrum ◽  
Magnesium Ferrite ◽  
Mössbauer Spectrum ◽  
Mössbauer Studies

Magnesium ferrite (MgFe2O[Formula: see text] being a soft magnetic material with fast frequency response, high a.c. heat power generation and high biocompatibility, is widely used in biomedical fields such as targeted drug delivery, magnetic hyperthermia, etc. This paper reports the synthesis of magnetic MgFe2O4 nanoparticles by hydrothermal method using chloride salts of metal ions. The effect of calcination on the structural and magnetic properties is studied by XRD, FTIR, VSM and Mossbauer spectrum analysis. Fine particles in the size range 3–24[Formula: see text]nm are obtained. On calcination, crystallite size increases and lattice parameter decreases. From the magnetic characterization, it is seen that the magnetic properties mainly depend on crystallite size and cation distribution. The mixed spinel states of the prepared materials are confirmed from the FTIR and Mossbauer spectrum analysis. The doublet spectrum obtained in the Mossbauer studies indicates the superparamagnetic relaxation at room temperature.

User-friendly software for Mössbauer spectrum analysis

1996 ◽  
Vol 210 (1) ◽  
pp. 105-118 ◽  
Author(s):  
Z. Klencsár ◽  
E. Kuzmann ◽  
A. Vértes
Keyword(s):  
Spectrum Analysis ◽  
Mossbauer Spectrum ◽  
Mössbauer Spectrum ◽  
User Friendly
Sign in / Sign up

Export Citation Format

Share Document