Constructing heterostructured Li–Fe–Ni–Mn–O cathodes for lithium-ion batteries: effective improvement of ultrafast lithium storage

2017 ◽  
Vol 19 (33) ◽  
pp. 22494-22501 ◽  
Author(s):  
Taolin Zhao ◽  
Na Zhou ◽  
Xiaoxiao Zhang ◽  
Qing Xue ◽  
Yuhua Wang ◽  
...  

A heterostructured Li–Fe–Ni–Mn–O cathode material with layered/spinel phases shows superior ultrafast lithium storage capability.

Batteries ◽  
2019 ◽  
Vol 5 (2) ◽  
pp. 46
Author(s):  
Qian Yang ◽  
Zhengguang Zou ◽  
Xingyu Wu ◽  
Shengyu Li ◽  
Yanjiao Zhang

Ni-doped VO2(B) samples (NixVO2(B)) were fabricated by a facile one-step hydrothermal method. When evaluated as a cathode material for lithium ion batteries (LIBs), these Ni-doped VO2(B) exhibited improved lithium storage performance as compared to the pure VO2(B). In particular, when the doping amount is 3%, NixVO2(B) showed the highest lithium storage capacity, best cycling stability, smallest electrochemical reaction resistance, and largest lithium diffusion coefficient. For example, after 100 cycles at a current density of 32.4 mA/g, NixVO2(B) delivered a high specific discharge capacity of 163.0 mAh/g, much higher than that of the pure VO2(B) sample (95.5 mAh/g). Therefore, Ni doping is an effective strategy for enhancing the lithium storage performance of VO2(B).


2018 ◽  
Vol 11 (04) ◽  
pp. 1850068 ◽  
Author(s):  
Changlei Niu

Aluminium has shown its superiority in stabilization of the monoclinic VO2(B) in free-standing nanobelts. In this paper, aluminium-doped VO2(B) nanobelts are successfully fabricated by a facile one-step hydrothermal method and used as cathode for lithium-ion battery. XPS results show that Al-doping promotes the formation of high valence state of vanadium in VO2(B) nanobelts. Due to the accommodation of valence state of vanadium and lattice volume, Al-doped VO2(B) nanobelts used as the cathode material for lithium-ion batteries exhibit better lithium storage properties with high capacity of 172[Formula: see text]mAh[Formula: see text]g[Formula: see text] and cycling stability than undoped VO2(B) nanobelts. This work demonstrates that the doping of aluminium can significantly enhance the electrochemical performance of VO2(B), suggesting that appropriate cationic doping is an efficient path to improve the electrochemical performance of electrode materials.


2019 ◽  
Vol 3 (10) ◽  
pp. 2697-2704 ◽  
Author(s):  
Jiali Wang ◽  
Yu Zhao ◽  
Xiaoqiang Zhang ◽  
Hailong Wu ◽  
Shouliang Hu ◽  
...  

By doping Mo into the Li2RuO3 framework, 0.98Li2RuO3–0.02Li2MoO3 is formed and displays enhanced electrochemical lithium storage reversibility in secondary batteries.


2021 ◽  
Vol 23 (10) ◽  
pp. 5992-5998
Author(s):  
Daniel Uxa ◽  
Helen J. Holmes ◽  
Kevin Meyer ◽  
Lars Dörrer ◽  
Harald Schmidt

Lithium tracer diffusivities in LiNi0.33Mn0.33Co0.33O2 cathode material for lithium-ion batteries follows the Arrhenius law with an activation energy of 0.85 eV.


2021 ◽  
Vol 421 ◽  
pp. 129964
Author(s):  
Guangchang Yang ◽  
Kai Pan ◽  
Feiyan Lai ◽  
Zhongmin Wang ◽  
Youqi Chu ◽  
...  

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