Contact engineering for 2D materials and devices

2018 ◽  
Vol 47 (9) ◽  
pp. 3037-3058 ◽  
Author(s):  
Daniel S. Schulman ◽  
Andrew J. Arnold ◽  
Saptarshi Das
Keyword(s):  
2D Materials ◽  
Layered Materials ◽  
Two Dimensional ◽  
The Past ◽  
2D Layered Materials ◽  
Physical Phenomena ◽  
Contact Engineering

Over the past decade, the field of two-dimensional (2D) layered materials has surged, promising a new platform for studying diverse physical phenomena that are scientifically intriguing and technologically relevant.

scholarly journals Research Advances of Typical Two Dimensional Layered Thermoelectric Materials

2020 ◽  
Vol 2 (2) ◽  
Author(s):  
Haihua HUANG ◽  
Xiaofeng FAN
Keyword(s):  
Structural Properties ◽  
Thermoelectric Properties ◽  
Thermoelectric Materials ◽  
Electronic Devices ◽  
Layered Materials ◽  
Two Dimensional ◽  
The Past ◽  
2D Layered Materials ◽  
Potential Applications ◽  
Properties Of Materials

Thermoelectric technologies have caught our intense attention due to their ability of heat conversion into electricity. The considerable efforts have been taken to develop and enhance thermoelectric properties of materials over the past several decades. Recently, two-dimensional layered materials are making the promise for potential applications of thermoelectric devices because of the excellent physical and structural properties. Here, a comprehensive coverage about recent progresses in thermoelectric properties of typical two dimensional (2D) layered materials, including the theoretical and experimental results, is provided. Moreover, the potential applications of 2D thermoelectric materials are also involved. These results indicate that the development of 2D thermoelectric materials take a key role in the flexible electronic devices with thermoelectric technologies.

Field emission applications of graphene analogous two dimensional materials: Recent developments and future perspectives

2021 ◽  
Author(s):  
Abhinandan Patra ◽  
Mahendra A More ◽  
Dattatray J Late ◽  
Chandra Sekhar Rout
Keyword(s):  
Field Emission ◽  
2D Materials ◽  
Layered Materials ◽  
Two Dimensional ◽  
Future Perspectives ◽  
2D Layered Materials ◽  
Two Dimensional Materials ◽  
Recent Developments ◽  
Technology Industries ◽  
Device Technology

2D layered materials are widely regarded as the revolutionary class of materials and hold great promises in the modern device technology industries. 2D materials family covers almost the entire spectrum...

scholarly journals MOLECULAR FUNCTIONALIZATION OF 2D MATERIALS

2021 ◽  
pp. 2140002
Author(s):  
MIRIAM C. RODRÍGUEZ GONZÁLEZ ◽  
RAHUL SASIKUMAR ◽  
STEVEN DE FEYTER
Keyword(s):  
2D Materials ◽  
Layered Materials ◽  
Two Dimensional ◽  
Chemical Modifications ◽  
2D Layered Materials ◽  
Non Covalent Interactions ◽  
Covalent Interactions

In this paper, we give an overview of different chemical modifications that can be done on the surface of two-dimensional (2D) layered materials. We place emphasis on the diversity of reactions that have been proposed and are now available to surface scientists working in 2D materials field. Using mainly, but not exclusively, MoS2 as example, reactions involving covalent and non-covalent interactions are discussed.

scholarly journals Thin film transistors based on two dimensional graphene and graphene/semiconductor heterojunctions

RSC Advances ◽  
2017 ◽  
Vol 7 (28) ◽  
pp. 17387-17397 ◽  
Author(s):  
Zhongcheng Zhu ◽  
Imran Murtaza ◽  
Hong Meng ◽  
Wei Huang
Keyword(s):  
Thin Film ◽  
Thin Film Transistors ◽  
Optoelectronic Devices ◽  
Building Blocks ◽  
Layered Materials ◽  
Two Dimensional ◽  
The Past ◽  
2D Layered Materials ◽  
Semiconductor Heterojunctions

During the past few years, two-dimensional (2D) layered materials have emerged as the most fundamental building blocks of a wide variety of optoelectronic devices.

scholarly journals A Universal Atomic Substitution Conversion Strategy Towards Synthesis of Large-Size Ultrathin Nonlayered Two-Dimensional Materials

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Mei Zhao ◽  
Sijie Yang ◽  
Kenan Zhang ◽  
Lijie Zhang ◽  
Ping Chen ◽  
...  
Keyword(s):  
Theoretical Calculations ◽  
2D Materials ◽  
Direct Synthesis ◽  
Two Dimensional ◽  
Covalent Bonds ◽  
2D Layered Materials ◽  
Large Size ◽  
Two Dimensional Materials ◽  
Microfabrication Technique ◽  
Atomic Substitution

AbstractNonlayered two-dimensional (2D) materials have attracted increasing attention, due to novel physical properties, unique surface structure, and high compatibility with microfabrication technique. However, owing to the inherent strong covalent bonds, the direct synthesis of 2D planar structure from nonlayered materials, especially for the realization of large-size ultrathin 2D nonlayered materials, is still a huge challenge. Here, a general atomic substitution conversion strategy is proposed to synthesize large-size, ultrathin nonlayered 2D materials. Taking nonlayered CdS as a typical example, large-size ultrathin nonlayered CdS single-crystalline flakes are successfully achieved via a facile low-temperature chemical sulfurization method, where pre-grown layered CdI2 flakes are employed as the precursor via a simple hot plate assisted vertical vapor deposition method. The size and thickness of CdS flakes can be controlled by the CdI2 precursor. The growth mechanism is ascribed to the chemical substitution reaction from I to S atoms between CdI2 and CdS, which has been evidenced by experiments and theoretical calculations. The atomic substitution conversion strategy demonstrates that the existing 2D layered materials can serve as the precursor for difficult-to-synthesize nonlayered 2D materials, providing a bridge between layered and nonlayered materials, meanwhile realizing the fabrication of large-size ultrathin nonlayered 2D materials.

Molecular Functionalization of 2D-Materials: From Atomically Planar 2D Architectures to Off-Plane 3D Functional Materials

2021 ◽  
Author(s):  
Adam Brill ◽  
Elad Koren ◽  
Graham de Ruiter
Keyword(s):  
2D Materials ◽  
Functional Materials ◽  
Two Dimensional ◽  
The Past ◽  
Two Dimensional Materials

Atomically thin two-dimensional materials (2DMs) have moved in the past 15 years from a serendipitously isolated single-layered graphene curiosity to a near technological renaissance, where 2DMs such as graphene and...

scholarly journals Molecular Scaffold Growth of Two-Dimensional, Strong Interlayer-Bonding-Layered Materials

CCS Chemistry ◽  
2019 ◽  
pp. 117-127 ◽  
Author(s):  
Mengqi Zeng ◽  
Yunxu Chen ◽  
Enze Zhang ◽  
Jiaxu Li ◽  
Rafael G. Mendes ◽  
...  
Keyword(s):  
2D Materials ◽  
Layered Materials ◽  
Max Phase ◽  
Future Application ◽  
Two Dimensional ◽  
Max Phases ◽  
Molecular Scaffold ◽  
Fundamental Properties ◽  
Synthesis Strategy ◽  
Interlayer Bonding

Currently, most two-dimensional (2D) materials that are of interest to emergent applications have focused on van der Waals–layered materials (VLMs) because of the ease with which the layers can be separated (e.g., graphene). Strong interlayer-bonding-layered materials (SLMs) in general have not been thoroughly explored, and one of the most critical present issues is the huge challenge of their preparation, although their physicochemical property transformation should be richer than VLMs and deserves greater attention. MAX phases are a classical kind of SLM. However, limited to the strong interlayer bonding, their corresponding 2D counterparts have never been obtained, nor has there been investigation of their fundamental properties in the 2D limitation. Here, the authors develop a controllable bottom-up synthesis strategy for obtaining 2D SLMs single crystal through the design of a molecular scaffold with Mo 2GaC, which is a typical kind of MAX phase, as an example. The superconducting transitions of Mo 2GaC at the 2D limit are clearly inherited from the bulk, which is consistent with Berezinskii–Kosterlitz–Thouless behavior. The authors believe that their molecular scaffold strategy will allow the fabrication of other high-quality 2D SLMs single crystals, which will further expand the family of 2D materials and promote their future application.

Mechanical, thermal transport, electronic and photocatalytic properties of penta-PdPS, -PdPSe and -PdPTe monolayers explored by first-principles calculations

2021 ◽  
Author(s):  
Bohayra Mortazavi ◽  
Masoud Shahrokhi ◽  
Xiaoying Zhuang ◽  
Alexander V. Shapeev ◽  
Timon Rabczuk
Keyword(s):  
First Principles ◽  
Thermal Transport ◽  
2D Materials ◽  
Layered Materials ◽  
Photocatalytic Properties ◽  
Two Dimensional ◽  
First Principles Calculations

In the latest experimental advances in the field of two-dimensional (2D) materials, penta-PdPS and penta-PdPSe layered materials have been fabricated. In this work, we conduct first-principles calculations to explore the...

First-principles investigation of copper diffusion barrier performance in defective 2D layered materials

2022 ◽  
Author(s):  
Manareldeen Ahmed ◽  
Yan Li ◽  
Wenchao Chen ◽  
Erping Li
Keyword(s):  
Barrier Layer ◽  
Diffusion Barrier ◽  
First Principles ◽  
Energy Barrier ◽  
2D Materials ◽  
Diffusion Path ◽  
Layered Materials ◽  
Vacancy Defects ◽  
2D Layered Materials ◽  
Barrier Performance

Abstract This paper investigates the diffusion barrier performance of 2D layered materials with pre-existing vacancy defects using first-principles density functional theory. Vacancy defects in 2D materials may give rise to a large amount of Cu accumulation, and consequently, the defect becomes a diffusion path for Cu. Five 2D layered structures are investigated as diffusion barriers for Cu, i.e., graphene with C vacancy, hBN with B/N vacancy, and MoS2 with Mo/2S vacancy. The calculated energy barriers using climbing image - nudged elastic band show that MoS2-V2S has the highest diffusion energy barrier among other 2D layers, followed by hBN-VN and graphene. The obtained energy barrier of Cu on defected layer is found to be proportional to the length of the diffusion path. Moreover, the diffusion of Cu through vacancy defects is found to modulate the electronic structures and magnetic properties of the 2D layer. The charge density difference shows that there exists a considerable charge transfer between Cu and barrier layer as quantified by Bader charge. Given the current need for an ultra-thin diffusion barrier layer, the obtained results contribute to the field of application of 2D materials as Cu diffusion barrier in the presence of mono-vacancy defects.

scholarly journals Growth and Properties of Dislocated Two-dimensional Layered Materials

MRS Advances ◽  
2020 ◽  
Vol 5 (64) ◽  
pp. 3437-3452
Author(s):  
Rui Chen ◽  
Jinhua Cao ◽  
Stephen Gee ◽  
Yin Liu ◽  
Jie Yao
Keyword(s):  
Catalytic Properties ◽  
Large Strain ◽  
Layered Materials ◽  
Research Field ◽  
Two Dimensional ◽  
Research Attention ◽  
Stacking Order ◽  
2D Layered Materials ◽  
Considerable Research ◽  
Local Modification

AbstractTwo-dimensional (2D) layered materials hosting dislocations have attracted considerable research attention in recent years. In particular, screw dislocations can result in a spiral topology and an interlayer twist in the layered materials, significantly impacting the stacking order and symmetry of the layers. Moreover, the dislocations with large strain and heavily distorted atomic registry can result in a local modification of the structures around the dislocation. The dislocations thus provide a useful route to engineering optical, electrical, thermal, mechanical and catalytic properties of the 2D layered materials, which show great potential to bring new functionalities. This article presents a comprehensive review of the experimental and theoretical progress on the growth and properties of the dislocated 2D layered materials. It also offers an outlook on the future works in this promising research field.

Sign in / Sign up

Export Citation Format

Share Document