Practices for the collection and reporting of electrocatalytic performance and mechanistic information for the CO2reduction reaction

2017 ◽  
Vol 7 (24) ◽  
pp. 5820-5832 ◽  
Author(s):  
James E. Pander III ◽  
Dan Ren ◽  
Boon Siang Yeo
Keyword(s):  
Carbon Dioxide ◽  
Electrochemical Reduction ◽  
Electrocatalytic Performance ◽  
Report Data

This work discusses how to best perform experiments and report data for the electrochemical reduction of carbon dioxide.

Highly Efficient Electrochemical Reduction of Carbon Dioxide to Formate on Sn Modified Bi2O3 Heterostructure

2021 ◽  
Author(s):  
Doufeng Wu ◽  
Pengzuo Chen ◽  
Dongmei Feng ◽  
Jiajia Song ◽  
Yun Tong
Keyword(s):  
Carbon Dioxide ◽  
Electrochemical Reduction ◽  
Co2 Reduction ◽  
Highly Efficient ◽  
Electrocatalytic Performance

In this work, the Sn species are deposited onto the surface of Bi2O3 material by a facile disproportionated reaction and the prepared catalyst shows superior electrocatalytic performance for CO2 reduction....

Photochemical and Electrochemical Reduction of Carbon Dioxide Catalyzed by a Polyoxometalate-Organic Photosensitizer Complex

2018 ◽  
Author(s):  
Chandan Dey ◽  
Ronny Neumann
Keyword(s):  
Carbon Dioxide ◽  
Cyclic Voltammetry ◽  
Formic Acid ◽  
Electrochemical Reduction ◽  
Mass Spectroscopy ◽  
Photochemical Reactions ◽  
Reducing Agent ◽  
Covalent Attachment ◽  
Hybrid Complex ◽  
Open Face

<p>A manganese substituted Anderson type polyoxometalate, [MnMo<sub>6</sub>O<sub>24</sub>]<sup>9-</sup>, tethered with an anthracene photosensitizer was prepared and used as catalyst for CO<sub>2</sub> reduction. The polyoxometalate-photosensitizer hybrid complex, obtained by covalent attachment of the sensitizer to only one face of the planar polyoxometalate, was characterized by NMR, IR and mass spectroscopy. Cyclic voltammetry measurements show a catalytic response for the reduction of carbon dioxide, thereby suggesting catalysis at the manganese site on the open face of the polyoxometalate. Controlled potentiometric electrolysis showed the reduction of CO<sub>2</sub> to CO with a TOF of ~15 sec<sup>-1</sup>. Further photochemical reactions showed that the polyoxometalate-anthracene hybrid complex was active for the reduction of CO<sub>2</sub> to yield formic acid and/or CO in varying amounts dependent on the reducing agent used. Control experiments showed that the attachment of the photosensitizer to [MnMo<sub>6</sub>O<sub>24</sub>]<sup>9-</sup> is necessary for photocatalysis.</p><div><br></div>

An overview of flow cell architectures design and optimization for electrochemical CO2 reduction

2021 ◽  
Author(s):  
Dui Ma ◽  
Ting Jin ◽  
Keyu Xie ◽  
Haitao Huang
Keyword(s):  
Carbon Dioxide ◽  
Global Warming ◽  
Electrochemical Reduction ◽  
Atmospheric Carbon Dioxide ◽  
Co2 Reduction ◽  
Value Added ◽  
Flow Cell ◽  
Design And Optimization ◽  
Electrochemical Co2 Reduction ◽  
Carbon Dioxide Levels

Converting CO2 into value-added fuels or chemical feedstocks through electrochemical reduction is one of the several promising avenues to reduce atmospheric carbon dioxide levels and alleviate global warming. This approach...

Metal-organic frameworks for electrochemical reduction of carbon dioxide: The role of metal centers

2020 ◽  
Vol 40 ◽  
pp. 156-170 ◽  
Author(s):  
Ping Shao ◽  
Luocai Yi ◽  
Shumei Chen ◽  
Tianhua Zhou ◽  
Jian Zhang
Keyword(s):  
Carbon Dioxide ◽  
Electrochemical Reduction ◽  
Metal Organic Frameworks ◽  
Metal Centers ◽  
Metal Organic

A General and Facile Approach for the Electrochemical Reduction of Carbon Dioxide Inspired by Deep Eutectic Solvents

ChemSusChem ◽  
2019 ◽  
Vol 12 (8) ◽  
pp. 1635-1639 ◽  
Author(s):  
Dmitry V. Vasilyev ◽  
Alexander V. Rudnev ◽  
Peter Broekmann ◽  
Paul J. Dyson
Keyword(s):  
Carbon Dioxide ◽  
Electrochemical Reduction ◽  
Deep Eutectic Solvents
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