Quantum-state-selected integral cross sections for the charge transfer collision of O2+(a4Πu5/2,3/2,1/2,−1/2: v+= 1–2; J+) [O2+(X2Πg3/2,1/2: v+= 22–23; J+)] + Ar at center-of-mass collision energies of 0.05–10.00 eV

2017 ◽  
Vol 19 (43) ◽  
pp. 29057-29067 ◽  
Author(s):  
Bo Xiong ◽  
Yih-Chung Chang ◽  
Cheuk-Yiu Ng

Study of spin–orbit and rovibronically selected ion-molecule reactions between O2+(a4Πu,ν+= 1–2; X2Πg,ν+= 22–23) and Ar.

2016 ◽  
Vol 18 (32) ◽  
pp. 22509-22515 ◽  
Author(s):  
Hongwei Song ◽  
Anyang Li ◽  
Hua Guo ◽  
Yuntao Xu ◽  
Bo Xiong ◽  
...  

A combined experimental–theoretical study of the rovibrationally state-selected ion–molecule reactions H2O+(X2B1; v1+v2+v3+; NKa+Kc++) + H2 (D2) → H3O+ (H2DO+) + H (D), where (v1+v2+v3+) = (000), (020), and (100) and NKa+Kc++ = 000, 111, and 211.


2002 ◽  
Vol 20 (3) ◽  
pp. 493-495 ◽  
Author(s):  
H. BRÄUNING ◽  
A. DIEHL ◽  
K.v. DIEMAR ◽  
A. THEIß ◽  
R. TRASSL ◽  
...  

In heavy ion fusion, the compression of the DT pellet requires high intensity beams of ions in the gigaelectron volt energy range. Charge-changing collisions due to intrabeam scattering can have a high impact on the design of adequate accelerator and storage rings. Not only do intensity losses have to be taken into account, but also the deposition of energy on the beam lines after bending magnets, for example, may be nonnegligible. The center-of-mass energy for these intrabeam collisions is typically in the kiloelectron volt range for beam energies in the order of several gigaelectron volts. In this article, we present experimental cross sections for charge transfer and ionization in homonuclear collisions of Ar4+, Kr4+, and Xe4+, and for charge transfer only in homonuclear collisions of Pb4+ and Bi4+. Using a hypothetical 100-Tm synchrotron as an example, expected particle losses are calculated based on the experimental data. The results are compared with expectations for singly charged Bi+ ions, which are usually considered for heavy ion fusion.


1986 ◽  
Vol 6 (6) ◽  
pp. 391-402 ◽  
Author(s):  
Mark L. Campbell ◽  
Nick Furio ◽  
Paul J. Dagdigian

Chemiluminescence cross sections for reaction of the individual spin–orbit states of metastable Ca(PJ03) with CH3I, CH2I2, and SF6 have been determined by the use of optical pumping state selection. This technique was also used to separate the chemiluminescence arising from the two excited metastable Ca 3P0 and 1D states. The spin–orbit dependence of the chemiluminescence pathway was found to be substantial for the CH3I and CH2I2 reactions and similar to that previously observed for halogen diatom and alkyl bromide reagents. By contrast, no spin–orbit effect was observed for Ca(3P0)+SF6. These results are discussed in terms of our previously presented model for the origin of spin–orbit effects in chemical reactions.


2021 ◽  
Vol 103 (19) ◽  
Author(s):  
Miguel J. Carballido ◽  
Christoph Kloeffel ◽  
Dominik M. Zumbühl ◽  
Daniel Loss

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