Insights into the effect of donor ability on photophysical properties of dihydroindeno[2,1-c]fluorene-based imide derivatives

2018 ◽  
Vol 20 (11) ◽  
pp. 7514-7522 ◽  
Author(s):  
Guiying He ◽  
Li-Li Zhou ◽  
Hongwei Song ◽  
Zhuoran Kuang ◽  
Xian Wang ◽  
...  

The photophysical properties of dihydroindeno[2,1-c]fluorene-based imide (DHIFI) derivatives were investigated by steady-state and time-resolved spectroscopy as well as quantum chemical calculations.

2011 ◽  
Vol 10 (04n05) ◽  
pp. 867-871
Author(s):  
TAPASI SEN ◽  
AMITAVA PATRA

The photophysical properties of the confined dye inside the γ-CD in presence of Au nanoparticles have been studied by steady state and time resolved spectroscopy. It is found that the photoluminescence quenching of C480 dye increases from 26% to 49% due to confinement of dye inside γ-CD. The designing of such new optical based materials having coumarin 480 dye inside the γ-CD in presence of Au nanoparticles may have potential applications for light harvesting system.


2005 ◽  
Vol 77 (6) ◽  
pp. 1035-1050 ◽  
Author(s):  
A. D’Aléo ◽  
S. Welter ◽  
E. Cecchetto ◽  
L. De Cola

The synthesis and photophysical properties of heterometallic dinuclear complexes based on ruthenium and osmium trisbipyridine units, Ru-mPh3-Os and Ru-mPh5-Os, in which the metal complexes are linked via an oligophenylene bridge centrally connected in the meta position, are described. Electronic energy transfer from the excited ruthenium-based component (donor) to the osmium moiety (acceptor) has been investigated using steady-state and time-resolved spectroscopy. The results obtained for the meta-substituted compounds are compared with the analogous systems in which the phenylene spacers are substituted in the para position. The mechanism of energy transfer is discussed.


RSC Advances ◽  
2020 ◽  
Vol 10 (71) ◽  
pp. 43459-43471
Author(s):  
Hussain A. Z. Sabek ◽  
Ahmed M. M. Alazaly ◽  
Dina Salah ◽  
Hesham S. Abdel-Samad ◽  
Mohamed A. Ismail ◽  
...  

Solvation-dependent photophysical properties of two push–pull thiophene-based compounds with donor–π–acceptor (D–π–A) structures were investigated using absorption, fluorescence emission and time resolved spectroscopy, and supported by different solvation models.


2017 ◽  
Vol 16 (4) ◽  
pp. 539-546 ◽  
Author(s):  
C. Rémy ◽  
C. Allain ◽  
I. Leray

A series of π conjugated naphthalimide derivatives were prepared. Compounds display efficient photoinduced charge transfer in solution which was rationalized by time-resolved spectroscopy and modelled by TD-DFT calculations.


1996 ◽  
Vol 70 (1-6) ◽  
pp. 364-376 ◽  
Author(s):  
S.V. Gaponenko ◽  
E.P. Petrov ◽  
U. Woggon ◽  
O. Wind ◽  
C. Klingshirn ◽  
...  

2004 ◽  
Vol 69 (4) ◽  
pp. 748-758 ◽  
Author(s):  
Israel V. Muthu Vijayan Enoch ◽  
Meenakshisundaram Swaminathan

The photophysical and photoprototropic behaviour of 4-aminobiphenyl (4ABP) in aqueous β-cyclodextrin (β-CDx) solution has been investigated using steady-state and time-resolved fluorescence spectroscopy. Fluorescence of the neutral form of 4ABP is enhanced due to the formation of a 1:1 complex with β-CDx. The formation of this complex has been confirmed by time-resolved spectroscopy. In the presence of β-CDx, no change was observed in the ground state pKa value but the excited state pKa value changed. Based on its photophysical and photoprototropic characteristics in β-CDx, the structure of the 1:1 inclusion complex is proposed.


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