scholarly journals A molecular approach to magnetic metallic nanostructures from metallopolymer precursors

2018 ◽  
Vol 47 (13) ◽  
pp. 4934-4953 ◽  
Author(s):  
Qingchen Dong ◽  
Zhengong Meng ◽  
Cheuk-Lam Ho ◽  
Hongen Guo ◽  
Weiyou Yang ◽  
...  

This tutorial review summarizes the strategies of using metallopolymers as precursors for generating functional magnetic metal/metal alloy NPs and other metal nanostructures.

2020 ◽  
Vol 18 (12) ◽  
pp. 861-880
Author(s):  
A. R. Aarathy ◽  
M. S. Gopika ◽  
S. Savitha Pillai

The advancements in magnetic nanoparticle mediated hyperthermia give so many optimistic and fruitful results that make it a promising and complementary approach for the existing treatment modalities of cancer. This thermotherapy is gaining wide acceptance among the medical community compared to the conventional treatment methods. The former provides a local heat generation in the malignant tumor cells and remains non-invasive to the adjacent healthy cells. The increased heating efficiency of magnetic nanoparticles and the control of local therapeutic temperature are the main challenges of hyperthermia. Superparamagnetic Iron Oxide nanoparticles have been intensively studied and dominating in magnetic hyperthermia. Recently many researchers successfully demonstrated high heating efficiency and biocompatibility of a wide variety of magnetic metal nanoparticles and proposed as the most promising alternative for traditional iron oxides, which opens up a new avenue for magnetic metal nanoparticles in magnetic hyperthermia. The review presents the recent advancements that occurred in the field of metal nanoparticle mediated magnetic hyperthermia. The theory underlying heat generation, synthesis methods, biofunctionalization, Specific Absorption Rate studies, challenges and future perspectives of magnetic metal nanoparticles are presented. This will inspire more in-depth research and advance practical applications of metal nanoparticles in magnetic hyperthermia.


2019 ◽  
Author(s):  
Yuji Naruse ◽  
Atsushi Takamori

Goodenough-Kanamori-Anderson rules (GKA rules) in superexchange interaction discriminate the magnetic properties of two magnetic metal ions bridged with an anion. We propose here that the GKA rules can be explained in terms of the orbital phase continuity-discontinuity property of cyclic orbital interaction including direct metal-metal orbital interaction.


2014 ◽  
Vol 288 ◽  
pp. 550-557 ◽  
Author(s):  
D.N. Patel ◽  
Ravi Pratap Singh ◽  
Raj K. Thareja

2014 ◽  
Vol 38 ◽  
pp. 90-96 ◽  
Author(s):  
Kong-Lin Wu ◽  
Xiang-Zi Li ◽  
Xian-Wen Wei ◽  
Ting-Hui Ding ◽  
Miao Jiang ◽  
...  

2020 ◽  
Author(s):  
Yuji Naruse ◽  
Atsushi Takamori

Goodenough-Kanamori-Anderson rules (GKA rules) in superexchange interaction discriminate the magnetic properties of two magnetic metal ions bridged with an anion. We propose here that the GKA rules can be explained in terms of the orbital phase continuity-discontinuity property of cyclic orbital interaction including direct metal-metal orbital interaction.


2020 ◽  
Vol 16 ◽  
Author(s):  
Burcu Dogan Topal ◽  
Ceren Elif Sener ◽  
Basak Kaya ◽  
Sibel Aysıl Ozkan

: Electrochemical analysis offers a number of important advantages such as providing information on pharmaceuticals analysis and their in vivo redox processes, and pharmacological activity. The interest in developing electrochemical sensing devices for use in clinical assays is growing rapidly. Metallic nanoparticles can be synthesized and modified with various chemical functional groups, which allow them to be conjugated with antibodies, ligands, and drugs of interest. In this article, the novel developments to enhance of the performance of sensor modified with metal nanoparticles of pharmaceuticals were reviewed. A discussion of the properties of metal nanostructures and their application in drug analysis is presented. Their application as modifier agent in determining low levels of drugs in pharmaceutical dosage forms and biological samples are discussed. It has been found that the electrocatalytic effect of the electrode, sensitivity and selectivity were increased using various working electrodes modified with nano-sized metal, metal oxide and metal / metal oxide particles.


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