scholarly journals Temperature dependent NIR emitting lanthanide-PMO/silica hybrid materials

2017 ◽  
Vol 46 (24) ◽  
pp. 7878-7887 ◽  
Author(s):  
Anna M. Kaczmarek ◽  
Dolores Esquivel ◽  
Judith Ouwehand ◽  
Pascal Van Der Voort ◽  
Francisco J. Romero-Salguero ◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Hybrid Materials ◽  
Temperature Dependent ◽  
Periodic Mesoporous Organosilica ◽  
Mesoporous Organosilica ◽  
Silica Hybrid

A mesoporous silica and a periodic mesoporous organosilica functionalized with dipyridyl-pyridazine were grafted with Nd3+, Er3+, and Yb3+ complexes to obtain hybrid NIR emitting materials.

Chemical sensors based on nano-sized lanthanide-grafted periodic mesoporous organosilica hybrid materials

2019 ◽  
Vol 7 (26) ◽  
pp. 8109-8119 ◽  
Author(s):  
Anna M. Kaczmarek ◽  
Pascal Van Der Voort
Keyword(s):  
Hybrid Materials ◽  
Chemical Sensors ◽  
Aprotic Solvent ◽  
Periodic Mesoporous Organosilica ◽  
Ion Sensing ◽  
Mesoporous Organosilica

Nano-sized PMOs grafted with lanthanides show selective ion sensing for Pb2+ and Cr3+ and strong solvatochromism allowing their use as protic and aprotic solvent sensors.

scholarly journals Lanthanide complex-incorporated periodic mesoporous organosilica nanospheres with tunable photoluminescence

RSC Advances ◽  
2015 ◽  
Vol 5 (101) ◽  
pp. 83368-83376 ◽  
Author(s):  
Ning Yuan ◽  
Yucang Liang ◽  
Egil Severin Erichsen ◽  
Reiner Anwander
Keyword(s):  
Rare Earth ◽  
Mesoporous Silica ◽  
Rare Earth Metal ◽  
Lanthanide Complex ◽  
Earth Metal ◽  
Periodic Mesoporous Organosilica ◽  
Spherical Morphology ◽  
Mesoporous Organosilica

Functional DPA (N,N-bis(trimethoxysilylpropyl)-2,6-pyridine dicarboxamide) can be successfully incorporated into mesoporous silica frameworks of regular spherical morphology to accommodate photoluminescent rare-earth metal centres.

Probing framework–guest interactions in phenylene-bridged periodic mesoporous organosilica using spin-probe EPR

2014 ◽  
Vol 16 (41) ◽  
pp. 22623-22631 ◽  
Author(s):  
Feng Lin ◽  
Xiangyan Meng ◽  
Myrjam Mertens ◽  
Pegie Cool ◽  
Sabine Van Doorslaer
Keyword(s):  
Mesoporous Silica ◽  
Spin Probe ◽  
Probe Molecules ◽  
Periodic Mesoporous Organosilica ◽  
Mesoporous Organosilica

Spin-probe EPR reveals significant differences in the adsorption of probe molecules in benzene-bridged periodic mesoporous silica with crystal-like or amorphous walls.

Photoresponsive polyelectrolyte/mesoporous silica hybrid materials with remote-controllable ionic transportation

2017 ◽  
Vol 322 ◽  
pp. 445-453 ◽  
Author(s):  
Wei Li ◽  
Tairong Kuang ◽  
Xiaoping Jiang ◽  
Jintao Yang ◽  
Ping Fan ◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Hybrid Materials ◽  
Silica Hybrid

scholarly journals Light-Emitting Lanthanide Periodic Mesoporous Organosilica (PMO) Hybrid Materials

Materials ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 566 ◽  
Author(s):  
Anna M. Kaczmarek ◽  
Pascal Van Der Voort
Keyword(s):  
Hybrid Materials ◽  
Mechanical Stability ◽  
Mesoporous Structure ◽  
Exciting Light ◽  
Periodic Mesoporous Organosilica ◽  
Light Emitting ◽  
Mesoporous Organosilica ◽  
Wide Range ◽  
Optical Applications ◽  
Mesoporous Organosilicas

Periodic mesoporous organosilicas (PMOs) have a well ordered mesoporous structure, a high thermal and mechanical stability and a uniform distribution of organic functionalities in the pore walls. The organic groups allow PMOs to be modified and functionalized by using a wide range of organic reactions. Since their first report in 1999, PMOs have found a vast range of applications, such as for catalysis, adsorbents, low-k films, biomedical supports and also for optical applications. Optical applications are very interesting as PMOs offer the possibility of designing advanced luminescent hybrid materials comprising of organic components, yet with much higher stability and very good processability. Despite their promising possibilities, the optical properties of pristine PMOs and PMOs grafted with d-metal or f-metal ions and complexes have been explored less frequently. In this review, we aimed to overview the exciting light emitting properties of various reported lanthanide PMO hybrid materials and interest the reader in this promising application for lanthanide PMO materials.

Polyelectrolyte/mesoporous silica hybrid materials for the high performance multiple-detection of pH value and temperature

2015 ◽  
Vol 6 (18) ◽  
pp. 3529-3536 ◽  
Author(s):  
Feng Chen ◽  
Xiaoping Jiang ◽  
Tairong Kuang ◽  
Lingqian Chang ◽  
Dajiong Fu ◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Silica Nanoparticles ◽  
Hybrid Materials ◽  
High Performance ◽  
Ph Value ◽  
Mesoporous Silica Nanoparticles ◽  
Multiple Detection ◽  
Silica Hybrid

Mesoporous silica nanoparticles are modified by electrolyte polymer, giving significant ionic permselectivity under pH and/or temperature switches.

Yolk-Shell Hybrid Materials with a Periodic Mesoporous Organosilica Shell: Ideal Nanoreactors for Selective Alcohol Oxidation

2011 ◽  
Vol 22 (3) ◽  
pp. 591-599 ◽  
Author(s):  
Jian Liu ◽  
Heng Quan Yang ◽  
Freddy Kleitz ◽  
Zhi Gang Chen ◽  
Tianyu Yang ◽  
...  
Keyword(s):  
Hybrid Materials ◽  
Alcohol Oxidation ◽  
Periodic Mesoporous Organosilica ◽  
Mesoporous Organosilica

Architecture of yolk–shell structured mesoporous silica nanospheres for catalytic applications

2018 ◽  
Vol 47 (27) ◽  
pp. 9072-9078 ◽  
Author(s):  
Xue Wang ◽  
Yapeng He ◽  
Yali Ma ◽  
Junmin Liu ◽  
Yunling Liu ◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Metal Nanoparticles ◽  
Noble Metal ◽  
Selective Etching ◽  
Noble Metal Nanoparticles ◽  
Silica Nanospheres ◽  
Periodic Mesoporous Organosilica ◽  
Mesoporous Organosilica ◽  
Catalytic Applications ◽  
Mesoporous Silica Nanospheres

We report the design and realization of yolk–shell structured nanospheres with periodic mesoporous organosilica (PMO) nanospheres or noble metal nanoparticles encapsulated in mesoporous silica shellsviaa selective etching method.

scholarly journals Structure and Dynamics of Water Confined in Mesoporous Silica and Periodic Mesoporous Organosilica

2012 ◽  
Vol 61 (12) ◽  
pp. 989-998
Author(s):  
Koji YOSHIDA ◽  
Aoi SODA ◽  
Mai ASO ◽  
Kanae ITO ◽  
Shigeharu KITTAKA ◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Periodic Mesoporous Organosilica ◽  
Structure And Dynamics ◽  
Mesoporous Organosilica
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