scholarly journals Different dominant transitions in holmium and ytterbium codoped oxyfluoride glass and glass ceramics originating from varying phonon energy environments

2017 ◽  
Vol 19 (44) ◽  
pp. 29833-29839 ◽  
Author(s):  
Qunhuo Liu ◽  
Ying Tian ◽  
Caizhi Wang ◽  
Feifei Huang ◽  
Xufeng Jing ◽  
...  

Varying phonon energy environments induce different dominant transitions, leading to enhanced visible upconversion and infrared emissions in glass ceramics.

2006 ◽  
Vol 99 (5) ◽  
pp. 053103 ◽  
Author(s):  
F. Lahoz ◽  
J. M. Almenara ◽  
U. R. Rodríguez-Mendoza ◽  
I. R. Martín ◽  
V. Lavín

MRS Bulletin ◽  
1998 ◽  
Vol 23 (11) ◽  
pp. 57-62 ◽  
Author(s):  
Matthew J. Dejneka

Low-phonon energy glasses are desirable hosts for rare-earth (RE) ions because they enable emission from RE energy levels that would otherwise be quenched in high-phonon energy glasses. Such emissions are of interest for fiber amplifiers operating at telecommunications wavelength band s of 1.31, 1.46, and 1.55 μm, and for up-conversion lasers and three-dimensional displays.Phonons are optical-frequency molecular vibrations in a material. If the RE energy level of interest lies only a few phonons in energy above the next lower lying level such as the 1G4 level of Pr3+, which is only 3,000 cm −1 above the 3F4, only three Si—O vibrational phonons (1,100 cm−1) are required to bridge the gap as shown in Figure 1. Thus any electrons excited to the 1G4 level via an external pump source will be deexcited to the 3F4 on down to the 3H4 ground state via phonons, and no radiation of usable light will be produced. This is why emission from the 1G4 level of Pr3+ is absent in silicates and why researchers have gone to great lengths to make low-phonon energy glasses.


2012 ◽  
Vol 96 (2) ◽  
pp. 476-480 ◽  
Author(s):  
Go Kawamura ◽  
Ryota Yoshimura ◽  
Kazunari Ota ◽  
Song-Yul Oh ◽  
Norio Hakiri ◽  
...  

Author(s):  
Marcin Środa ◽  
Krzysztof Szlósarczyk ◽  
Marek Różański ◽  
Maciej Sitarz ◽  
Piotr Jeleń

2013 ◽  
Vol 137 ◽  
pp. 70-72 ◽  
Author(s):  
YunLe Wei ◽  
Jingjing Li ◽  
JingWen Yang ◽  
XianNian Chi ◽  
Hai Guo

2008 ◽  
Vol 3 (12) ◽  
pp. 516-520 ◽  
Author(s):  
Hua Yu ◽  
Nan Hu ◽  
Ya-Nan Wang ◽  
Zi-Lan Wang ◽  
Zong-Song Gan ◽  
...  

2018 ◽  
Vol 193 ◽  
pp. 61-69 ◽  
Author(s):  
J.J. Velázquez ◽  
R. Balda ◽  
J. Fernández ◽  
G. Gorni ◽  
L. Pascual ◽  
...  

2012 ◽  
Vol 49 (6-I) ◽  
pp. 44-48
Author(s):  
I. Brice ◽  
U. Rogulis ◽  
E. Elsts ◽  
J. Grūbe

Abstract The photoluminescence of SiO2-Al2O3-LiO2-LaF3 oxyfluoride glass and glass ceramic samples doped with Ce3+, Eu2+ and Ce3+/Eu2+ is investigated, and the spectra and fluorescence intensities are compared. The luminescence of samples activated by Eu ions is found to be more intensive than of the samples doped with Ce or Ce/Eu. The luminescence of glass ceramics is higher than that of the corresponding glass, which indicates that a proportion of the activator ions are embedded in the fluoride crystallites.


2019 ◽  
Vol 237 ◽  
pp. 121830 ◽  
Author(s):  
S.E. Kichanov ◽  
Yu.E. Gorshkova ◽  
G.E. Rachkovskaya ◽  
D.P. Kozlenko ◽  
G.B. Zakharevich ◽  
...  

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