Understanding proton capture and cation-induced dimerization of [Ag29(BDT)12]3−clusters by ion mobility mass spectrometry

2018 ◽  
Vol 20 (11) ◽  
pp. 7593-7603 ◽  
Author(s):  
Papri Chakraborty ◽  
Ananya Baksi ◽  
Sathish Kumar Mudedla ◽  
Abhijit Nag ◽  
Ganesan Paramasivam ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Alkali Metal ◽  
Metal Ions ◽  
Ion Mobility ◽  
Alkali Metal Ions ◽  
Ion Mobility Mass Spectrometry ◽  
Proton Capture ◽  
Unique Reaction

We present a unique reaction of [Ag29(BDT)12]3−cluster with protons and dimerization of the cluster induced by alkali metal ions.

Conformational Analysis and Binding Affinity Determination for Host—Guest Complexation of Alkali Metal Ions with Bis-Crown Ethers by Electrospray Mass Spectrometry and Molecular Modeling

2002 ◽  
Vol 8 (5) ◽  
pp. 375-380 ◽  
Author(s):  
Hui-Fen Wu ◽  
Shun-Min Huan ◽  
Chun-Fu Wu
Keyword(s):  
Mass Spectrometry ◽  
Alkali Metal ◽  
Metal Ions ◽  
Binding Affinity ◽  
Alkali Metal Ions ◽  
Ionization Mass ◽  
Potassium Ions ◽  
Esi Ms ◽  
Sandwich Type

This study presents the application of electrospray ionization mass spectrometry (ESI/MS) to investigate the host–guest complexation phenomenon for an array of alkali metal ions with bis[(benzo-15–crown-5)-15–ylmethyl] pimelate (BBCP). The results have shown that potassium ions possess the best binding affinity with the BBCP, owing to formation of the very stable sandwich-type (1:1) complexes and the strong K+ cation-π electron interactions between the K+ ion and the benzene rings of BBCP. The results of the competition experiments indicate the selectivity for BBCP toward the alkali metal ions is K+ > Rb+ > Cs+ > Na+ > Li+. In addition, combining the results of ESI/MS and molecular mechanics conformational searches reveal that the formation of sandwich-type (1:1) complexes can be observed for larger metal ions including K+, Rb+ and Cs+. As for Na+ ions, both 1:1 and 1:2 complexes can be observed.

Alkali Metal Cationization of Tumor-associated Antigen Peptides for Improved Dissociation and Measurement by Differential Ion Mobility-Mass Spectrometry

2020 ◽  
Vol 19 (8) ◽  
pp. 3176-3183
Author(s):  
James E. Keating ◽  
Chris Chung ◽  
Shengjie Chai ◽  
Jans F. Prins ◽  
Benjamin G. Vincent ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Alkali Metal ◽  
Ion Mobility ◽  
Ion Mobility Mass Spectrometry ◽  
Tumor Associated Antigen

A possible origin of [M − nH + mX](m−n)+ ions (X = alkali metal ions) in electrospray mass spectrometry of peptides

1999 ◽  
Vol 192 (1-3) ◽  
pp. 303-317 ◽  
Author(s):  
Christopher F Rodriquez ◽  
René Fournier ◽  
Ivan K Chu ◽  
Alan C Hopkinson ◽  
K.W.Michael Siu
Keyword(s):  
Mass Spectrometry ◽  
Alkali Metal ◽  
Metal Ions ◽  
Electrospray Mass Spectrometry ◽  
Alkali Metal Ions

scholarly journals Alkali metal cation adduct effect on polybutylene adipate oligomers: Ion mobility-mass spectrometry

Polymer ◽  
2019 ◽  
Vol 173 ◽  
pp. 58-65 ◽  
Author(s):  
Tiffany M. Crescentini ◽  
Jody C. May ◽  
John A. McLean ◽  
David M. Hercules
Keyword(s):  
Mass Spectrometry ◽  
Alkali Metal ◽  
Ion Mobility ◽  
Metal Cation ◽  
Alkali Metal Cation ◽  
Ion Mobility Mass Spectrometry
Sign in / Sign up

Export Citation Format

Share Document