scholarly journals Elucidating electrolyte decomposition under electron-rich environments at the lithium-metal anode

2017 ◽  
Vol 19 (45) ◽  
pp. 30861-30873 ◽  
Author(s):  
Luis E. Camacho-Forero ◽  
Perla B. Balbuena
Keyword(s):  
Lithium Metal ◽  
Next Generation ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Battery Systems ◽  
Lithium Sulfur

The lithium metal anode is one of the key components of the lithium–sulfur (Li–S) batteries, which are considered one of the most promising candidates for the next generation of battery systems.

Highly Stable Lithium Metal Anode Interface via Molecular Layer Deposition Zircone Coatings for Long Life Next‐Generation Battery Systems

2019 ◽  
Vol 131 (44) ◽  
pp. 15944-15949 ◽  
Author(s):  
Keegan R. Adair ◽  
Changtai Zhao ◽  
Mohammad Norouzi Banis ◽  
Yang Zhao ◽  
Ruying Li ◽  
...  
Keyword(s):  
Molecular Layer ◽  
Lithium Metal ◽  
Next Generation ◽  
Molecular Layer Deposition ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Layer Deposition ◽  
Battery Systems ◽  
Long Life

scholarly journals Artificial dual solid-electrolyte interfaces based on in situ organothiol transformation in lithium sulfur battery

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Wei Guo ◽  
Wanying Zhang ◽  
Yubing Si ◽  
Donghai Wang ◽  
Yongzhu Fu ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Interface Reaction ◽  
Interfacial Instability ◽  
Anode Surface ◽  
Commercial Application ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Lithium Sulfur

AbstractThe interfacial instability of the lithium-metal anode and shuttling of lithium polysulfides in lithium-sulfur (Li-S) batteries hinder the commercial application. Herein, we report a bifunctional electrolyte additive, i.e., 1,3,5-benzenetrithiol (BTT), which is used to construct solid-electrolyte interfaces (SEIs) on both electrodes from in situ organothiol transformation. BTT reacts with lithium metal to form lithium 1,3,5-benzenetrithiolate depositing on the anode surface, enabling reversible lithium deposition/stripping. BTT also reacts with sulfur to form an oligomer/polymer SEI covering the cathode surface, reducing the dissolution and shuttling of lithium polysulfides. The Li–S cell with BTT delivers a specific discharge capacity of 1,239 mAh g−1 (based on sulfur), and high cycling stability of over 300 cycles at 1C rate. A Li–S pouch cell with BTT is also evaluated to prove the concept. This study constructs an ingenious interface reaction based on bond chemistry, aiming to solve the inherent problems of Li–S batteries.

scholarly journals Binary PMMA/PVDF blend film modified substrate enables superior lithium metal anode for lithium batteries

2021 ◽  
Author(s):  
Yuping Wu ◽  
Xiaosong Xiong ◽  
Ruoyu Zhi ◽  
Qi Zhou ◽  
Wenqi Yan ◽  
...  
Keyword(s):  
Electrode Material ◽  
Lithium Batteries ◽  
Specific Capacity ◽  
Lithium Metal ◽  
Next Generation ◽  
Safety Hazards ◽  
Blend Film ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Metallic Lithium

Metallic lithium is an promising next generation electrode material due to its ultrahigh specific capacity and the lowest potential. However, short cycling lifespan and safety hazards have hindered the practical...

scholarly journals Next-Generation Lithium Metal Anode Engineering via Atomic Layer Deposition

ACS Nano ◽  
2015 ◽  
Vol 9 (6) ◽  
pp. 5884-5892 ◽  
Author(s):  
Alexander C. Kozen ◽  
Chuan-Fu Lin ◽  
Alexander J. Pearse ◽  
Marshall A. Schroeder ◽  
Xiaogang Han ◽  
...  
Keyword(s):  
Atomic Layer Deposition ◽  
Atomic Layer ◽  
Lithium Metal ◽  
Next Generation ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Layer Deposition

Self‐Formed Protection Layer on a 3D Lithium Metal Anode for Ultrastable Lithium–Sulfur Batteries

ChemSusChem ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 2263-2270 ◽  
Author(s):  
Xinxiu Yan ◽  
Huan Zhang ◽  
Meiling Huang ◽  
Meizhen Qu ◽  
Zhikai Wei
Keyword(s):  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Lithium Sulfur Batteries ◽  
Protection Layer ◽  
Lithium Sulfur

scholarly journals Reactivity at the Lithium–Metal Anode Surface of Lithium–Sulfur Batteries

2015 ◽  
Vol 119 (48) ◽  
pp. 26828-26839 ◽  
Author(s):  
Luis E. Camacho-Forero ◽  
Taylor W. Smith ◽  
Samuel Bertolini ◽  
Perla B. Balbuena
Keyword(s):  
Anode Surface ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Lithium Sulfur Batteries ◽  
Lithium Sulfur

scholarly journals Engineering and characterization of interphases for Lithium metal anode 

2021 ◽  
Author(s):  
Zulipiya Shadike ◽  
Sha Tan ◽  
Ruoqian Lin ◽  
Xia Cao ◽  
Enyuan Hu ◽  
...  
Keyword(s):  
Energy Density ◽  
Specific Capacity ◽  
High Energy ◽  
High Energy Density ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Battery Systems ◽  
Theoretical Specific Capacity

Lithium metal is a very promising anode material in achieving high energy density for next generation battery systems due to its low redox potential and high theoretical specific capacity of...

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