Multiple interaction regulated phase transition behavior of thermo-responsive copolymers containing cationic poly(ionic liquid)s

2017 ◽  
Vol 19 (45) ◽  
pp. 30804-30813 ◽  
Author(s):  
Yingna Zhang ◽  
Hui Tang ◽  
Peiyi Wu

Schematic illustration of the phase transition mechanism of the P(OEGMA-co-BVIm[SCN]) copolymer.

2018 ◽  
Vol 9 (21) ◽  
pp. 2887-2896 ◽  
Author(s):  
Shoumin Chen ◽  
Xuezhen Lin ◽  
Zhenghao Zhai ◽  
Ruyue Lan ◽  
Jin Li ◽  
...  

A class of poly(ionic liquid) microgels exhibiting CO2-switchable temperature-responsive volume phase transition behavior have been synthesized and used for CO2 fixation.


2017 ◽  
Vol 19 (33) ◽  
pp. 22263-22271 ◽  
Author(s):  
Lan Ma ◽  
Ge Wang ◽  
Shengtong Sun ◽  
Peiyi Wu

The study of a ternary solution involving a thermoresponsive polymer, a thermoresponsive ionic liquid (IL), and a solvent will not only help with interpreting their distinct phase transition behavior, but also promote the development of novel thermoresponsive systems.


Soft Matter ◽  
2018 ◽  
Vol 14 (21) ◽  
pp. 4380-4387
Author(s):  
Yingna Zhang ◽  
Hui Tang ◽  
Peiyi Wu

Schematic illustration of the phase transition mechanism of P[SS-P2] aqueous solutions.


2015 ◽  
Vol 17 (38) ◽  
pp. 25525-25535 ◽  
Author(s):  
Yuanyuan Zhou ◽  
Hui Tang ◽  
Peiyi Wu

Thermodynamic volume phase transition mechanisms of poly[oligo(ethylene glycol)methacrylate] (POEGMA) microgels with poly(ionic liquid) (PIL) cross-linking moieties were investigated in detail on the basis of Fourier transform infrared (FTIR) spectroscopy.


2018 ◽  
Vol 20 (12) ◽  
pp. 8077-8087 ◽  
Author(s):  
Lan Ma ◽  
Peiyi Wu

By comparing with the linear homopolymer mixture, the influence of spatial structure on the phase behavior of thermosensitive interpenetrating polymer network (IPN) microgels was clarified.


2017 ◽  
Vol 19 (28) ◽  
pp. 18556-18564 ◽  
Author(s):  
Yalan Dai ◽  
Peiyi Wu

PMEO2MA-b-P[P4,4,4,4][SS] exhibits a two-step microdynamic aggregation process upon heating, but only one LCST-type transition point from the macroscopic perspective.


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