scholarly journals Structure–property relationships in protic ionic liquids: a thermochemical study

2017 ◽  
Vol 19 (30) ◽  
pp. 19928-19936 ◽  
Author(s):  
Joshua E. S. J. Reid ◽  
Filipe Agapito ◽  
Carlos E. S. Bernardes ◽  
Filomena Martins ◽  
Adam J. Walker ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Intermolecular Interactions ◽  
Fundamental Question ◽  
Thermochemical Study ◽  
Structure Property ◽  
Protic Ionic Liquids ◽  
Structure Property Relationships ◽  
Invaluable Tool

How does cation functionality influence the strength of intermolecular interactions in protic ionic liquids (PILs)? Quantifying the energetics of PILs can be an invaluable tool to answer this fundamental question.

scholarly journals Structure–property relationships in protic ionic liquids: a study of solvent–solvent and solvent–solute interactions

2017 ◽  
Vol 19 (41) ◽  
pp. 28133-28138 ◽  
Author(s):  
Joshua E. S. J. Reid ◽  
Carlos E. S. Bernardes ◽  
Filipe Agapito ◽  
Filomena Martins ◽  
Seishi Shimizu ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Structure Property ◽  
Protic Ionic Liquids ◽  
Structure Property Relationships ◽  
Solute Interactions ◽  
Solvent Solvent

Ionicity of protic ionic liquids are significantly affected by additional functionality, thereby influencing solvation properties.

Synthesis and Structure-Property Relationships in Herbicidal Ionic Liquids and their Double Salts

ChemPlusChem ◽  
2018 ◽  
Vol 83 (6) ◽  
pp. 529-541 ◽  
Author(s):  
Michał Niemczak ◽  
Tomasz Rzemieniecki ◽  
Agnieszka Biedziak ◽  
Katarzyna Marcinkowska ◽  
Juliusz Pernak
Keyword(s):  
Ionic Liquids ◽  
Structure Property ◽  
Structure Property Relationships ◽  
Double Salts

Structure-Property Relationships of Silylamine-Type Reversible Ionic Liquids for Use as a Switchable Electrolyte

2021 ◽  
Vol 168 (3) ◽  
pp. 036516
Author(s):  
Sungyup Jung ◽  
Showmik Podder ◽  
Josephine Chen ◽  
Elizabeth J. Biddinger
Keyword(s):  
Ionic Liquids ◽  
Structure Property ◽  
Structure Property Relationships

COSMO-RS Studies: Structure–Property Relationships for CO2 Capture by Reversible Ionic Liquids

2012 ◽  
Vol 51 (49) ◽  
pp. 16066-16073 ◽  
Author(s):  
Maria Gonzalez-Miquel ◽  
Manish Talreja ◽  
Amy L. Ethier ◽  
Kyle Flack ◽  
Jackson R. Switzer ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Co2 Capture ◽  
Structure Property ◽  
Structure Property Relationships

Amino Acid-derived Protic Ionic Liquids: Physicochemical Properties and Behaviour as Amphiphile Self-assembly Media

2011 ◽  
Vol 64 (2) ◽  
pp. 180 ◽  
Author(s):  
Jiayi Wang ◽  
Tamar L. Greaves ◽  
Danielle F. Kennedy ◽  
Asoka Weerawardena ◽  
Gonghua Song ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Amino Acid ◽  
Methyl Ester ◽  
Physicochemical Properties ◽  
Self Assembly ◽  
Ionic Surfactant ◽  
Hexadecyltrimethylammonium Bromide ◽  
Structure Property ◽  
Protic Ionic Liquids ◽  
Fused Salts

The thermal phase transitions and physicochemical properties of a series of 21 amino acid-derived protic ionic liquids and four protic molten salts have been investigated. Structure–property comparisons for this series were investigated for alkyl- and cyclic amino acid cations, and ethoxy and methoxy groups on the cation, combined with nitrate or various carboxylate-containing anions. All the protic fused salts were found to be ‘fragile’. Most of the protic fused salts exhibited a glass transition, with the transition temperatures ranging from –90° to –42°C. Viscosities and conductivities ranged from 0.03 to 15.46 Pa s and 0.02 to 2.20 mS cm–1 at 25°C respectively. The protic ionic liquids alanine methyl ester glycolate, proline methyl ester nitrate, and proline methyl ester glycolate were found to be capable of supporting amphiphile self-assembly. Lamellar or hexagonal liquid crystalline phases were observed with the cationic surfactant hexadecyltrimethylammonium bromide and the non-ionic surfactant Myverol 18–99K.

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