scholarly journals Modifying bis(triflimide) ionic liquids by dissolving early transition metal carbamates

2018 ◽  
Vol 20 (7) ◽  
pp. 5057-5066 ◽  
Author(s):  
Lorenzo Biancalana ◽  
Giulio Bresciani ◽  
Cinzia Chiappe ◽  
Fabio Marchetti ◽  
Guido Pampaloni ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Transition Metal ◽  
Transition Metals ◽  
Metal Complexes ◽  
Electrostatic Interaction ◽  
Early Transition Metal ◽  
Maximum Value ◽  
Early Transition

Bis(triflimide) ionic liquids have been modified by dissolution ofN,N-dialkylcarbamates of early transition metals, the solubilities reaching the maximum value (1.46 M) with Nb(O2CNEt2)3. The solutions contain intact metal complexes, undergoing electrostatic interaction with the solvent cation.

New main-group and early transition-metal complexes of mono-pendant arm triazacyclononane ligands

2001 ◽  
pp. 170-180 ◽  
Author(s):  
Sergei Y. Bylikin ◽  
David A. Robson ◽  
Nigel A. H. Male ◽  
Leigh H. Rees ◽  
Philip Mountford ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Main Group ◽  
Early Transition Metal ◽  
Pendant Arm ◽  
Early Transition

End-on versus side-on bonding of dinitrogen to dinuclear early transition-metal complexes

1993 ◽  
Vol 115 (7) ◽  
pp. 2782-2792 ◽  
Author(s):  
Michael D. Fryzuk ◽  
T. S. Haddad ◽  
Murugesapillai Mylvaganam ◽  
David H. McConville ◽  
Steven J. Rettig
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Early Transition Metal ◽  
Early Transition
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