Ultrafast dynamics of the ESIPT photoswitch N-(3-pyridinyl)-2-pyridinecarboxamide

2018 ◽  
Vol 20 (4) ◽  
pp. 2646-2655 ◽  
Author(s):  
Hendrik Böhnke ◽  
Julia Bahrenburg ◽  
Xiaonan Ma ◽  
Katharina Röttger ◽  
Christian Näther ◽  
...  

A potential ESIPT photoswitch has been investigated by femtosecond time-resolved electronic and vibrational absorption spectroscopy.

2022 ◽  
Vol 29 (1) ◽  
Author(s):  
Yujin Kim ◽  
Daewoong Nam ◽  
Rory Ma ◽  
Sangsoo Kim ◽  
Myung-jin Kim ◽  
...  

Understanding the ultrafast dynamics of molecules is of fundamental importance. Time-resolved X-ray absorption spectroscopy (TR-XAS) is a powerful spectroscopic technique for unveiling the time-dependent structural and electronic information of molecules that has been widely applied in various fields. Herein, the design and technical achievement of a newly developed experimental apparatus for TR-XAS measurements in the tender X-ray range with X-ray free-electron lasers (XFELs) at the Pohang Accelerator Laboratory XFEL (PAL-XFEL) are described. Femtosecond TR-XAS measurements were conducted at the Ru L 3-edge of well known photosensitizer tris(bipyridine)ruthenium(II) chloride ([Ru(bpy)3]2+) in water. The results indicate ultrafast photoinduced electron transfer from the Ru center to the ligand, which demonstrates that the newly designed setup is applicable for monitoring ultrafast reactions in the femtosecond domain.


2018 ◽  
Vol 20 (30) ◽  
pp. 20033-20042 ◽  
Author(s):  
Hendrik Böhnke ◽  
Katharina Röttger ◽  
Rebecca A. Ingle ◽  
Hugo J. B. Marroux ◽  
Mats Bohnsack ◽  
...  

The photophysical dynamics of 2-aminopurine, a fluorescent analogue of the canonical nucleobase adenine, has been studied by femtosecond transient vibrational absorption spectroscopy.


Nano Letters ◽  
2021 ◽  
Vol 21 (4) ◽  
pp. 1729-1734
Author(s):  
Jacopo Stefano Pelli Cresi ◽  
Emiliano Principi ◽  
Eleonora Spurio ◽  
Daniele Catone ◽  
Patrick O’Keeffe ◽  
...  

2016 ◽  
Vol 18 (37) ◽  
pp. 26224-26235 ◽  
Author(s):  
Daisuke Koyama ◽  
Andrew J. Orr-Ewing

An adduct-mediated triplet energy transfer from a triplet thione to an alkene is observed with time-resolved vibrational absorption spectroscopy.


2020 ◽  
Vol 7 (4) ◽  
pp. 044101
Author(s):  
Khadijeh Khalili ◽  
Ludger Inhester ◽  
Caroline Arnold ◽  
Anders S. Gertsen ◽  
Jens Wenzel Andreasen ◽  
...  

Author(s):  
Qun Zhang ◽  
Yi Luo

Over the past decade the integration of ultrafast spectroscopy with nanoscience has greatly propelled the development of nanoscience, as the key information gleaned from the mechanistic studies with the assistance of ultrafast spectroscopy enables a deeper understanding of the structure–function interplay and various interactions involved in the nanosystems. This mini-review presents an overview of the recent advances achieved in our ultrafast spectroscopy laboratory that address the ultrafast dynamics and related mechanisms in several representative nanomaterial complex systems by means of femtosecond time-resolved transient absorption spectroscopy. We attempt to convey instructive, consistent information regarding the important processes, pathways, dynamics, and interactions involved in the nanomaterial complex systems, most of which exhibit excellent performance in photocatalysis.


2000 ◽  
Vol 104 (17) ◽  
pp. 3964-3973 ◽  
Author(s):  
Sergey A. Nizkorodov ◽  
Warren W. Harper ◽  
Bradley W. Blackmon ◽  
David J. Nesbitt

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