The dynamics of the Hg + Br2 reaction: elucidation of the reaction mechanism for the Br exchange reaction

2017 ◽  
Vol 19 (25) ◽  
pp. 16433-16445 ◽  
Author(s):  
P. G. Jambrina ◽  
M. Menéndez ◽  
F. J. Aoiz

The mechanism of the Hg + Br2 abstraction reaction reveals a richer and more complex dynamics that that could be expected.

1976 ◽  
Vol 54 (10) ◽  
pp. 1617-1623 ◽  
Author(s):  
T. N. Bell ◽  
P. J. Young

The reaction of CF3 radicals with SnMe4 leads to hydrogen abstraction and also radical exchange.[Formula: see text]We propose the exchange reaction proceeds via a five coordinate intermediate. The Arrhenius parameters for the exchange reaction are,[Formula: see text]Additional data for the H abstraction reaction[Formula: see text]combined with previous data yields an improved rate constant for abstraction,[Formula: see text]


1987 ◽  
Vol 35 (5) ◽  
pp. 1617-1630 ◽  
Author(s):  
K. I. Pearce ◽  
N. M. Clarke ◽  
R. J. Griffiths ◽  
P. J. Simmonds ◽  
and A. C. Dodd ◽  
...  

1973 ◽  
Vol 58 (3) ◽  
pp. 1202-1204 ◽  
Author(s):  
B. Freihaut ◽  
L. M. Raff

2017 ◽  
Vol 30 (12) ◽  
pp. e3713 ◽  
Author(s):  
Angappan Mano Priya ◽  
Senthilkumar Lakshmipathi

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