scholarly journals Nonlinear optical properties, upconversion and lasing in metal–organic frameworks

2017 ◽  
Vol 46 (16) ◽  
pp. 4976-5004 ◽  
Author(s):  
Raghavender Medishetty ◽  
Jan K. Zaręba ◽  
David Mayer ◽  
Marek Samoć ◽  
Roland A. Fischer

The building block modular approach that lies behind coordination polymers (CPs) and metal–organic frameworks (MOFs) results not only in a plethora of materials that can be obtained but also in a vast array of nonlinear optical properties that could be aimed at.

2016 ◽  
Vol 45 (10) ◽  
pp. 4218-4223 ◽  
Author(s):  
Tao Song ◽  
Jiancan Yu ◽  
Yuanjing Cui ◽  
Yu Yang ◽  
Guodong Qian

Two series of cationic dyes have been encapsulated in the 1D channel of MOFs, and the tunable second order nonlinear optical properties of these MOF⊃dye materials were observed.


Author(s):  
Domenica Marabello ◽  
Paola Antoniotti ◽  
Paola Benzi ◽  
Fabio Beccari ◽  
Carlo Canepa ◽  
...  

In the last few decades optical imaging techniques based on nonlinear optical properties have been of interest for biosensing applications. This work focuses on two isostructural and isomorphous sugar-derived metal–organic frameworks (MOFs) with second-harmonic generation (SHG) properties, in order to investigate their possible application as biosensors in view of their high biocompatibility. Combining 2-deoxy-D-galactose with the metal halogenides CaX 2 (X = Br, I), two new isomorphous MOFs of formula [Ca(C6H12O5)2]X 2 were obtained and characterized through single-crystal X-ray diffraction. The first-order static hyperpolarizability and second-order susceptibility were estimated by in vacuo and in-crystal density functional theory calculations, and compared with the experimental SHG response of powdered samples. The parameters influencing the SHG response of these compounds were investigated by comparison with similar previously analysed MOFs, to understand how to design more efficient materials to be used as nanoprobes by exploiting crystal engineering techniques.


1995 ◽  
Vol 401 ◽  
Author(s):  
B. W. Wessels ◽  
M. J. Nystrom ◽  
J. Chen ◽  
D. Studebaker ◽  
T. J. Marks

AbstractFerroelectric oxide thin films show considerable potential as electro-optic and non-linear optical materials. Of particular interest are the niobates such as strontium barium niobate and potassium niobate. The growth of these epitaxial oxide films by metal-organic chemical vapor deposition (MOCVD) has been investigated. This technique has yielded epitaxial thin films with excellent non-linear optical properties. Issues concerning the epitaxy of these thin films and its relationship to their optical and nonlinear optical properties are discussed.


CrystEngComm ◽  
2019 ◽  
Vol 21 (21) ◽  
pp. 3343-3348 ◽  
Author(s):  
Quan Liu ◽  
Hong-Juan Xu ◽  
Li-Ce Yu ◽  
Ming-Jie Lu ◽  
Yan-Fang Shang ◽  
...  

Three isoreticular W/Cu/S 1D coordination polymers show good third-order NLO performance.


2017 ◽  
Vol 66 ◽  
pp. 197-200 ◽  
Author(s):  
Min Tan ◽  
Ruiqi Chen ◽  
Sanjun Yang ◽  
Qiming Liu

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