Dicyanoaurate-based heterobimetallic uranyl coordination polymers

2017 ◽  
Vol 46 (22) ◽  
pp. 7169-7180 ◽  
Author(s):  
Matthew L. Brown ◽  
Jeffrey S. Ovens ◽  
Daniel B. Leznoff

The first series of uranyl ([UO2]2+)-dicyanoaurate coordination polymers and molecular complexes has been synthesized, with small changes in reaction solvent resulting in large changes in structural morphology.

CrystEngComm ◽  
2020 ◽  
Vol 22 (27) ◽  
pp. 4531-4543
Author(s):  
Nikita Y. Gugin ◽  
Alexander Virovets ◽  
Eugenia Peresypkina ◽  
Elena I. Davydova ◽  
Alexey Y. Timoshkin

Diverse molecular (0D and 1D) as well as ionic (0D, 1D, 2D, mixed 1D–2D) crystal structures of complexes of aluminium and gallium trihalides with bis(4-pyridylethylene) were obtained by solvent-free melt reactions.


2016 ◽  
Vol 45 (17) ◽  
pp. 7240-7243 ◽  
Author(s):  
Zbigniew Wróbel ◽  
Iwona Justyniak ◽  
Izabela Dranka ◽  
Janusz Lewiński

The equimolar reaction of R2Zn (where R = Et or tBu) with pyrrole-based N,O-proligands afforded a series of alkylzinc compounds with a variety of structures including a macrocyclic complex and 1D coordination polymers with versatile intramolecular or intermolecular bonding modes.


CrystEngComm ◽  
2007 ◽  
Vol 9 (6) ◽  
pp. 503 ◽  
Author(s):  
Subhashree Mallika Krishnan ◽  
Niral M. Patel ◽  
Warren R. Knapp ◽  
Ronald M. Supkowski ◽  
Robert L. LaDuca

2009 ◽  
Vol 58 (9) ◽  
pp. 1858-1865 ◽  
Author(s):  
M. I. Naumova ◽  
E. A. Mainicheva ◽  
O. A. Gerasko ◽  
V. P. Fedin

Author(s):  
S.G. Pal ◽  
G. Baur ◽  
B. Ghosh ◽  
S. Palit ◽  
S. Modak ◽  
...  

In recent years some of the blood cells of several molluscs and insects are characterised as immunocytes. Similar cells from a few invertebrates from India have been looked into under conventional TEM to register the ultrastructural features. This type of study is first of its kind in the subcontinent. Immunocytes from bivalve molluscs Meretrix meretrix, Laroellidens marqinalis and two insect species, apterygote Ctenolepism a longicaudata and pterygote Gesonula punctifrons provide a new set of fine structural information which forms a basis of comparison with those studied earlier.Immunocytes have been collected from the fresh live species of bivalve molluscs and insects obtained locally at Calcutta. These were fixed in icecold 2% glutaraldehyde in 0.1M phosphate buffer (pH 7.2-7.4) for 1-2 hours at 4-5°C. Subseguently pellets were post-osmicated in 1% OsO4 at room temperature for 1-2 hours. Following dehydration these were embedded in Araldite mixture in plastic capsules and polymerization was effected for 2 days at 60°C. Ultrathin sections were cut in a ultrotome and sections were double stained with Uranyl acetate and lead citrate. These were viewed in a TEM.


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