Central-metal effect on intramolecular vibrational energy transfer of M(CO)5Br (M = Mn, Re) probed by two-dimensional infrared spectroscopy

2018 ◽  
Vol 20 (5) ◽  
pp. 3637-3647 ◽  
Author(s):  
Fan Yang ◽  
Xueqian Dong ◽  
Minjun Feng ◽  
Juan Zhao ◽  
Jianping Wang
Keyword(s):  
Energy Transfer ◽  
Infrared Spectroscopy ◽  
Vibrational Energy ◽  
Central Metal ◽  
Two Dimensional ◽  
Vibrational Energy Transfer ◽  
Vibrational Coupling ◽  
Two Dimensional Infrared Spectroscopy ◽  
Metal Effect

Central-metal effect on IVR time correlates with the vibrational coupling between the two involved modes.

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