A kinetic study of the CH2OO Criegee intermediate reaction with SO2, (H2O)2, CH2I2 and I atoms using OH laser induced fluorescence

2017 ◽  
Vol 19 (31) ◽  
pp. 20786-20794 ◽  
Author(s):  
Yiqiang Liu ◽  
Fenghua Liu ◽  
Siyue Liu ◽  
Dongxu Dai ◽  
Wenrui Dong ◽  
...  
Keyword(s):  
Kinetic Study ◽  
Laser Induced Fluorescence ◽  
Fluorescence Method ◽  
Intermediate Reaction ◽  
Kinetics Of

The OH laser induced fluorescence method was used to study the kinetics of CH2OO reacting with SO2, (H2O)2, CH2I2 and I atoms.

Kinetics of the reaction of the simplest Criegee intermediate with ammonia: a combination of experiment and theory

2018 ◽  
Vol 20 (47) ◽  
pp. 29669-29676 ◽  
Author(s):  
Yiqiang Liu ◽  
Cangtao Yin ◽  
Mica C. Smith ◽  
Siyue Liu ◽  
Maodu Chen ◽  
...  
Keyword(s):  
Temperature Dependence ◽  
Rate Coefficient ◽  
Negative Temperature ◽  
Laser Induced Fluorescence ◽  
Fluorescence Method ◽  
Kinetics Of

The negative temperature dependence of the rate coefficient for CH2OO + NH3 reaction was observed using an OH laser-induced fluorescence method.

scholarly journals The Reaction Kinetics of Amino Radicals with Sulfur Dioxide

2015 ◽  
Vol 229 (10-12) ◽  
Author(s):  
Yide Gao ◽  
Peter Glarborg ◽  
Paul Marshall
Keyword(s):  
Sulfur Dioxide ◽  
Reaction Kinetics ◽  
Laser Induced Fluorescence ◽  
Laser Photolysis ◽  
Fluorescence Method ◽  
Photolysis Laser ◽  
Kinetics Of

AbstractApplication of the laser photolysis–laser-induced fluorescence method to the reaction NH

A Kinetic Study of the Thermal Isomerization of and Related Complexes

1975 ◽  
Vol 53 (12) ◽  
pp. 1735-1738 ◽  
Author(s):  
William R. Cullen ◽  
Frank L. Hou
Keyword(s):  
Kinetic Study ◽  
Thermal Isomerization ◽  
Isomerization Reaction ◽  
Kinetics Of

The kinetics of the unimolecular isomerization reaction[Formula: see text]have been studied. The ΔH≠ values in kcal mol−1 are 36.8 ± 2.0 (M = M′ = Mn ), 46.8 ± 0.5 (M = M′ = Re ), 39.2 ± 2.8 (M = Mn, M′ = Re ). The mechanism of the rearrangement is discussed.

The Kinetics of Methyl Methacrylate Miniemulsion Polymerization Characterized through a Fluorescence Method

2012 ◽  
Vol 178-181 ◽  
pp. 609-612
Author(s):  
Hai Ke Feng ◽  
Hua Yu Qiu ◽  
Li Yuan Ding ◽  
Cun Jin Xu
Keyword(s):  
Methyl Methacrylate ◽  
Anionic Surfactant ◽  
Sodium Dodecyl Sulphate ◽  
Sodium Dodecyl ◽  
Miniemulsion Polymerization ◽  
Time Measurement ◽  
Fluorescence Method ◽  
Real Time Measurement ◽  
Measurement Results ◽  
Kinetics Of

In this paper, we followed the kinetics of methyl methacrylate (MMA) through a novel fluorescence method. The real-time measurement results show that in the regime of very low monomer contents, such as a solution containing 0.1 wt% of MMA with respect to water and with the anionic surfactant of sodium dodecyl sulphate (SDS), the kinetic of the miniemulsion could be followed by this embed fluorescence method. The processes of changing from emulsion to miniemulsion with different amount of surfactant and cosurfactant also have been monitored.

Kinetic Study of the Diels-Alder Reaction of Cyclopentadiene with Bis(2-Ethylhexyl) Maleate

2013 ◽  
Vol 634-638 ◽  
pp. 541-545 ◽  
Author(s):  
Jun Seong Park ◽  
Dae Hee Yun ◽  
Tae Won Ko ◽  
Yong Sung Park ◽  
Je Wan Woo
Keyword(s):  
Kinetic Study ◽  
Reaction Temperature ◽  
Atmospheric Pressure ◽  
Arrhenius Equation ◽  
Alder Reaction ◽  
Diels Alder ◽  
Influence Of Temperature ◽  
Diels Alder Reaction ◽  
Influence Of Temperature On ◽  
Kinetics Of

The kinetics of the Diels-Alder reaction of cyclopentadiene with bis(2-ethylhexyl) maleate has been studied at temperatures between 25 and 100 °C and at atmospheric pressure. The influence of temperature on the kinetic constants was determined by fitting the results to the Arrhenius equation. As a result, fitting line similar with the linear curve of the Arrhenius equation at 25, 30 and 40 °C. However, the fitting curve, at 60, 80 and 100 °C, tended towards the outside of the curve in the form of Arrhenius equation. The ratio of endo/exo was a slight change from increase of the reaction temperature.

Sign in / Sign up

Export Citation Format

Share Document