Liquid-phase oxidation of alkylaromatics to aromatic ketones with molecular oxygen over a Mn-based metal–organic framework

2017 ◽  
Vol 46 (26) ◽  
pp. 8415-8421 ◽  
Author(s):  
Yasutaka Kuwahara ◽  
Yukihiro Yoshimura ◽  
Hiromi Yamashita
Keyword(s):  
Liquid Phase ◽  
Molecular Oxygen ◽  
Heterogeneous Catalyst ◽  
Metal Organic Framework ◽  
Liquid Phase Oxidation ◽  
Aromatic Ketones ◽  
Phase Oxidation ◽  
Metal Organic ◽  
Organic Framework

A microporous Mn-based metal–organic framework (Mn-MOF-74) acts as a heterogeneous catalyst active for liquid-phase oxidation of alkylaromatics with molecular O2.

A reusable CuII based metal–organic framework as a catalyst for the oxidation of olefins

2014 ◽  
Vol 4 (8) ◽  
pp. 2599-2607 ◽  
Author(s):  
Patricio Cancino ◽  
Verónica Paredes-García ◽  
Pedro Aguirre ◽  
Evgenia Spodine
Keyword(s):  
Liquid Phase ◽  
Heterogeneous Catalyst ◽  
Metal Organic Framework ◽  
Liquid Phase Oxidation ◽  
Phase Oxidation ◽  
Oxidation Of Olefins ◽  
Metal Organic ◽  
Organic Framework

The metal–organic framework [Cu2(bipy)2(btec)]∞ was used as a heterogeneous catalyst in the liquid phase oxidation of styrene and cyclohexene with tert-butylhydroperoxide (TBHP) as the oxidant either in water–dichloroethane or n-decane medium.

In situ-created Mn(iii) complexes active for liquid-phase oxidation of alkylaromatics to aromatic ketones with molecular oxygen

2016 ◽  
Vol 6 (2) ◽  
pp. 442-448 ◽  
Author(s):  
Yasutaka Kuwahara ◽  
Yukihiro Yoshimura ◽  
Hiromi Yamashita
Keyword(s):  
Liquid Phase ◽  
Molecular Oxygen ◽  
Liquid Phase Oxidation ◽  
Aromatic Ketones ◽  
Phase Oxidation

Mn(OH)x supported on oxides in situ transforms into a monomeric Mn(iii) species coordinated with the PhCOO− ligand, which efficiently oxidizes alkylaromatics with O2.

A new superacid hafnium-based metal–organic framework as a highly active heterogeneous catalyst for the synthesis of benzoxazoles under solvent-free conditions

2017 ◽  
Vol 7 (19) ◽  
pp. 4346-4350 ◽  
Author(s):  
Linh H. T. Nguyen ◽  
The T. Nguyen ◽  
Ha L. Nguyen ◽  
Tan L. H. Doan ◽  
Phuong Hoang Tran
Keyword(s):  
Heterogeneous Catalyst ◽  
Metal Organic Framework ◽  
Solvent Free ◽  
Highly Active ◽  
Solvent Free Conditions ◽  
Metal Organic ◽  
Efficient Heterogeneous Catalyst ◽  
Organic Framework

A new superacid Hf-based MOF, termed VNU-11-P-SO4, was used as an efficient heterogeneous catalyst for solvent-free 2-arylbenzoxazole synthesis.

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