Titanium coordination compounds: from discrete metal complexes to metal–organic frameworks

2017 ◽  
Vol 46 (11) ◽  
pp. 3431-3452 ◽  
Author(s):  
Hala Assi ◽  
Georges Mouchaham ◽  
Nathalie Steunou ◽  
Thomas Devic ◽  
Christian Serre
Keyword(s):  
Metal Complexes ◽  
Coordination Compounds ◽  
Metal Organic Frameworks ◽  
Recent Advances ◽  
Metal Organic ◽  
Molecular Compounds

Recent advances in titanium based MOFs and relevant titanium molecular compounds will be discussed in this review. Particular attention will be devoted to their promising photoredox properties.

Recent advances on thermal energy storage using metal-organic frameworks (MOFs)

2021 ◽  
Vol 34 ◽  
pp. 102179
Author(s):  
Nokubonga Makhanya ◽  
Bilainu Oboirien ◽  
Jianwei Ren ◽  
Nicholas Musyoka ◽  
Adriano Sciacovelli
Keyword(s):  
Energy Storage ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Metal Organic Frameworks ◽  
Recent Advances ◽  
Metal Organic

Recent advances in adsorptive removal and catalytic reduction of hexavalent chromium by metal-organic frameworks composites

2021 ◽  
pp. 118274
Author(s):  
Mohamed E. Mahmoud ◽  
Sarah M. Elsayed ◽  
Safe ELdeen M.E. Mahmoud ◽  
Reham O. Aljedaani ◽  
Mohamed Abdel Salam
Keyword(s):  
Hexavalent Chromium ◽  
Catalytic Reduction ◽  
Metal Organic Frameworks ◽  
Adsorptive Removal ◽  
Recent Advances ◽  
Metal Organic

Recent advances in molecular logic gate chemosensors based on luminescent metal organic frameworks

2021 ◽  
Author(s):  
Bei Li ◽  
Dongsheng Zhao ◽  
Feng Wang ◽  
Xiaoxian Zhang ◽  
Wenqian Li ◽  
...  
Keyword(s):  
Logic Gate ◽  
Metal Organic Frameworks ◽  
Logic Gates ◽  
Design Strategies ◽  
Molecular Logic Gate ◽  
Future Developments ◽  
Molecular Logic ◽  
Molecular Logic Gates ◽  
Recent Advances ◽  
Metal Organic

This review covers the latest advancements of molecular logic gates based on LMOF. The classification, design strategies, related sensing mechanisms, future developments, and challenges of LMOFs-based logic gates are discussed.

scholarly journals X-ray crystallographic insights into post-synthetic metalation products in a metal–organic framework

2017 ◽  
Vol 375 (2084) ◽  
pp. 20160028 ◽  
Author(s):  
Michael T. Huxley ◽  
Campbell J. Coghlan ◽  
Witold M. Bloch ◽  
Alexandre Burgun ◽  
Christian J. Doonan ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Coordination Sphere ◽  
Metal Organic Frameworks ◽  
Void Space ◽  
X Ray ◽  
X Ray Crystallography ◽  
Metal Nitrates ◽  
Metal Organic

Post-synthetic modification of metal–organic frameworks (MOFs) facilitates a strategic transformation of potentially inert frameworks into functionalized materials, tailoring them for specific applications. In particular, the post-synthetic incorporation of transition-metal complexes within MOFs, a process known as ‘metalation’, is a particularly promising avenue towards functionalizing MOFs. Herein, we describe the post-synthetic metalation of a microporous MOF with various transition-metal nitrates. The parent framework, 1 , contains free-nitrogen donor chelation sites, which readily coordinate metal complexes in a single-crystal to single-crystal transformation which, remarkably, can be readily monitored by X-ray crystallography. The presence of an open void surrounding the chelation site in 1 prompted us to investigate the effect of the MOF pore environment on included metal complexes, particularly examining whether void space would induce changes in the coordination sphere of chelated complexes reminiscent of those found in the solution state. To test this hypothesis, we systematically metalated 1 with first-row transition-metal nitrates and elucidated the coordination environment of the respective transition-metal complexes using X-ray crystallography. Comparison of the coordination sphere parameters of coordinated transition-metal complexes in 1 against equivalent solid- and solution-state species suggests that the void space in 1 does not markedly influence the coordination sphere of chelated species but we show notably different post-synthetic metalation outcomes when different solvents are used. This article is part of the themed issue ‘Coordination polymers and metal–organic frameworks: materials by design’.

Recent advances in biomolecule immobilization based on self-assembly: organic–inorganic hybrid nanoflowers and metal–organic frameworks as novel substrates

2018 ◽  
Vol 6 (11) ◽  
pp. 1581-1594 ◽  
Author(s):  
Zhixian Lei ◽  
Chenling Gao ◽  
Lei Chen ◽  
Yanting He ◽  
Wende Ma ◽  
...  
Keyword(s):  
Self Assembly ◽  
Metal Organic Frameworks ◽  
Inorganic Hybrid ◽  
The Past ◽  
Biomolecule Immobilization ◽  
Recent Advances ◽  
Metal Organic

In the past few years, the immobilization of biomolecules on hybrid nanoflowers and metal–organic frameworks (MOFs) via self-assembly synthesis has received much attention due to its superior advantages.

Recent advances of metal-organic frameworks in corrosion protection: from synthesis to applications

2021 ◽  
pp. 132823
Author(s):  
Li Jiang ◽  
Yanmao Dong ◽  
Yan Yuan ◽  
Xing Zhou ◽  
Yingrui Liu ◽  
...  
Keyword(s):  
Corrosion Protection ◽  
Metal Organic Frameworks ◽  
Recent Advances ◽  
Metal Organic
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